公开(公告)号：WO2005019373A3

公开(公告)日：2005-05-19

申请号：PCT/EP2004009269

申请日：2004-08-18

Applicant: BASF AG ,  BOLD MARKUS ,  LENNARTZ CHRISTIAN ,  PRINZ MARTINA ,  SCHMIDT HANS-WERNER ,  THELAKKAT MUKUNDAN ,  BAETE MARKUS ,  NEUBER CHRISTIAN ,  KOWALSKY WOLFGANG ,  SCHILDKNECHT CHRISTIAN ,  JOHANNES HANS-HERMANN

Inventor： BOLD MARKUS ,  LENNARTZ CHRISTIAN ,  PRINZ MARTINA ,  SCHMIDT HANS-WERNER ,  THELAKKAT MUKUNDAN ,  BAETE MARKUS ,  NEUBER CHRISTIAN ,  KOWALSKY WOLFGANG ,  SCHILDKNECHT CHRISTIAN ,  JOHANNES HANS-HERMANN

IPC: B01J31/22 ,  C07F15/00 ,  C09K11/06 ,  H01L51/00 ,  H01L51/50

CPC classification number: H01L51/0085 ,  B01J31/2265 ,  B01J31/2273 ,  B01J2531/16 ,  B01J2531/17 ,  B01J2531/18 ,  B01J2531/57 ,  B01J2531/60 ,  B01J2531/70 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/827 ,  B01J2531/828 ,  C07F15/0033 ,  C09B57/00 ,  C09B57/10 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1018 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/18 ,  C09K2211/185 ,  H01L51/0081 ,  H01L51/5016 ,  H01L51/5096 ,  Y02P20/582

Abstract: The invention relates to the use of transition metal complexes of formula (I) in organic light-emitting diodes, wherein: M represents a metal atom; carbene represents a carbene ligand; L represents a monoanionic or dianionic ligand; K represents a neutral monodentate or bidentate ligand selected from the group consisting of phosphines, CO, pyridines, nitriles and of conjugated dienes that form a pi-complex with M ; n represents a number of carbene ligands, whereby n is at least 1; m represents a number of ligands L, whereby m can be 0 or = 1; o represents a number of ligands K, whereby o can be 0 or = 1, and the sum n + m + o depends on the oxidation stage and coordination number of the metal atom used and on the dentation of the ligands carbene, L and K as well as on the charge of the ligands carbene and L, with the condition that n is at least 1. The invention also relates to an OLED containing these transition metal complexes, a light-emitting layer containing these transition metal complexes, OLED's containing this light-emitting layer, devices that contain an inventive OLED, and to special transition metal complexes containing at least two carbene ligands.

Abstract translation: 式（I）中的有机发光二极管，其特征在于，过渡金属配合物的用途：M <1>金属原子; 卡宾碳烯配体; L是单 - 或双阴离子配位体; K是不带电的单 - 或选自膦组成的组中的二齿配体; CO; 吡啶; 腈和共轭二烯构成的pI络合物其中M <1>; 碳烯配体，其中n是至少为1的n个; 中号配位体L，其中m可以是数字0或> = 1; o是配体K，其中，o可以是0或> = 1的数量; 其中在所述电荷的配位体和L中的配位体L和K和卡宾的齿合度使用的金属原子的和的氧化态和配位数的n + m之+ O卡宾是相关的，其条件是n为至少1，和 的OLED包含这些过渡金属络合物，一个发光层，其包含这些过渡金属络合物，有机发光二极管，其包括这些发光层，含有本发明的OLED，以及包含至少两个碳烯配体的特殊的过渡金属配合物的设备。

公开(公告)号：WO2004035530A3

公开(公告)日：2004-06-10

申请号：PCT/EP0311378

申请日：2003-10-14

Applicant: BASF AG ,  STEINBRENNER ULRICH ,  HEIDEMANN THOMAS ,  NARBESHUBER THOMAS ,  MAAS HEIKO ,  PRINZ MARTINA ,  BOTTKE NILS ,  TROPSCH JUERGEN ,  BENFER REGINA ,  FUNKE FRANK ,  STEPHAN JUERGEN

Inventor： STEINBRENNER ULRICH ,  HEIDEMANN THOMAS ,  NARBESHUBER THOMAS ,  MAAS HEIKO ,  PRINZ MARTINA ,  BOTTKE NILS ,  TROPSCH JUERGEN ,  BENFER REGINA ,  FUNKE FRANK ,  STEPHAN JUERGEN

IPC: C07C29/17 ,  C07C303/06 ,  C07C303/08 ,  C07C309/31 ,  C07C9/16 ,  C07C15/107 ,  C07C31/125 ,  C11D1/24

CPC classification number: C07C303/06 ,  C07C29/175 ,  C07C303/08 ,  C07C309/31 ,  C07C31/125

Abstract: The invention relates to a method for producing alkylaryl sulfonates, the alkylaryl sulfonates obtained according to said method, alcohol mixtures and olefin mixtures obtained as intermediate products, alkylaromatic compounds obtained therefrom, the use of said alkylaryl sulfonates as surfactants, and detergents containing said surfactants.

Abstract translation: 本发明涉及一种用于烷基芳基磺酸盐的制备方法，通过该方法获得和可作为烷基芳基磺酸盐中间体醇的混合物，以及由其烷基芳族化合物得到的烯烃混合物，使用烷基芳基磺酸盐表面活性剂和洗涤剂和含有它们的清洁剂。

公开(公告)号：AU2003294692A8

公开(公告)日：2004-05-04

申请号：AU2003294692

申请日：2003-10-14

Applicant: BASF AG

Inventor： NARBESHUBER THOMAS ,  BOTTKE NILS ,  PRINZ MARTINA ,  STEPHAN JURGEN ,  STEINBRENNER ULRICH ,  BENFER REGINA ,  MAAS HEIKO ,  HEIDEMANN THOMAS ,  FUNKE FRANK ,  TROPSCH JURGEN

IPC: C07C29/17 ,  C07C303/06 ,  C07C303/08 ,  C07C309/31 ,  C07C9/16 ,  C07C15/107 ,  C07C31/125 ,  C11D1/24

公开(公告)号：DE10211386A1

公开(公告)日：2003-09-25

申请号：DE10211386

申请日：2002-03-14

Applicant: BASF AG

Inventor： MIHAN SHAHRAM ,  MOLNAR FERENC ,  MAAS HEIKO ,  PRINZ MARTINA ,  KOEHN RANDOLF

IPC: B01J31/22 ,  B01J23/26 ,  B01J31/12 ,  B01J31/14 ,  B01J31/18 ,  C07B61/00 ,  C07C2/32 ,  C07C11/02 ,  C07C11/107 ,  C08F4/69 ,  C08F10/00 ,  C07C2/08 ,  B01J37/00

Abstract: Disclosed is a method for the oligomerization of olefins, wherein an olefin is brought into contact with a catalyst system that is obtained from a chromium source, a cycloalkylalkyl-substituted triazacyclohexane, especially a 1,3,5-tris-(cycloalkylalkyl)-1,3,5-triazacyclohexane and an activator such as an alkyl aluminum compound or an alkylalumoxane.

公开(公告)号：AU2003294692A1

公开(公告)日：2004-05-04

申请号：AU2003294692

申请日：2003-10-14

Applicant: BASF AG

Inventor： STEINBRENNER ULRICH ,  HEIDEMANN THOMAS ,  NARBESHUBER THOMAS ,  MAAS HEIKO ,  PRINZ MARTINA ,  BOTTKE NILS ,  TROPSCH JURGEN ,  BENFER REGINA ,  FUNKE FRANK ,  STEPHAN JURGEN

IPC: C07C29/17 ,  C07C303/06 ,  C07C303/08 ,  C07C309/31 ,  C07C303/00

公开(公告)号：AU2003227586A1

公开(公告)日：2003-10-20

申请号：AU2003227586

申请日：2003-04-09

Applicant: BASF AG

Inventor： MIHAN SHAHRAM ,  MAAS HEIKO ,  PRINZ MARTINA

IPC: C07C2/06 ,  C07B61/00 ,  C07C2/32 ,  C07C11/02

Abstract: Olefins are oligomerized by contacting an olefin with a catalyst system that is comprised of a) at least one transition metal complex that is complexed with a polydentate complexing ligand and b) an alkylaluminoxane, each component being present in such amounts that the molar ratio of aluminum transition metal is greater than 10, wherein at least part of the amount of the transition metal complex is added continuously or in portions during the oligomerization.

公开(公告)号：AU2003208874A1

公开(公告)日：2003-09-09

申请号：AU2003208874

申请日：2003-02-19

Applicant: BASF AG

Inventor： ROPER MICHAEL ,  STEPHAN JURGEN ,  SCHINDLER GOTZ-PETER ,  TROPSCH JURGEN ,  HEIDEMANN THOMAS ,  PRINZ MARTINA ,  ZIMDAHL SOEREN

IPC: C07B61/00 ,  C07C2/00 ,  C07C2/06 ,  C07C2/10 ,  C07C6/04 ,  C07C11/02 ,  C07C11/107 ,  C07C29/141 ,  C07C29/16 ,  C07C31/125 ,  C07C41/03 ,  C07C45/50 ,  C07C47/21 ,  C07C29/03

Abstract: Production of surfactant alcohols or their ethers by derivatization of 10-20C olefins or mixtures, comprises: (i) metathesizing a 4C olefin mixture; (ii) removing the 5-8C olefins; (iii) dimerizing the separated olefins to a 10-16C olefin mixture; (iv) derivatizing the mixture to a mixture of surfactant alcohols; and optionally (v) alkoxylating the alcohols. Production of surfactant alcohols or their ethers by derivatization of 10-20C olefins or mixtures, comprises: (i) metathesizing a 4C olefin mixture of 1-butene/2-butene ratio at least 1.2; (ii) removing the 5-8C olefins; (iii) dimerizing the separated olefins (optionally in admixture) to a 10-16C olefin mixture; (iv) derivatizing the mixture to a mixture of surfactant alcohols (optionally after fractionation); and optionally (v) alkoxylating the alcohols. Independent claims are also included for: (1) the novel olefin mixtures obtained by steps (i) - (iii) above; and (2) the novel surfactant alcohols and their alkoxylates obtained by steps (i) - (iv) and optionally also step (v) above.

公开(公告)号：DE10206845A1

公开(公告)日：2003-08-28

申请号：DE10206845

申请日：2002-02-19

Applicant: BASF AG

Inventor： ROEPER MICHAEL ,  STEPHAN JUERGEN ,  SCHINDLER GOETZ-PETER ,  TROPSCH JUERGEN ,  HEIDEMANN THOMAS ,  PRINZ MARTINA

IPC: C07B61/00 ,  C07C2/00 ,  C07C2/06 ,  C07C2/10 ,  C07C6/04 ,  C07C11/02 ,  C07C11/107 ,  C07C29/141 ,  C07C29/16 ,  C07C31/125 ,  C07C41/03 ,  C07C45/50 ,  C07C47/21 ,  C07C29/00 ,  C11D1/12 ,  C07H15/04 ,  C08B37/00 ,  C07C303/24 ,  C07F9/09

Abstract: Production of surfactant alcohols or their ethers by derivatization of 10-20C olefins or mixtures, comprises: (i) metathesizing a 4C olefin mixture; (ii) removing the 5-8C olefins; (iii) dimerizing the separated olefins to a 10-16C olefin mixture; (iv) derivatizing the mixture to a mixture of surfactant alcohols; and optionally (v) alkoxylating the alcohols. Production of surfactant alcohols or their ethers by derivatization of 10-20C olefins or mixtures, comprises: (i) metathesizing a 4C olefin mixture of 1-butene/2-butene ratio at least 1.2; (ii) removing the 5-8C olefins; (iii) dimerizing the separated olefins (optionally in admixture) to a 10-16C olefin mixture; (iv) derivatizing the mixture to a mixture of surfactant alcohols (optionally after fractionation); and optionally (v) alkoxylating the alcohols. Independent claims are also included for: (1) the novel olefin mixtures obtained by steps (i) - (iii) above; and (2) the novel surfactant alcohols and their alkoxylates obtained by steps (i) - (iv) and optionally also step (v) above.

公开(公告)号：DE10248002A1

公开(公告)日：2004-04-29

申请号：DE10248002

申请日：2002-10-15

Applicant: BASF AG

Inventor： STEINBRENNER ULRICH ,  HEIDEMANN THOMAS ,  NARBESHUBER THOMAS ,  MAAS HEIKO ,  PRINZ MARTINA ,  BOTTKE NILS ,  TROPSCH JUERGEN ,  BENFER REGINA ,  FUNKE FRANK ,  STEPHAN JUERGEN

IPC: C07C29/17 ,  C07C303/06 ,  C07C303/08 ,  C07C309/31 ,  C07C2/06 ,  C07C2/66 ,  C07C2/86 ,  C07C6/04 ,  C11D1/22

公开(公告)号：DE10215754A1

公开(公告)日：2003-10-30

申请号：DE10215754

申请日：2002-04-10

Applicant: BASF AG

Inventor： SHAHRAM MIHAN ,  MAAS HEIKO ,  PRINZ MARTINA

IPC: C07C2/06 ,  C07B61/00 ,  C07C2/32 ,  C07C11/02 ,  C07C2/58 ,  B01J31/12

Abstract: Olefins are oligomerized by contacting an olefin with a catalyst system that is comprised of a) at least one transition metal complex that is complexed with a polydentate complexing ligand and b) an alkylaluminoxane, each component being present in such amounts that the molar ratio of aluminum transition metal is greater than 10, wherein at least part of the amount of the transition metal complex is added continuously or in portions during the oligomerization.