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公开(公告)号:DE2729974A1
公开(公告)日:1979-01-18
申请号:DE2729974
申请日:1977-07-02
Applicant: BASF AG
Inventor: REIF WERNER PROF DR , SCHULZ BERNHARD DR , GRAFEN PAUL DR , SCHOLZ HANS-ULRICH DR , GRASSNER HANS DR
Abstract: 10-70 wt.% organic solvent solutions of polyenyl-triaryl-phosphonium salts of formula (I) (R is a 5-20C aliphatic, cycloaliphatic-aliphatic or araliphatic polyenyl residue; X is the anion equivalent of a strong acid; Ar is aryl) are converted into solvent-free aq. solutions or fine dispersions. the solvent and other steam-volatile cpds. originating from the synthesis of (I) are driven off with steam at 30-120degrees C. Part of the steam is allowed to condense so as to produce the aq. soln. or dispersion. Some cpds. (I) are useful as pesticides (e.g. against water snails), while others are intermediates, esp. for carotenoids. Aq. solns. or dispersions of (I) often preferred for organic syntheses) are easily obtd. from the organic solutions formed in the synthesis of (I).