公开(公告)号：AU5334396A

公开(公告)日：1996-10-30

申请号：AU5334396

申请日：1996-03-25

Applicant: BASF AG

Inventor： MULLER RUTH ,  REMY BENOIT ,  BAYER HERBERT ,  GOTZ NORBERT ,  SAUTER HUBERT

IPC: C07D231/12 ,  C07B61/00 ,  C07C249/04 ,  C07C249/12 ,  C07C249/14 ,  C07C251/38 ,  C07C251/48 ,  C07C255/62 ,  C07D261/08

Abstract: PCT No. PCT/EP96/01306 Sec. 371 Date Oct. 7, 1997 Sec. 102(e) Date Oct. 7, 1997 PCT Filed Mar. 25, 1996 PCT Pub. No. WO96/32373 PCT Pub. Date Oct. 17, 1996A process for the preparation of largely isomerically pure alpha -bisoximes of the formula IaR1O-N=CR2-CR3=N-OR4Iawhere the groups R1O- and R2 on the N=C bond are cis to one another and where the radicals have the following meanings: R1 and R4 are hydrogen or a C-organic radical; R2 is hydrogen, cyano, nitro, hydroxyl, amino, halogen or an organic radical which can be bonded to the structure directly or via an oxygen, sulfur or nitrogen atom; R3 is hydrogen, cyano, nitro, hydroxyl, amino, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylamino, dialkylamino or cycloalkyl, from a mixture of the isomers of the a-bisoximes Ia and Ib is described.

公开(公告)号：AT201196T

公开(公告)日：2001-06-15

申请号：AT96910014

申请日：1996-03-25

Applicant: BASF AG

Inventor： MUELLER RUTH ,  REMY BENOIT ,  BAYER HERBERT ,  GOETZ NORBERT ,  SAUTER HUBERT

IPC: C07D231/12 ,  C07B61/00 ,  C07C249/04 ,  C07C249/12 ,  C07C249/14 ,  C07C251/38 ,  C07C251/48 ,  C07C255/62 ,  C07D261/08

Abstract: PCT No. PCT/EP96/01306 Sec. 371 Date Oct. 7, 1997 Sec. 102(e) Date Oct. 7, 1997 PCT Filed Mar. 25, 1996 PCT Pub. No. WO96/32373 PCT Pub. Date Oct. 17, 1996A process for the preparation of largely isomerically pure alpha -bisoximes of the formula IaR1O-N=CR2-CR3=N-OR4Iawhere the groups R1O- and R2 on the N=C bond are cis to one another and where the radicals have the following meanings: R1 and R4 are hydrogen or a C-organic radical; R2 is hydrogen, cyano, nitro, hydroxyl, amino, halogen or an organic radical which can be bonded to the structure directly or via an oxygen, sulfur or nitrogen atom; R3 is hydrogen, cyano, nitro, hydroxyl, amino, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylamino, dialkylamino or cycloalkyl, from a mixture of the isomers of the a-bisoximes Ia and Ib is described.

公开(公告)号：EA000404B1

公开(公告)日：1999-06-24

申请号：EA199700300

申请日：1996-03-25

Applicant: BASF AG

Inventor： MULLER RUTH ,  REMY BENOIT ,  BAYER HERBERT ,  GOTZ NORBERT ,  SAURER HUBERT

IPC: C07B61/00 ,  C07C249/04 ,  C07D231/12 ,  C07C249/12 ,  C07C249/14 ,  C07C251/38 ,  C07C251/48 ,  C07C255/62 ,  C07D261/08

公开(公告)号：BG101939A

公开(公告)日：1998-09-30

申请号：BG10193997

申请日：1997-10-02

Applicant: BASF AG

Inventor： MUELLER RUTH ,  REMY BENOIT ,  BAYER HERBERT ,  GOETZ NORBERT ,  SAUTER HUBERT

IPC: C07D231/12 ,  C07B61/00 ,  C07C249/04 ,  C07C249/12 ,  C07C249/14 ,  C07C251/38 ,  C07C251/48 ,  C07C255/62 ,  C07D261/08

Abstract: The invention relates to a method for the preparation ofconsiderably pure isomers of -bis-oximes having the formulaR10-N=CR2-CR3=N-Or4ciswhere groups R10- and R2 in the N=C- bond are found incis-position towards each other and the residues in them have thefollowing meanings: R1 & R4 mean hydrogen or C-organic residue, R2is hydrogen, cyano, nitro, hydroxy, amino, halogen or organicresidue which can be bound directly or by oxygen, sulphur ornitrogen atom to the carbon chain, R3 is hydrogen, cyano, nitro,hydroxy, amino, halogen, alkyl, halogenalkyl, alkoxy,halogenalkoxy, alkylthio, alkylamino, dialkylamino or cycloalkyl.The compounds are produced form a mixture of the isomers of-bis-oximes with formula Ia and with formulaR10-N=CR2-CR3=N-OR4transwhich is treated in organic solvent with Lewis acid.12 claims

公开(公告)号：PL322690A1

公开(公告)日：1998-02-16

申请号：PL32269096

申请日：1996-03-25

Applicant: BASF AG

Inventor： MUELLER RUTH ,  REMY BENOIT ,  BAYER HERBERT ,  GOETZ NORBERT ,  SAUTER HUBERT

IPC: C07B61/00 ,  C07C249/04 ,  C07D231/12 ,  C07C249/12 ,  C07C249/14 ,  C07C251/38 ,  C07C251/48 ,  C07C255/62 ,  C07D261/08

Abstract: PCT No. PCT/EP96/01306 Sec. 371 Date Oct. 7, 1997 Sec. 102(e) Date Oct. 7, 1997 PCT Filed Mar. 25, 1996 PCT Pub. No. WO96/32373 PCT Pub. Date Oct. 17, 1996A process for the preparation of largely isomerically pure alpha -bisoximes of the formula IaR1O-N=CR2-CR3=N-OR4Iawhere the groups R1O- and R2 on the N=C bond are cis to one another and where the radicals have the following meanings: R1 and R4 are hydrogen or a C-organic radical; R2 is hydrogen, cyano, nitro, hydroxyl, amino, halogen or an organic radical which can be bonded to the structure directly or via an oxygen, sulfur or nitrogen atom; R3 is hydrogen, cyano, nitro, hydroxyl, amino, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylamino, dialkylamino or cycloalkyl, from a mixture of the isomers of the a-bisoximes Ia and Ib is described.

公开(公告)号：NO974635L

公开(公告)日：1997-10-07

申请号：NO974635

申请日：1997-10-07

Applicant: BASF AG

Inventor： MUELLER RUTH ,  REMY BENOIT ,  BAYER HERBERT ,  GOETZ NORBERT ,  SAUTER HUBERT

IPC: C07B61/00 ,  C07C249/04 ,  C07D231/12 ,  C07C249/12 ,  C07C249/14 ,  C07C251/38 ,  C07C251/48 ,  C07C255/62 ,  C07D261/08

Abstract: PCT No. PCT/EP96/01306 Sec. 371 Date Oct. 7, 1997 Sec. 102(e) Date Oct. 7, 1997 PCT Filed Mar. 25, 1996 PCT Pub. No. WO96/32373 PCT Pub. Date Oct. 17, 1996A process for the preparation of largely isomerically pure alpha -bisoximes of the formula IaR1O-N=CR2-CR3=N-OR4Iawhere the groups R1O- and R2 on the N=C bond are cis to one another and where the radicals have the following meanings: R1 and R4 are hydrogen or a C-organic radical; R2 is hydrogen, cyano, nitro, hydroxyl, amino, halogen or an organic radical which can be bonded to the structure directly or via an oxygen, sulfur or nitrogen atom; R3 is hydrogen, cyano, nitro, hydroxyl, amino, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylamino, dialkylamino or cycloalkyl, from a mixture of the isomers of the a-bisoximes Ia and Ib is described.

公开(公告)号：GR3036351T3

公开(公告)日：2001-11-30

申请号：GR20010401203

申请日：2001-08-08

Applicant: BASF AG

Inventor： MUELLER RUTH ,  REMY BENOIT ,  BAYER HERBERT ,  GOETZ NORBERT ,  SAUTER HUBERT

IPC: C07B61/00 ,  C07C249/04 ,  C07D231/12 ,  C07C249/12 ,  C07C249/14 ,  C07C251/38 ,  C07C251/48 ,  C07C255/62 ,  C07D261/08

Abstract: PCT No. PCT/EP96/01306 Sec. 371 Date Oct. 7, 1997 Sec. 102(e) Date Oct. 7, 1997 PCT Filed Mar. 25, 1996 PCT Pub. No. WO96/32373 PCT Pub. Date Oct. 17, 1996A process for the preparation of largely isomerically pure alpha -bisoximes of the formula IaR1O-N=CR2-CR3=N-OR4Iawhere the groups R1O- and R2 on the N=C bond are cis to one another and where the radicals have the following meanings: R1 and R4 are hydrogen or a C-organic radical; R2 is hydrogen, cyano, nitro, hydroxyl, amino, halogen or an organic radical which can be bonded to the structure directly or via an oxygen, sulfur or nitrogen atom; R3 is hydrogen, cyano, nitro, hydroxyl, amino, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylamino, dialkylamino or cycloalkyl, from a mixture of the isomers of the a-bisoximes Ia and Ib is described.

公开(公告)号：SK127097A3

公开(公告)日：1998-05-06

申请号：SK127097

申请日：1996-03-25

Applicant: BASF AG

Inventor： MULLER RUTH ,  REMY BENOIT ,  BAYER HERBERT ,  GOTZ NORBERT ,  SAUTER HUBERT

IPC: C07B61/00 ,  C07C249/04 ,  C07C249/12 ,  C07D231/12 ,  C07C249/14 ,  C07C251/38 ,  C07C251/48 ,  C07C255/62 ,  C07D261/08

Abstract: PCT No. PCT/EP96/01306 Sec. 371 Date Oct. 7, 1997 Sec. 102(e) Date Oct. 7, 1997 PCT Filed Mar. 25, 1996 PCT Pub. No. WO96/32373 PCT Pub. Date Oct. 17, 1996A process for the preparation of largely isomerically pure alpha -bisoximes of the formula IaR1O-N=CR2-CR3=N-OR4Iawhere the groups R1O- and R2 on the N=C bond are cis to one another and where the radicals have the following meanings: R1 and R4 are hydrogen or a C-organic radical; R2 is hydrogen, cyano, nitro, hydroxyl, amino, halogen or an organic radical which can be bonded to the structure directly or via an oxygen, sulfur or nitrogen atom; R3 is hydrogen, cyano, nitro, hydroxyl, amino, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylamino, dialkylamino or cycloalkyl, from a mixture of the isomers of the a-bisoximes Ia and Ib is described.

公开(公告)号：NO974635D0

公开(公告)日：1997-10-07

申请号：NO974635

申请日：1997-10-07

Applicant: BASF AG

Inventor： MUELLER RUTH ,  REMY BENOIT ,  BAYER HERBERT ,  GOETZ NORBERT ,  SAUTER HUBERT

IPC: C07B61/00 ,  C07C249/04 ,  C07D231/12 ,  C07C249/12 ,  C07C249/14 ,  C07C251/38 ,  C07C251/48 ,  C07C255/62 ,  C07D261/08

Abstract: PCT No. PCT/EP96/01306 Sec. 371 Date Oct. 7, 1997 Sec. 102(e) Date Oct. 7, 1997 PCT Filed Mar. 25, 1996 PCT Pub. No. WO96/32373 PCT Pub. Date Oct. 17, 1996A process for the preparation of largely isomerically pure alpha -bisoximes of the formula IaR1O-N=CR2-CR3=N-OR4Iawhere the groups R1O- and R2 on the N=C bond are cis to one another and where the radicals have the following meanings: R1 and R4 are hydrogen or a C-organic radical; R2 is hydrogen, cyano, nitro, hydroxyl, amino, halogen or an organic radical which can be bonded to the structure directly or via an oxygen, sulfur or nitrogen atom; R3 is hydrogen, cyano, nitro, hydroxyl, amino, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylamino, dialkylamino or cycloalkyl, from a mixture of the isomers of the a-bisoximes Ia and Ib is described.