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公开(公告)号:BR0213108A
公开(公告)日:2004-09-21
申请号:BR0213108
申请日:2002-10-04
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , BAUMANN ROBERT , KUNSMANN-KEITEL DAGMAR PASCALE , HADERLEIN GERD , JUNGKAMP TIM , ALMAYER MARCO , SIEGEL WOLFGANG , MOLNAR FERENC
IPC: B01J31/22 , B01J31/18 , C07B61/00 , C07C253/10 , C07C253/30 , C07C255/04 , C07C255/07 , C07F9/46 , C07F15/04 , C07F9/50
Abstract: Phosphinites I of the formula 1, 2 or 3 where R1, R2, R4 are each, independently of one another, hydrogen, an alkyl or alkylene group having from 1 to 8 carbon atoms or an alkoxy group having from 1 to 8 carbon atoms, with the proviso that at least one of the groups R1, R2, R4 is not H, R3 is H or methyl X is F, Cl or CF 3 n is 0, 1 or 2 can be used as catalysts.
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公开(公告)号:DE10211386A1
公开(公告)日:2003-09-25
申请号:DE10211386
申请日:2002-03-14
Applicant: BASF AG
Inventor: MIHAN SHAHRAM , MOLNAR FERENC , MAAS HEIKO , PRINZ MARTINA , KOEHN RANDOLF
IPC: B01J31/22 , B01J23/26 , B01J31/12 , B01J31/14 , B01J31/18 , C07B61/00 , C07C2/32 , C07C11/02 , C07C11/107 , C08F4/69 , C08F10/00 , C07C2/08 , B01J37/00
Abstract: Disclosed is a method for the oligomerization of olefins, wherein an olefin is brought into contact with a catalyst system that is obtained from a chromium source, a cycloalkylalkyl-substituted triazacyclohexane, especially a 1,3,5-tris-(cycloalkylalkyl)-1,3,5-triazacyclohexane and an activator such as an alkyl aluminum compound or an alkylalumoxane.
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公开(公告)号:DE10150286A1
公开(公告)日:2003-04-17
申请号:DE10150286
申请日:2001-10-12
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , BAUMANN ROBERT , KUNSMANN-KEITEL DAGMAR PASCA , HADERLEIN GERD , JUNGKAMP TIM , ALTMAYER MARCO , SIEGEL WOLFGANG , MOLNAR FERENC
IPC: B01J31/22 , B01J31/18 , C07B61/00 , C07C253/10 , C07C253/30 , C07C255/04 , C07C255/07 , C07F9/46 , C07F15/04 , C07C255/06 , B01J31/12
Abstract: Bisphosphinites (I) are new. Bisphosphinites of formula (Ar)2P-O-Q-O-O(Ar)2 (I) are new; Ar = phenyl substituted with 0-2 of F, Cl or CF3; Q = a group of formula (i)-(iii). Independent claims are also included for: (1) transition metal complexes of (I); (2) production of transition metal complexes of (I) by reacting a transition metal or transition metal compound with (I); (3) addition of hydrogen cyanide to an olefinic double bond in the presence of a catalyst which is a complex as above; (4) isomerization of organic nitriles in the presence of a catalyst which is a complex as above. R , R , R = H, 1-8C alkyl, 2-8C alkenyl or 1-8C alkoxy, but not all H; R = H or Me.
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公开(公告)号:AT360481T
公开(公告)日:2007-05-15
申请号:AT02801302
申请日:2002-10-01
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , BAUMANN ROBERT , KUNSMANN-KEITEL DAGMAR PASCALE , HADERLEIN GERD , JUNGKAMP TIM , ALTMAYER MARCO , SIEGEL WOLFGANG , MOLNAR FERENC
IPC: B01J31/22 , B01J31/18 , C07B61/00 , C07C253/10 , C07C253/30 , C07C255/04 , C07C255/07 , C07F9/48
Abstract: Phosphonites I of the formula 1 or 2 where R1, R2 are each, independently of one another, hydrogen, an alkyl or alkylene group having from 1 to 8 carbon atoms or an alkoxy group having from 1 to 8 carbon atoms, with the proviso that R1 and R2 are not simultaneously H, R3 is H or methyl, R4 is t-butyl, R5, R6, R7, R8, R9 are each, independently of one another, H or an alkyl or alkylene group having from 1 to 8 carbon atoms.
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公开(公告)号:DE50207332D1
公开(公告)日:2006-08-03
申请号:DE50207332
申请日:2002-10-04
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , BAUMANN ROBERT , KUNSMANN-KEITEL PASCALE , HADERLEIN GERD , JUNGKAMP TIM , ALTMAYER MARCO , SIEGEL WOLFGANG , MOLNAR FERENC
IPC: B01J31/22 , C07F9/48 , B01J31/18 , C07B61/00 , C07C253/10 , C07C253/30 , C07C255/04 , C07C255/07
Abstract: The invention relates to phosphinites I of formulae (1) or (2), in which R1, R2, R5, R6, R7, R8, R9 independently represent hydrogen, an alkyl or alkylene group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms; R3 is H or methyl; R4 is i-propyl or t-butyl; X is F, Cl or CF 3 and n is 1 or 2.
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公开(公告)号:BRPI0408722A
公开(公告)日:2006-03-07
申请号:BRPI0408722
申请日:2004-03-24
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , BAUMANN ROBERT , HADERLEIN GERD , FLORES MIGUEL ANGEL , JUNGKAMP TIM , LUYKEN HERMANN , SCHEIDEL JEAN , SIEGEL WOLFGANG , MOLNAR FERENC
IPC: B01J23/755 , B01J31/02 , B01J31/14 , B01J31/18 , C07C253/10 , C07C255/04 , B01J27/14 , B01J27/18
Abstract: A system which is suitable as a catalyst for the hydrocyanation of olefinically unsaturated compounds and comprises a) Ni(0) b) a compound which complexes Ni(0) as a ligand and contains trivalent phosphorus, c) a Lewis acid and d) a compound of the formula M Rn where M: Al or Ti R: identical or different monovalent alkoxy radicals, in which case a plurality of alkoxy radicals may be bonded together, and additionally, in the case that M=Al, R may be identical or different monovalent alkyl radicals, in which case a plurality of alkyl radicals may be bonded together or one or more alkyl radicals may be bonded to one or more of the abovementioned alkoxy radicals, n: valency of M, and processes for hydrocyanating an olefinically unsaturated compound in the presence of such a system.
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公开(公告)号:DE10150285A1
公开(公告)日:2003-04-17
申请号:DE10150285
申请日:2001-10-12
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , BAUMANN ROBERT , KUNSMANN-KEITEL DAGMAR PASCA , HADERLEIN GERD , JUNGKAMP TIM , ALTMAYER MARCO , SIEGEL WOLFGANG , MOLNAR FERENC
IPC: B01J31/22 , B01J31/18 , C07B61/00 , C07C253/10 , C07C253/30 , C07C255/04 , C07C255/07 , C07F9/48 , C07F15/04 , C07C255/06 , B01J31/12
Abstract: Bisphosphonites (I) are new. Bisphosphonites of formula (I) are new; R , R = H, 1-8C alkyl, 2-8C alkenyl or 1-8C alkoxy, but not both H; R = H or Me; R = t-Bu; R -R = H, 1-8C alkyl or 2-8C alkenyl; alternatively, R +R = CH=CH-CHR=CH; R = H, 1-8C alkyl, 2-8C alkenyl or 1-8C alkoxy; R = H. Independent claims are also included for: (1) transition metal complexes of (I); (2) production of transition metal complexes of (I) by reacting a transition metal or transition metal compound with (I); (3) addition of hydrogen cyanide to an olefinic double bond in the presence of a catalyst which is a complex as above; (4) isomerization of organic nitriles in the presence of a catalyst which is a complex as above.
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公开(公告)号:PL1610893T3
公开(公告)日:2007-07-31
申请号:PL04722843
申请日:2004-03-24
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , BAUMANN ROBERT , HADERLEIN GERD , FLORES MIGUEL ANGEL , JUNGKAMP TIM , LUYKEN HERMANN , SCHEIDEL JENS , SIEGEL WOLFGANG , MOLNAR FERENC
IPC: B01J27/14 , B01J23/755 , B01J31/02 , B01J31/14 , B01J31/18 , C07C253/10 , C07C255/04
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公开(公告)号:BR0212966A
公开(公告)日:2004-10-13
申请号:BR0212966
申请日:2002-10-01
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , BAUMANN ROBERT , KUNSMANN-KEITEL DAGMAR PASCALE , HADERLEIN GERD , JUNGKAMP TIM , ALTMAYER MARCO , SIEGEL WOLFGANG , MOLNAR FERENC
IPC: B01J31/22 , B01J31/18 , C07B61/00 , C07C253/10 , C07C253/30 , C07C255/04 , C07C255/07 , C07F9/48
Abstract: Phosphonites I of the formula 1 or 2 where R1, R2 are each, independently of one another, hydrogen, an alkyl or alkylene group having from 1 to 8 carbon atoms or an alkoxy group having from 1 to 8 carbon atoms, with the proviso that R1 and R2 are not simultaneously H, R3 is H or methyl, R4 is t-butyl, R5, R6, R7, R8, R9 are each, independently of one another, H or an alkyl or alkylene group having from 1 to 8 carbon atoms.
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公开(公告)号:CA2462720A1
公开(公告)日:2003-04-24
申请号:CA2462720
申请日:2002-10-04
Applicant: BASF AG
Inventor: HADERLEIN GERD , SIEGEL WOLFGANG , JUNGKAMP TIM , ALTMAYER MARCO , MOLNAR FERENC , KUNSMANN-KEITEL DAGMAR PASCALE , BAUMANN ROBERT , BARTSCH MICHAEL
IPC: B01J31/22 , B01J31/18 , C07B61/00 , C07C253/10 , C07C253/30 , C07C255/04 , C07C255/07 , C07F9/46 , C07F15/04 , C07F9/50
Abstract: The invention relates to phosphinites I of formulae (1) or (2) or (3) and mixtures thereof, in which Rl, R2, R4 independently represent hydrogen, an alkyl or alkylene group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms, provided that at least one of the groups Rl, R2, R4 is different from H; R3 is H or methyl; X is F, Cl or CF3 and n is 0, 1 or 2.
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