Abstract:
PROBLEM TO BE SOLVED: To obtain the subject new compounds useful as intermediate compounds for the production of phenylacetic acid derivatives suitable as bactericides, effective for a wide variety of phytopathogens and usable also as leaf and soil disinfectants. SOLUTION: The objective compound is expressed by the formula R5ON=C (R4)-C(R3)=NOH [R3 is H, cyano, nitro, hydroxy, amino, a halogen, a 1-4C (halo)alkyl or the like; R4 is H, cyano, nitro, hydroxy, amino, a halogen, a 1-6C alkyl or the like; R5 is H, a 1-10C alkyl or the like], e.g. (E,E)-2- methoxyimino-2-[2'-(1"-methyl,1"-acetyl)-iminoxymethyl]phenylacetic acid methyl ester. The objective compound of the formula can be produced by reacting the corresponding hydroxyimine of the formula HON=C(R4)-C(R3)=NOH with a nucleophilically substituted reagent of the formula R5-L2 (L2 is a nucleophilic exchangeable eliminable group such as a halogen or sulfonate).
Abstract:
PROBLEM TO BE SOLVED: To obtain a new compound having an excellent effect. SOLUTION: This invention relates to a derivative of phenylacetic acid expressed by formula I, and its salt, method of manufacturing of the same, a medicine including the compound to remove a toxic material and a poisonous fungus and its using method.
Abstract:
Phenyl acetic acid derivatives of formula (I) in which the substituents and index have the following meanings: X is oxygen or sulphur; R is hydrogen and alkyl; R is hydrogen and alkyl; R is cyano, nitro, trifluoromethyl, halogen, alkyl and alkoxy; m is 0, 1 ou 2, in which the radicals R may be different if m is 2; R is hydrogen, cyano, nitro, hydroxy, amino, halogen, alkyl, halogen alkyl, alkoxy, halogen alkoxy, alkylthio, alkylamino or dialkylamino; R is hydrogen, cyano, nitro, hydroxy, amino, halogen, possibly substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkinyl, alkinyloxy, alkinylthio, alkinylamino, N-alkinyl-N-alkylamino; optionally substituted cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocylcyl-N-alkylamino, aryl, aryloxy, arylthio, arylamino, n-aryl-n-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino, N-hetaryl-N-alkylamino; R is hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, alkinyl, alkylcarbonyl, alkenylcarbonyl, alkinylcarbonyl or alkylsulfonyl; optionally substituted aryl, arylcarbonyl, arylsulfonyl, hetaryl, hetarylcarbonyl or hetarylsulphonyl; and their salts, process and intermediate products for their production, and their use.
Abstract:
PCT No. PCT/EP96/04446 Sec. 371 Date Apr. 15, 1998 Sec. 102(e) Date Apr. 15, 1998 PCT Filed Oct. 11, 1996 PCT Pub. No. WO97/15552 PCT Pub. Date May 1, 1997Phenylacetic acid derivatives of the formula I where the substituents and the index have the following meanings: x is NOCH3, CHOCH3, CHCH3; Y is O, NR R1,R independently of one another are hydrogen and C1-C4-alkyl; R2 is cyano, nitro, trifluoromethyl, halogen, alkyl and alkoxy; m is 0, 1 or 2, it being possible for the radicals R2 to be different when m is 2; R3 is hydrogen, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl; R4, R5 and R6 have the meanings given in claim 1, and their salts, a process and intermediates for the preparation of these compounds, and compositions comprising them for controlling animal pests and harmful fungi.
Abstract:
In the present invention, there are disclosed phenylacetic acid derivatives of the general formula I, in which X represents NOCHi3, CHOCHi3, CHCHi3 or CHCHi2CHi3; Re1 denotes a hydrogen atom or alkyl; Re2 represents a cyano, nitro, trifluoromethyl group, a halogen atom, alkyl or -alkoxy; m is 0, 1 or 2, whereby the radicals Re2 may be different when m is 2; Re3 represents a hydrogen atom, cyclopropyl, a cyano, nitro, hydroxyl, amino group, a halogen atom, alkyl; Re4 denotes a hydrogen atom, a cyano, nitro, hydroxyl, amino group and a halogen atom; Re5 represents a hydrogen atom, substituted alkyls and aryls. The invention further relates to a process for preparing the compound of the general formula I, in which the Re3 substituent does not represent a halogen atom, composition against animal pest or harmful fungi, method for controlling harmful fungi and animal pest except for treating and use of the claimed composition for the preparation of compositions against animal pest or harmful fungi.
Abstract:
PCT No. PCT/EP97/01668 Sec. 371 Date Oct. 22, 1998 Sec. 102(e) Date Oct. 22, 1998 PCT Filed Apr. 3, 1997 PCT Pub. No. WO97/40672 PCT Pub. Date Nov. 6, 1997Fungicidal mixtures, comprising a1) at least one compound from the group selected from oxime ethers of the formula I where the substituents have the following meanings: X is oxygen or amino (NH); Y is CH or N; Z is oxygen, sulfur, amino (NH) or C1-C4-alkylamino (N-C1-C4-alkyl); R' is C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-alkenyl, C2-C6-haloalkenyl, C3-C6-alkynyl, C3-C6-haloalkynyl, C3-C6-cycloalkylmethyl, or is benzyl which can be partially or fully halogenated and/or can have attached to it one to three of the following radicals: cyano, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy and C1-C4-alkylthio; a2) carbamates of the formula II where T is CH or N, n is 0, 1 or 2 and R is halogen, C1-C4-alkyl or C1-C4-haloalkyl, it being possible for the radicals R to be different if n is 2, and b) a phthalimide derivative selected from the group of the compounds III and IV in a synergistically active amount.
Abstract:
Fungicidal mixtures, comprisinga) oxime ether of the formula I where the substituents have the following meanings:X is oxygen or amino (NH);Y is CH or N;Z is oxygen, sulfur, amino (NH) or C1-C4-alkylamino (N-C1-C4-alkyl);R' is C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-alkenyl, C2-C6-haloalkenyl, C3-C6-alkynyl, C3-C6-haloalkynyl, C3-C6-cycloalkylmethyl, or is benzyl which can be partially or fully halogenated and/or can have attached to it one to three of the following radicals: cyano, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-halo-alkoxy and C1-C4-alkylthio; and/orb) a carbamate of the formula I, where T is CH or N, n is 0, 1 or 2 and R is halogen, C1-C4-alkyl or C1-C4-haloalkyl, it being possible for the radicals R to be different when n is 2, andc) (±)-(2-chlorophenyl)(4-chlorophenyl)(pyrimidin-5-yl)methanol in a synergistically active amount.
Abstract:
PCT No. PCT/EP97/02015 Sec. 371 Date Oct. 22, 1998 Sec. 102(e) Date Oct. 22, 1998 PCT Filed Apr. 22, 1997 PCT Pub. No. WO97/40673 PCT Pub. Date Nov. 6, 1997Fungicidal mixtures, comprising a) an oxime ether of the formula I where the substituents have the following meanings: X is oxygen or amino (NH); Y is CH or N; Z is oxygen, sulfur, amino (NH) or C1-C4-alkylamino (N-C1-C4-alkyl); R' is C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-alkenyl, C2-C6-haloalkenyl, C3-C6-alkynyl, C3-C6-haloalkynyl, C3-C6-cycloalkylmethyl, or is benzyl which can be partially or fully halogenated and/or can have attached to it one to three of the following radicals: cyano, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy and C1-C4-alkylthio and/or b) a carbamate of the formula II where T is CH or N, n is 0, 1 or 2 and R is halogen, C1-C4-alkyl or C1-C4-haloalkyl, it being possible for the radicals R to be different if n is 2, and c) a morpholine or piperidine derivative III selected from the group of the compounds IIIa, IIIb and IIIc in a synergistically active amount.