11.
    发明专利
    未知

    公开(公告)号:DE4142240A1

    公开(公告)日:1993-06-24

    申请号:DE4142240

    申请日:1991-12-20

    Applicant: BASF AG

    Abstract: Pigment preparations useful for pigmenting or delustering finishes for leather and leather substitutes consist essentially of pigments or delusterants or a mixture thereof, binders, water and if desired further customary dispersants and auxiliaries, the binders used being copolymers of A) from 40 to 80% by weight of at least one aromatic vinyl compound of the general formula I (* CHEMICAL STRUCTURE *) I where R1, R2 and R3 are each hydrogen, methyl or ethyl and n is 1 or 2, B) from 20 to 60% by weight of acrylic acid or methacrylic acid or a mixture thereof, and C) from 0 to 10% by weight of further copolymerizable monomers, in the form of their salts.

    DYESTUFFS CONTAINING SULPHONIC ACID GROUPS

    公开(公告)号:DE3261127D1

    公开(公告)日:1984-12-06

    申请号:DE3261127

    申请日:1982-06-12

    Applicant: BASF AG

    Abstract: The present invention discloses substituted phenyl di and trisazo dyes free of reactive groups having two or three sulfonic acid groups, of the general formula: (I) wherein D1 is Z is hydrogen or D4-N=N-; D2 is phenyl substituted by hydroxyl, hydroxysulfonyl, chlorine or nitro, or is naphthyl substituted by hydroxy, hydroxysulfonyl or nitro, X, independently of one another, are hydroxyl or amino, D3 is phenyl which is substituted by hydroxysulfonyl, chlorine, bromine, methyl, methoxy, ethoxy, nitro, phenylamino, sulfophenylamino or nitrosulfophenylamino, or is naphthyl which is substituted by hydroxysulfonyl; D4 is phenyl which is unsubstituted or substituted by methyl, ethyl, methoxy, ethoxy, chlorine, bromine, nitro, sulfamoyl or hydroxysulfonyl, or is naphthyl which is substituted by hydroxysulfonyl; and R2 is methyl, ethyl or allyl; the rings B and E may additionally be substituted by methyl, ethyl, methoxy, ethoxy, chlorine, bromine or hydroxysulfonyl, with the proviso that D2 has a hydroxyl group ortho to the azo bond; or the iron, manganese, cobalt, chromium, nickel or copper complexes of this dye. These compounds, particularly in the form of their metal complexes are suitable for dyeing nitrogen-containing fibers such as wool, and preferably, leather. The present dyes yield very fast brown hues, in particular on retanned leather.

    18.
    发明专利
    未知

    公开(公告)号:DE3310270A1

    公开(公告)日:1984-09-27

    申请号:DE3310270

    申请日:1983-03-22

    Applicant: BASF AG

    Abstract: The invention relates to basic chromium aluminum sulfates which are soluble in cold water and are of the general formula CrxAl2-x(OH)2y. (SO4)3-y.n H2O where x is from 0.1 to 1.9, y is from 0.01 to 2 and n is from 4 to 24, and a process for the preparation thereof. The process comprises reacting chromium (III)-containing waste sulfuric acid having a water content of 20-50% by weight with aluminum oxide and/or aluminum oxide hydroxide and/or aluminum hydroxide at a temperature of 100 DEG to 200 DEG C. The molten product is converted to droplet form and allowed to solidify in free fall.

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