公开(公告)号：DE1200062B

公开(公告)日：1965-09-02

申请号：DEB0075134

申请日：1964-01-24

Applicant: BASF AG

Inventor： RAFF DR PAUL ,  SCHUSTER DR LUDWIG ,  FISCHER DR ADOLF ,  SCHEUERER DR GUENTER ,  STEINBRUNN DR GUSTAV

IPC: C07C275/26

公开(公告)号：DE1272919B

公开(公告)日：1968-07-18

申请号：DEB0088963

申请日：1966-09-17

Applicant: BASF AG

Inventor： RAFF DR PAUL ,  PEINE DR HANS GEORG ,  SCHUSTER DR LUDWIG ,  ADAM DR KARL

IPC: B01J27/186 ,  B01J27/187

Abstract: 1,191,935. Bis - (4 - Aminocyclohexyl) - alkanes. BADISCHE ANILIN- & SODA-FABRIK A.G. 15 Sept., 1967 [17 Sept., 1966], No. 42183/67. Heading C2C. Bis - (4 - Aminocyclohexyl) - alkanes are produced by reacting a bis-(4-hydroxycyclohexyl)- alkane with ammonia in the presence of hydrogen at elevated temperature and pressure in the liquid phase in the presence of a hydrogenation catalyst which contains cobalt, manganese and phosphoric acid. The preferred starting materials are those of Formula (I) in which R denotes an alkylene or alkylidene radical having 1-4 carbon atoms. Preferably the reaction is carried out at 150-200‹ C., a hydrogen partial pressure of 10-150 atm. gauge, and at a pressure of 400 atm. in the presence of a catalyst containing 99-90% by weight of cobalt and 1-10% by weight of manganese based on the total metal present at 0À5-10% of phosphoric acid based on the metal content. Examples are given of the production of bis-(4-amino-cyclohexyl)-propane-(2,2).

公开(公告)号：DE1227892B

公开(公告)日：1966-11-03

申请号：DEB0074749

申请日：1963-12-20

Applicant: BASF AG

Inventor： RAFF DR PAUL ,  SCHUSTER DR LUDWIG

IPC: C08G18/32 ,  C08G59/50 ,  C08G69/26

公开(公告)号：DE1178846B

公开(公告)日：1964-10-01

申请号：DEB0068739

申请日：1962-09-06

Applicant: BASF AG

Inventor： SCHUSTER DR LUDWIG