16.
    发明专利
    未知

    公开(公告)号:DE4106909A1

    公开(公告)日:1992-09-10

    申请号:DE4106909

    申请日:1991-03-05

    Applicant: BASF AG

    Abstract: The invention relates to graft copolymers obtainable by …… A) Emulsion polymerisation of from 5 to 35% by weight of a monomer mixture comprising …… a1) 60-80% by weight of at least one vinyl aromatic monomer, … a2) 20-40% by weight of at least one ethylenically unsaturated nitrile … a3) 0-10% by weight of at least one di- or polyethylenically unsaturated monomer, … and … B) subsequent emulsion polymerisation, in the presence of the emulsion polymer obtained from step A), of 20-45% by weight of a monomer mixture comprising …… b1) 50-75% by weight of at least one vinyl aromatic monomer, … b2) 25-50% by weight of at least one C1-C18-alkyl acrylate … b3) 0-10% by weight of at least one di- or polyethylenically unsaturated monomer, … and … C) subsequent emulsion polymerisation, in the presence of the emulsion polymer obtained in step B), of 5-35% by weight of a monomer mixture comprising …… c1) 60-80% by weight of at least one vinyl aromatic monomer, … c2) 20-40% by weight of at least one ethylenically unsaturated nitrile … c3) 0-10% by weight of at least one di- or polyethylenically unsaturated monomer, … and … D) subsequent emulsion polymerisation, in the presence of the emulsion polymer obtained in Step C), of 15-45% by weight of a monomer mixture comprising …… d1) 80-99.9% by weight of at least one C1-C18-alkyl acrylate, … d2) 0.1-10% by weight of at least one di- or polyethylenically unsaturated monomer. ……

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