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    Halogenation of cyclopropyl-methyl ketone
    1.
    发明专利
    Halogenation of cyclopropyl-methyl ketone 未知

    公开(公告)号：DE19732292A1

    公开(公告)日：1999-01-28

    申请号：DE19732292

    申请日：1997-07-26

    Applicant: BASF AG

    Inventor： STAMM ARMIN DR ,  HENNINGSEN MICHAEL DR ,  FISCHER MARTIN DR ,  HENKELMANN JOCHEM DR

    IPC: C07C1/30 ,  C07C17/00 ,  C07C17/18 ,  C07F9/535 ,  C07C22/00 ,  C07C13/04

    Abstract: Halogenation of cyclopropyl-methyl ketone (CPMK) is effected with at least one dihalo-triorganophosphorane of formula (R)3P(X)2 (I) at 80-130 deg C, where (I) is prepared in situ from a triorgano-phosphane oxide or sulphide of formula R)3P=A (II) and a halogenating agent. The novelty is that (II) is used in a catalytic amount. R = optionally saturated 1-20C aliphatic hydrocarbyl; or phenyl or (1-4C)alkyl-phenyl (both optionally substituted by 1 or 2 of F, Cl and NO2); X = Cl, Br or I; A = O or S. Also claimed are: (i) the halogenated product obtained by the process; and (ii) the preparation of cyclopropyl-acetylene (CPA) by treating the halogenated product as in (i) with a strong base at -33 to +250 deg C.

    Selective oxidation of non-cyclic unsaturated hydrocarbon
    2.
    发明专利
    Selective oxidation of non-cyclic unsaturated hydrocarbon 未知

    公开(公告)号：DE19705326A1

    公开(公告)日：1998-08-13

    申请号：DE19705326

    申请日：1997-02-12

    Applicant: BASF AG

    Inventor： NOE RALF DR ,  HAGEMEYER ALFRED DR ,  HOELZLE MARKUS DR ,  HIBST HARTMUT PROF DR ,  KUEHBAUCH HARTWIG DR ,  FISCHER MARTIN DR ,  NEUMANN HANS-PETER DR

    IPC: B01J23/68 ,  C07B41/00 ,  C07C45/34 ,  C07C51/25 ,  B01J23/89 ,  B01J27/224 ,  C07C47/06 ,  C07C47/22 ,  C07C47/28 ,  C07C57/05 ,  C07D307/36 ,  C07D307/60

    Abstract: A process for the selective oxidation of non-cyclic unsaturated hydrocarbons (UHC) other than isobutene, especially non-cyclic poly-unsaturated alkenes, to give oxygen-containing organic compounds. The process comprises reacting the UHC, or a gas mixture containing UHC, at 150-600 (preferably 180-450) deg C with an optionally supported catalyst material based on a silver- vanadium mixed oxide of formula AgxMyVOz (I), in which x = 0.001-3; M = another element, preferably from main groups 1-6 or sub-Groups 1-3 and 5-8; y = 0-0.5; z = the number required for charge neutrality between cations and oxygen anions. Preferably x = 0.001-1, with y and z as above. Preferred (I) is a beta - or delta -silver-vanadium bronze. The catalyst may be used as an unsupported bulk material, or supported on clay, pillared clay, zeolites, aluminium phosphate, silicon carbide, silicon nitride, boron nitride, carbon, or oxides of titanium, zirconium, zinc, thorium, magnesium, calcium, barium or silicon. The process comprises (a) at least partial reduction of (I) by contact with the UHC or an oxygen-free gas mixture containing UHC, and (b) re-oxidation of the reduced catalyst with gas containing molecular oxygen or another oxygen- containing oxidising agent. Stage (a) is preferably carried out with a gas containing the UHC and a sub-stoichiometric amount of O2 (especially using air) or other oxidising agent as above, preferably dinitrogen oxide.

    6.
    发明专利
    未知

    公开(公告)号：ES2059921T3

    公开(公告)日：1994-11-16

    申请号：ES90114340

    申请日：1990-07-26

    Applicant: BASF AG

    Inventor： FISCHER MARTIN DR

    IPC: B01J27/06 ,  B01J27/135 ,  B01J27/138 ,  C07B61/00 ,  C07D303/04 ,  C07D307/28

    Abstract: A process for the preparation of 2,5-dihydrofurans of the general formula I I where R1, R2, R3, R4, R5 and R6 are identical or different and are hydrogen or C1-C4-alkyl, by the catalytic rearrangement of 3,4-epoxy-1-butenes of the general formula II II comprises the rearrangement being catalyzed by a system which contains components A, B and C, at from 60 DEG to 200 DEG C., where A is a halide of an alkali metal or alkaline earth metal or an onium halide, B is an organic solubilizer for component A, and C is a Lewis acid or elemental iodine, with the proviso that at least one of components A or C is an iodide. 2,5-Dihydrofurans are intermediates for the well known tetrahydrofurans which are used as solvents, e.g. for polyvinyl chloride, polyvinylidene chloride, and other difficultly soluble organic materials, and are also used as monomers for the preparation of polytetrahydrofurans.

    7.
    发明专利
    未知

    公开(公告)号：DE4228160A1

    公开(公告)日：1994-03-03

    申请号：DE4228160

    申请日：1992-08-25

    Applicant: BASF AG

    Inventor： BENDER DIETMAR DR ,  BRONSTERT KLAUS DR ,  MACH HELMUT DR ,  FISCHER MARTIN DR

    IPC: C08F8/12 ,  C08C19/02 ,  C08C19/26 ,  C08C19/40 ,  C08C19/42 ,  C08F8/00 ,  C08F8/30 ,  C08F8/42 ,  C08F236/10 ,  C08F8/08 ,  C08F36/04 ,  C08F297/04 ,  C08G81/02 ,  C10M149/02 ,  C10M145/02

    Abstract: Polymers Ia and Ib carrying functional groups, obtainable by A) 1. hydrogenation of the olefinic double bonds of a polymer IIa comprising a) from 20 to 100% by weight of a conjugated diene, b) from 0 to 80% by weight of a vinylaromatic compound and c) from 0 to 20% by weight of further comonomers, to give the hydrogenated polymers IIb, 2. metallation of IIb using an organoalkali metal compound to give IIc, 3. reaction of IIc with a diaziridine III to give IId and 4. hydrolysis or alcoholysis of IId to give Ia, or by B) 1. partial hydrogenation of IIa to give partially hydrogenated polymers IIb', 2. epoxidation of the double bonds of IIb' to give IIe and 3. reaction of IIe with a compound IV carrying functional groups to give Ib. These polymers Ia and Ib are suitable as viscosity index improvers for engine oils.

    8.
    发明专利
    未知

    公开(公告)号：DE4112841A1

    公开(公告)日：1992-10-22

    申请号：DE4112841

    申请日：1991-04-19

    Applicant: BASF AG

    Inventor： DIEHL KLAUS DR ,  FISCHER MARTIN DR ,  DIMMLER MANFRED DR

    IPC: B01J27/10 ,  B01J27/125 ,  B01J27/128 ,  B01J27/135 ,  C07B61/00 ,  C07D209/08 ,  C07D317/38

    Abstract: Process for preparing indolenines of the general formula I in which R , R and R independently of one another represent hydrogen, C1- to C20-alkyl, C2- to C20-alkenyl, C3- to C8-cycloalkyl, aryl, C7- to C20-alkylphenyl, C7- to C20-phenalkyl, or R and R or R and R together represent a C3- to C8-alkylene chain which is optionally substituted by C1- to C12-alkyl, X and Y independently of one another represent hydrogen, C1- to C8-alkyl, C1- to C8-alkoxy, C2- to C8-alkoxyalkyl, C2- to C8-alkoxycarbonyl, C1- to C4-alkylsulphonyl, halogen, nitro or cyano, by reacting 4-methylene-1,3-dioxolan-2-ones of the general formula II in which the radicals R , R and R have the abovementioned meanings, with anilines of the general formula III in which the radicals X and Y have the abovementioned meanings, in the presence of Lewis acids and, if appropriate, in the presence of halides of main group I or II of the Periodic System of the Elements at temperatures from 100 to 350 DEG C under pressures from 1 to 50 bar, by carrying out the reaction in polar solvents.

    9.
    发明专利
    未知

    公开(公告)号：DE3717037A1

    公开(公告)日：1988-12-08

    申请号：DE3717037

    申请日：1987-05-21

    Applicant: BASF AG

    Inventor： BOETTCHER ANDREAS DR ,  FISCHER MARTIN DR ,  ALDAG REINHARD DR ,  BLUEMEL THOMAS DR

    IPC: G03C1/00 ,  G03F7/031 ,  G03C1/72 ,  G03C1/68 ,  G03F7/10

    Abstract: Photopolymerizable recording materials suitable for producing photoresist layers and lithographic printing plates are composed of one or more photopolymerizable olefinically unsaturated organic compounds, optionally a polymeric binder, one or more photopolymerization initiators, a color-forming system which on irradiation with actinic light causes an increase in the color intensity of the recording material, a sensitizer and optionally further additive and/or auxiliary substances, and contain as the color-forming system (a) one or more colorless or virtually colorless organic compounds which are oxidizable to colored compounds, and (b) a photooxidant for the colorless or virtually colorless organic compound(s) (a), wherein photooxidant (b) comprises an organic salt with a substituted or unsubstituted hetaromatic system, this hetaromatic system having one or more built-in groups of the general formula (I) (I) where R is substituted or unsubstituted alkenyl, alkynyl, hetaryl, alkoxycarbonyl, carbamoyl, alkylsulfonyl or arylsulfonylaminosulfinyl, substituted cycloalkyl or a substituted or unsubstituted hetaryl cation, with the proviso that the maximum of the long-wave absorption band of the salt is below 400 nm.

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