1.
    发明专利
    未知

    公开(公告)号:ES2070362T3

    公开(公告)日:1995-06-01

    申请号:ES91107074

    申请日:1991-05-02

    Applicant: BASF AG

    Abstract: Products of the condensation of phenolmonosulfonic acids, dihydroxydiphenyl sulfones, urea and formaldehyde can be obtained by (A) preparing a homogeneous reaction mixture in sulfuric acid from the phenolmonosulfonic acid and dihydroxydiphenyl sulfone in the molar ratio of from 3:1 to 10:1, with the proviso that the water content of the mixture is not more than 10% of the total weight of the components, and the mixture contains from 0.3 to 1.5 moles of sulfuric acid per mole of dihydroxydiphenyl sulfone, at from 100 DEG to 180 DEG C., (B) subsequently, at from 40 DEG to 90 DEG C., carrying out a precondensation with 1 to 2 moles of formaldehyde and 0.5 to 1.5 moles of urea per mole of phenol units present in aqueous medium, (C) partially neutralizing the reaction mixture, (D) adding to the partially neutralized reaction mixture 0 to 0.5 mole of phenol per mole of phenol units present and then 0.1 to 0.8 mole of formaldehyde per mole of phenol units then present, (E) further condensing at from 40 DEG to 90 DEG C., (F) shifting the pH of the reaction mixture into the neutral range and (G) subsequently acidifying with a weak acid.

    2.
    发明专利
    未知

    公开(公告)号:DE59008123D1

    公开(公告)日:1995-02-09

    申请号:DE59008123

    申请日:1990-09-06

    Applicant: BASF AG

    Abstract: Use of copolymers that contain as copolymerised units …… a) from 50 to 90 % by weight of C8-C40-alkyl (meth)acrylates, vinyl esters of C8-C40-carboxylic acids or mixtures thereof and … b) from 10 to 50 % by weight of monoethylenically unsaturated C3-C12-carboxylic acids, monoethylenically unsaturated dicarboxylic anhydrides, monoesters or monoamides of monoethylenically unsaturated C4-C12-dicarboxylic acids, amides of C3-C12-monocarboxylic acids or mixtures thereof and have molecular weights of from 500 to 30,000 g per mole, in at least partially neutralised form in aqueous solution or in aqueous dispersion for waterproofing leathers and fur pelts. …

    9.
    发明专利
    未知

    公开(公告)号:DE59105078D1

    公开(公告)日:1995-05-11

    申请号:DE59105078

    申请日:1991-05-02

    Applicant: BASF AG

    Abstract: Products of the condensation of phenolmonosulfonic acids, dihydroxydiphenyl sulfones, urea and formaldehyde can be obtained by (A) preparing a homogeneous reaction mixture in sulfuric acid from the phenolmonosulfonic acid and dihydroxydiphenyl sulfone in the molar ratio of from 3:1 to 10:1, with the proviso that the water content of the mixture is not more than 10% of the total weight of the components, and the mixture contains from 0.3 to 1.5 moles of sulfuric acid per mole of dihydroxydiphenyl sulfone, at from 100 DEG to 180 DEG C., (B) subsequently, at from 40 DEG to 90 DEG C., carrying out a precondensation with 1 to 2 moles of formaldehyde and 0.5 to 1.5 moles of urea per mole of phenol units present in aqueous medium, (C) partially neutralizing the reaction mixture, (D) adding to the partially neutralized reaction mixture 0 to 0.5 mole of phenol per mole of phenol units present and then 0.1 to 0.8 mole of formaldehyde per mole of phenol units then present, (E) further condensing at from 40 DEG to 90 DEG C., (F) shifting the pH of the reaction mixture into the neutral range and (G) subsequently acidifying with a weak acid.

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