公开(公告)号：CH626082A5

公开(公告)日：1981-10-30

申请号：CH190577

申请日：1977-02-16

Applicant: BASF AG

Inventor： GRAFEN PAUL DR ,  KROESCHE HENNING DR ,  SCHULZ BERNHARD DR ,  PAUST JOACHIM DR ,  PFOHL SIGBERG DR

IPC: C07D311/72

公开(公告)号：DE2860043D1

公开(公告)日：1980-11-13

申请号：DE2860043

申请日：1978-06-13

Applicant: BASF AG

Inventor： SCHULZ BERNHARD DR ,  GRAFEN PAUL DR ,  SCHOLZ HANS-ULRICH DR ,  GRASSNER HANS DR ,  REIF WERNER DR

IPC: C07F9/54

Abstract: Aqueous solutions of polyenyltriarylphosphonium salts are prepared from solutions of the corresponding polyenyltriarylphosphonium salts in organic solvents by driving off the solvent with steam, part of the steam being allowed to condense. Some of the said triarylphosphonium salts may be used directly as pesticides while others are used as intermediates for organic syntheses, especially in the carotinoid field.

公开(公告)号：DE19506999A1

公开(公告)日：1996-08-29

申请号：DE19506999

申请日：1995-02-28

Applicant: BASF AG

Inventor： KRAUSE WOLFGANG DR ,  MUENSTER PETER DR ,  ERNST HANSGEORG DR ,  PAUST JOACHIM DR ,  SCHULZ BERNHARD DR ,  KOCHNER ARNO ,  ETZRODT HEINZ DR

IPC: B01J31/02 ,  C07C50/00 ,  C07C251/22 ,  C07C403/14 ,  C07C403/20

Abstract: Prodn. of polyenecarbonyl cpds. (I) having high all-E content, and their acetals and ketals, comprises reacting a carbonyl cpd. (II) with a dialkyl phosphonate in a Horner-Emmons reaction or with a CH-acidic cpd. in an aldol condensation in the presence of 0.3-10 mol.% (based on (II)) of a component (B) comprising a) oxygen or nitrogen monoxide (opt. mixed with an inert gas); b) the stable 2,2-diphenyl-1-picrylhydrazyl radical or a hydrogen peroxide-urea adduct; c) quinone, a quinone deriv. or coenzyme Q10 hydroquinone; and/or d) a stable radical of formula (a) or (b). R1, R2 = 1-4C alkyl; or R1+R2 = ethylene, propylene, vinylene or propenylene (all opt. substd. by alkyl, aryl, OH, alkoxy, silyloxy, oxo, NH2, SH, alkylthio, CN, COOH, carbamoyl, heteroaryl or alkylcarbonyloxy); R3-R5 = as R1, R2.

公开(公告)号：DE59201251D1

公开(公告)日：1995-03-09

申请号：DE59201251

申请日：1992-03-24

Applicant: BASF AG

Inventor： FRANK JUERGEN DR ,  RHEUDE UDO DR ,  SCHULZ BERNHARD DR ,  PAUST JOACHIM DR ,  HICKMANN ECKHARD DR

IPC: B01J27/128 ,  B01J27/138 ,  C07B61/00 ,  C07C47/21 ,  C07C403/24 ,  C07D307/28

公开(公告)号：DE3760738D1

公开(公告)日：1989-11-16

申请号：DE3760738

申请日：1987-06-26

Applicant: BASF AG

Inventor： SCHULZ BERNHARD DR ,  FISCHER ROLF DR

IPC: C07C67/02 ,  C07C69/007 ,  C07C69/16 ,  C07C69/28 ,  C07C69/78 ,  C07D317/30

公开(公告)号：DE3622601A1

公开(公告)日：1988-01-14

申请号：DE3622601

申请日：1986-07-05

Applicant: BASF AG

Inventor： SCHULZ BERNHARD DR ,  FISCHER ROLF DR

IPC: C07C67/02 ,  C07C69/007 ,  C07C69/16 ,  C07C69/28 ,  C07C69/78 ,  C07D317/30

公开(公告)号：DE2729974A1

公开(公告)日：1979-01-18

申请号：DE2729974

申请日：1977-07-02

Applicant: BASF AG

Inventor： REIF WERNER PROF DR ,  SCHULZ BERNHARD DR ,  GRAFEN PAUL DR ,  SCHOLZ HANS-ULRICH DR ,  GRASSNER HANS DR

IPC: A01N57/00 ,  C07F9/54 ,  A01N9/36

Abstract: 10-70 wt.% organic solvent solutions of polyenyl-triaryl-phosphonium salts of formula (I) (R is a 5-20C aliphatic, cycloaliphatic-aliphatic or araliphatic polyenyl residue; X is the anion equivalent of a strong acid; Ar is aryl) are converted into solvent-free aq. solutions or fine dispersions. the solvent and other steam-volatile cpds. originating from the synthesis of (I) are driven off with steam at 30-120degrees C. Part of the steam is allowed to condense so as to produce the aq. soln. or dispersion. Some cpds. (I) are useful as pesticides (e.g. against water snails), while others are intermediates, esp. for carotenoids. Aq. solns. or dispersions of (I) often preferred for organic syntheses) are easily obtd. from the organic solutions formed in the synthesis of (I).