公开(公告)号：AU2003253356A1

公开(公告)日：2004-03-19

申请号：AU2003253356

申请日：2003-07-30

Applicant: BASF AG

Inventor： LENZ ROBERT ,  ADAMI CHRISTOPH ,  KARL JORN ,  HAUK ALEXANDER ,  BOHLING RALF ,  PASTRE JORG

IPC: A23K1/16 ,  A01N1/00 ,  A01N3/00 ,  A61K31/19 ,  A61P3/00 ,  B01D9/02 ,  C07C51/09 ,  C07C51/41 ,  C07C53/06 ,  C07C53/02

Abstract: Formic acid-formates are produced by (a) partial hydrolysis of methyl formate (MF) with water, (b) distillation to give (S1) formic acid and water, (c) conversion of the other product from (b) (mainly MF) into a stream (S2) containing formate and water by reaction with aqueous strong base and distillation of methanol, and (d) combination of (S1) with (S2). A method for the production of formic acid-formates (I) involves: (a) partial hydrolysis of methyl formate (MF) with water; (b) distillation to give a stream (S1) containing formic acid and water; (c) conversion of the MF- and possibly methanol-containing stream from (b) into a formate- and water-containing stream (S2) by (i) reaction with a basic compound of an acid with a pKa value of at least 3 in presence of water followed by (ii) removal of methanol by distillation; and (d) combination of streams (S1) and (S2). An Independent claim is also included for apparatus for the production of (I), comprising: (A) a reactor for the hydrolysis of MF; (B) a distillation column for separating a stream containing MF, formic acid, methanol and water; (C) a column for the hydrolysis of MF with a basic compound with removal of methanol by distillation (with an inlet for the base above the inlet for the product from (B)); and (D) a column connected to the bottom of (B) for removing water from the stream containing formic acid and water.

公开(公告)号：NO328392B1

公开(公告)日：2010-02-08

申请号：NO20040560

申请日：2004-02-06

Applicant: BASF AG

Inventor： ZEHNER PETER ,  PASTRE JORG ,  STUEER WOLFRAM

IPC: C07C27/02 ,  C07C51/09 ,  C07C27/00 ,  C07C45/41 ,  C07C45/46 ,  C07C45/89 ,  C07C49/90 ,  C07C51/083 ,  C07C51/56 ,  C07C53/02 ,  C07C53/08 ,  C07C67/00 ,  C07C67/08 ,  C07C67/10 ,  C07C67/297 ,  C07C69/14 ,  C07C69/15

Abstract: Joint production of formic acid with a \- 2C carboxylic acid (or derivative) involves transesterifying a formic ester (I) with a \- 2C carboxylic acid (II) to give formic acid (III) and the corresponding carboxylic acid ester (IV), and carbonylating part of (IV) to the corresponding carboxylic acid anhydride (V).

公开(公告)号：BRPI0514677A

公开(公告)日：2008-06-17

申请号：BRPI0514677

申请日：2005-09-02

Applicant: BASF AG

Inventor： BECKER STEFAN ,  PASTRE JORG ,  PAKUSCH JOACHIM ,  GOTZ THOMAS ,  BUREK ARNOLD ,  HANSCH WOLFGANG ,  SPILGER STEFANIE

IPC: C08F290/06 ,  C07C69/54

Abstract: A process for preparing poly-C2-C4-alkylene glycol mono(meth)acrylic acid esters by reacting (meth)acrylic anhydride with a poly-C2-C4-alkylene glycol carrying at least one OH group in the presence of abase having a solubility in the poly-C2-C4-alkylene glycol of not more than 10 g/l at 90° C.

公开(公告)号：NO20050534L

公开(公告)日：2005-03-02

申请号：NO20050534

申请日：2005-01-31

Applicant: BASF AG

Inventor： PASTRE JORG ,  KARL JORN ,  ADAMI CHRISTOPH ,  HAUK ALEXANDER ,  LENZ ROBERT ,  BOHLING RALF

IPC: C07C51/09 ,  C07C51/43 ,  C07C51/44 ,  A23K3/03

Abstract: A method for the production of formic acid-formates (I) involves (a) partial hydrolysis of methyl formate (MF) with water, (b) distillation to give formic acid and water (stream S1) and (c) combination of (S1) with the corresponding formate (F) to give a mixture of (I) and water. An Independent claim is also included for apparatus for the production of (I), comprising a reactor (A) for the hydrolysis of MF, a distillation column (B) for separating a stream containing MF, formic acid, methanol and water into MF, methanol and a stream (S1) containing formic acid and water, and a column (E) for removing water from S1.

公开(公告)号：NO20050538A

公开(公告)日：2005-02-28

申请号：NO20050538

申请日：2005-01-31

Applicant: BASF AG

Inventor： PASTRE JORG ,  KARL JORN ,  ADAMI CHRISTOPH ,  HAUK ALEXANDER ,  LENZ ROBERT ,  BOHLING RALF

IPC: A23K1/16 ,  A01N1/00 ,  A01N3/00 ,  A61K31/19 ,  A61P3/00 ,  B01D9/02 ,  C07C51/09 ,  C07C51/41 ,  C07C53/06 ,  C07C53/02

CPC classification number: C07C51/412 ,  C07C53/06

公开(公告)号：AU2003278114A1

公开(公告)日：2004-05-13

申请号：AU2003278114

申请日：2003-10-21

Applicant: BASF AG

Inventor： PASTRE JORG ,  EXNER KAI MICHAEL ,  STUER WOLFRAM ,  GEISSLER ELKE ,  MACHHAMMER OTTO

IPC: C07C51/09 ,  C07C51/54 ,  C07C51/56 ,  C07C67/10 ,  C07C53/122 ,  C07C53/124 ,  C07C63/313 ,  C07C53/02 ,  C07C69/14 ,  C07C53/12

Abstract: Disclosed is a method for jointly producing (i) formic acid (III); (ii) a carboxylic acid comprising at least two carbon atoms (II) and/or the derivatives thereof; and (iii) a carboxylic acid anhydride (VII). According to said method, (a) a formic acid ester (I) is transesterfied to formic acid (III) and the corresponding carboxylic acid ester (IV) by means of a carboxylic acid comprising at least two carbon atoms (II); (b) at least one portion of the carboxylic acid ester (IV) formed in step (a) is carbonylated in order to obtain the carboxylic acid anhydride (V); and (c) at least one portion of the carboxylic acid anhydride (V) formed in step (b) is further dehydrated by means of a carboxylic acid (VI) so as to form a carboxylic acid anhydride (VII) and the carboxylic acid (II).