Continuous photooximation of cyclododecane

    公开(公告)号:GB1136747A

    公开(公告)日:1968-12-18

    申请号:GB1722566

    申请日:1966-04-20

    Applicant: BASF AG

    Abstract: 1,136,747. Cyclododecane oxime. BADISCHE ANILIN- & SODA-FABRIK A.G. 20 April, 1966 [21 April, 1965], No. 17225/66. Heading C2C. Cyclododecane is converted to its oxime by treating a solution of cyclododecane in chlorobenzene with a nitrosating agent and with light having a wavelength of 360-600 millimicrons while mixing the reaction mixture with turbulence, the cyclododecane oxime being removed from the reaction mixture outside the reaction zone by extraction with strong sulphuric acid. Suitable nitrosating agents are, for example, nitrosyl chloride or compounds which form nitrosyl chloride in the reaction medium. If desired, the process may be carried out in the presence of hydrogen chloride.

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