公开(公告)号：DE1225179B

公开(公告)日：1966-09-22

申请号：DEB0075778

申请日：1964-03-07

Applicant: BASF AG

Inventor： PASEDACH DR HEINRICH ,  PEINE DR HANS GEORG ,  AMANN DR AUGUST

IPC: C07D211/52 ,  C07D211/74

公开(公告)号：DE1262601B

公开(公告)日：1968-03-07

申请号：DEB0079058

申请日：1964-10-24

Applicant: BASF AG

Inventor： RAFF DR PAUL ,  PEINE DR HANS GEORG ,  LOUIS DR GERD ,  FAULHABER DR GERHARD

IPC: C08F2/22 ,  C08F20/50

公开(公告)号：DE1272919B

公开(公告)日：1968-07-18

申请号：DEB0088963

申请日：1966-09-17

Applicant: BASF AG

Inventor： RAFF DR PAUL ,  PEINE DR HANS GEORG ,  SCHUSTER DR LUDWIG ,  ADAM DR KARL

IPC: B01J27/186 ,  B01J27/187

Abstract: 1,191,935. Bis - (4 - Aminocyclohexyl) - alkanes. BADISCHE ANILIN- & SODA-FABRIK A.G. 15 Sept., 1967 [17 Sept., 1966], No. 42183/67. Heading C2C. Bis - (4 - Aminocyclohexyl) - alkanes are produced by reacting a bis-(4-hydroxycyclohexyl)- alkane with ammonia in the presence of hydrogen at elevated temperature and pressure in the liquid phase in the presence of a hydrogenation catalyst which contains cobalt, manganese and phosphoric acid. The preferred starting materials are those of Formula (I) in which R denotes an alkylene or alkylidene radical having 1-4 carbon atoms. Preferably the reaction is carried out at 150-200‹ C., a hydrogen partial pressure of 10-150 atm. gauge, and at a pressure of 400 atm. in the presence of a catalyst containing 99-90% by weight of cobalt and 1-10% by weight of manganese based on the total metal present at 0À5-10% of phosphoric acid based on the metal content. Examples are given of the production of bis-(4-amino-cyclohexyl)-propane-(2,2).