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    Curing polyepoxide compounds
    12.
    发明专利
    Curing polyepoxide compounds 未知

    公开(公告)号：GB1109853A

    公开(公告)日：1968-04-18

    申请号：GB2409465

    申请日：1965-06-08

    Applicant: BASF AG

    Inventor： STEDEN FRANZ ,  BEER LUDWIG ,  LISSNER OSKAR

    IPC: C08G59/50

    Abstract: A 1-aminomethyl-2-aminopropylcyclohexane is used to cure a polyepoxide having more than one 1,2-epoxy group at 20 DEG to 200 DEG C. The polyepoxide may be a glycidyl ether of a polyhydric phenol or polyhydric alcohol. The hardening agent may have one or more substituents, e.g. cycloaliphatic, aliphatic-aromatic or aromatic hydrocarbon radicals; it may be used at 5-50 parts by weight per 100 parts of polyepoxide A filler, pigment dye or plasticizer may be incorporated into the mixture prior to curing. Urea formaldehyde or phenol formaldehyde resins may also be present.

    Curing polyepoxide compounds
    13.
    发明专利
    Curing polyepoxide compounds 未知

    公开(公告)号：GB1100964A

    公开(公告)日：1968-01-31

    申请号：GB1717665

    申请日：1965-04-23

    Applicant: BASF AG

    Inventor： MEYER FERDINAND ,  STEDEN FRANZ

    IPC: C08G59/54 ,  C08G69/00 ,  C08L63/00

    Abstract: Polyepoxides are cured by basic polyamides obtained by reacting a molar excess of a primary and/or secondary polyamine with an adduct of a natural resin acid with an a ,b -ethylenically unsaturated carboxylic acid and/or a derivative thereof which will form amide groups. Preferred adducts are of maleic, fumaric, itaconic, acrylic, aconitic or citraconic acid with colophony or with pimaric or abietic acids and their derivatives, whilst the preferred amines are polyalkylenepolyamines. Many polyepoxides are specified. Conventional hardeners or accelerators for the curing of polyepoxides may also be present in the curable mixtures as may be solvents. The curable compositions are useful as lacquers, moulding compositions, casting or laminating resins, dip resins, adhesives and encapsulating compositions. Polyamides are prepared by reacting a colophony acrylic acid adduct with diethylenetriamine or diethylenetriamine and 1,3-bisaminomethylbenzene under nitrogen.ALSO:Sheet steel and glass sheets are painted with lacquers comprising a polyepoxide, a polyamide derived from a molar excess of a polyamine and an adduct of an a , b -ethylenically p unsaturated carboxylic acid with a natural resin acid and an organic solvent (see Division C3).

    14.
    发明专利
    未知

    公开(公告)号：FR1456153A

    公开(公告)日：1966-10-21

    申请号：FR39021

    申请日：1965-11-19

    Applicant: BASF AG

    Inventor： STEDEN FRANZ ,  SCHAEDLER HUGO ,  LISSNER OSKAR ,  SCHUSTER LUDWIG

    IPC: C08G59/50

    Abstract: Poly-1, 2-epoxides are cured with tetrahydrocyclopentadienylenediamine of the formula or a substitution product thereof bearing C1- 4 alkyl groups. Up to 50% by weight of the tetrahydrocyclopentadienylenediamine may be replaced by a conventional curing agent in compositions containing 1 to 3 equivalents of the diamine and 1 equivalent of the polyepoxide. The curable compositions may also contain levelling agents and organic solvents and are useful as moulding, coating, encapsulating, laminating and bonding compositions.ALSO:Coatings on, for example, sheet glass and sheet metal are produced by applying lacquers comprising a polyepoxide and a tetrahydrotricyclopentadienylenediamine of the formula:- or a C1-4 alkyl substituted tetrahydrotricyclopentadienylenediamine with as optional ingredients conventional curing agents for epoxy resins organic solvents and levelling agents.

    Hardening casting epoxy resins
    17.
    发明专利
    Hardening casting epoxy resins 未知

    公开(公告)号：GB944832A

    公开(公告)日：1963-12-18

    申请号：GB646362

    申请日：1962-02-20

    Applicant: BASF AG

    Inventor： STEDEN FRANZ ,  MEYER FERDINAND

    IPC: C08G59/32

    Abstract: 1,2-5,6-9,10-triepoxycyclododecane is prepared by the reaction of cyclododecatriene-(1,5,9) with peroxy acids or other peroxy compounds, preferably in the presence of inert organic solvents.ALSO:A hardening casting resin comprises a mixture of (i) 1, 2-5, 6-9, 10-triepoxycyclododecane with or without at least one other compound having more than one epoxy group, and (ii) a curing agent for compounds having more than one epoxy group, with or without (iii) up to 20% by weight of (i) and (ii) of a liquid substance other than a polymerizable ethylenically unsaturated substance; polymerizable liquid ethylenically unsaturated substances (iv) may be added in quantities up to 30% by weight of (i) and (ii) Compounds specified are:-(i) the polyglycidyl ethers of ethyleneglycol, glycerine, pentaerythritol and bisphenol A, vinyl cyclohexene dioxide, and 1, 2-5, 6-diepoxycyclooctane; (ii) o-, m- and p-benzene dicarboxylic acids, phthalic and maleic anhydrides, 1, 4-diaminobenzene and 4, 41-3, 31-dimethyldicyclohexylmethane, with or without sulphuric or phosphoric acids, AlCl3, BF3, FeCl3, ZnCl2, SnCl4, NaOH, KOH, quaternary ammonium compounds and BF3-amine complexes; (iii) water, aqueous solutions of simple alcohols or ketones, liquid hydrocarbons, or simple alcohols, ketones or ethers; (iv) styrene and acrylic or methacrylic esters of monohydric lower aliphatic alcohols. Fillers, glass fibres and pigments may also be added.

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