19.
    发明专利
    未知

    公开(公告)号:ES2127969T3

    公开(公告)日:1999-05-01

    申请号:ES95109311

    申请日:1995-06-16

    Applicant: BASF AG

    Abstract: The prodn. of aliphatic and cycloaliphatic oximes (1) comprises reacting the corresp. imine (2) with oxygen or oxygen-contg. gas in the presence of a catalyst, except for catalysts of formula (Tix(M*D1-x)(2n/3*E1-x))O2 (I), where D = Si or Ge; E = Ce of Al; x = 0.06-0.9; m = 1 if n = 0; m = 0 if n = 1. Also claimed is a process for the prodn. of (1) comprising (a) imination of the corresp. ketone with ammonia by known methods followed by (b) catalytic oxidn. of the imine as above.

    20.
    发明专利
    未知

    公开(公告)号:DE19739716A1

    公开(公告)日:1999-03-11

    申请号:DE19739716

    申请日:1997-09-10

    Applicant: BASF AG

    Abstract: Unsaturated ketones, comprising optionally substituted but-3-enyl and/or buta-2.3-dienyl methyl ketones, are prepared by: (a) reacting allyl alcohols and/or propargyl alcohols with isopropenyl ethers, with formation of ketals as by-product; (b) preparing isopropenyl ethers by catalytic gas phase reaction of ketals with propyne and/or allene; and (c) feeding the ketal from stage (a) into stage (b). The but-3-enyl methyl ketones of formula (Ia) and but-2,3-dienyl methyl ketones of formula (Ib) formed, allyl alcohols of formula (IIa) and/or propargyl alcohols of formula (IIb) and isopropenyl ethers (III) used as starting materials are ketals (IV). R1, R2, R3, R4, R5 = H or (cyclo)alkyl, (cyclo)alkenyl or ar(alk)yl (optionally containing O); or R1R2 = 5-6-membered ring; and R6 = 1-4C alkyl. (III) are prepared by the gas phase reaction of (IV) and propyne or allene at elevated temperature in the presence of a heterogeneous catalyst containing Zn or Cd plus Si and O.

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