Black perylene pigments comprising fused-ring dipyridoperylenedione isomers useful for coloring high molecular weight organic material of natural and synthetic origin

    公开(公告)号:DE102004057876A1

    公开(公告)日:2006-06-01

    申请号:DE102004057876

    申请日:2004-11-30

    Applicant: BASF AG

    Abstract: Black perylene pigments (I) comprising fused-ring dipyridoperylenedione isomers and having a black number of at least 210 in an alkyd/melamine stoving lacquer are new. Black perylene pigments (I) comprising fused-ring dipyridoperylenedione isomers of formula (Ia) and/or (Ib) and having a black number of at least 210 in an alkyd/melamine stoving lacquer are new. [Image] [Image] R 1>, R 2>phenylene, naphthylene or pyridylene, all optionally substituted with 1-12C alkyl, 1-6C alkoxy, OH, NO 2 and/or halo; X : halo; n : 0-4. Independent claims are also included for: (1) producing the perylene pigments from synthetically produced crude pigments by either comminution and optionally recrystallization from a liquid medium or comminution and simultaneous recrystallization; (2) producing the crude pigments by condensing perylene-3,4;9,10-tetracarboxylic acid dianhydride with an aromatic ortho-diamine and cyclizing the product, where condensation and cyclization are effected in a reaction medium comprising phenol or a non-fused nitrogen-containing heteroaromatic compound; (3) pigment synergists comprising isomers of formula (Ia') or (Ib'). [Image] [Image] R 1>', R 2>' : phenylene, naphthylene or pyridylene, all substituted with COOM, COOR 3>, CONR 3>R 4>, COO -> N +>R 3>R 4>R 5>R 6>, SO 2NR 3>R 4>, CH 2NR 3>R 4>, CH 2N +>R 3>R 4>R 5>R 6> R 3>COO -> and/or CH 2R 7> and optionally substituted with 1-12C alkyl, 1-6C alkoxy, OH, NO 2 and/or halo; R 3>-R 6>H; 1-12C alkyl or 2-12C alkenyl optionally interrupted by O, S, NR 8>, CO or SO 2 and optionally substituted with OH, halo, aryl, 1-4C alkoxy and/or acetyl; or 3-8C cycloalkyl optionally interrupted by O, S, NR 8> or CO and optionally substituted with acetyl; R 7>phthalimidyl; R 8>H or 1-8C alkyl; M : H or metal; X : halo; n : 0-4.

    14.
    发明专利
    未知

    公开(公告)号:BR0315133A

    公开(公告)日:2005-08-16

    申请号:BR0315133

    申请日:2003-10-06

    Applicant: BASF AG

    Abstract: A process for producing colored oriented strand board, which comprises the wood strands which serve as a base material for oriented strand board being contacted, before or after-drying, with a liquid colorant preparation, then conventionally resinated, and formed into three-layered mats and these three-layered mats being hot-pressed into board having a center layer and two outside layers.

    15.
    发明专利
    未知

    公开(公告)号:DE10248083A1

    公开(公告)日:2004-04-29

    申请号:DE10248083

    申请日:2002-10-15

    Applicant: BASF AG

    Abstract: A process for producing colored oriented strand board, which comprises the wood strands which serve as a base material for oriented strand board being contacted, before or after-drying, with a liquid colorant preparation, then conventionally resinated, and formed into three-layered mats and these three-layered mats being hot-pressed into board having a center layer and two outside layers.

    16.
    发明专利
    未知

    公开(公告)号:DE50309110D1

    公开(公告)日:2008-03-20

    申请号:DE50309110

    申请日:2003-11-28

    Applicant: BASF AG

    Abstract: Solid pigment preparations containing the following ingredients as substantial components: (A) 60-85 wt. % of at least one organic pigment, (B) 0.1-15 wt. % of at least one pigment derivative of general formula I wherein the variables have the following meanings: P is the radical of the parent substance of an organic pigment; T 1 , T 2 independently represent a chemical bond, -CONR 1 - or -SO 2 NR 1 -; B 1 , B 2 independently represent a chemical bond, C1-C8-alkylene or phenylene;X, Y independently represent similar or different groups -SO 3 - Ka + or -COO- Ka + ; m, n represent a rational number from 0 to 3, whereby 1=m+n=4; Ka + H + , Li + , Na + , K + , N + R 2 R 3 R 4 R 5 or a mixture of said cations; R 1 represents hydrogen; C 1 -C 4 -alkyl; phenyl or naphthyl which can be respectively substituted by C 1 -C 18 -alkyl; R 2 , R 3 , R 4 , R 5 independently represent hydrogen; C 1 -C 30 -alkyl; C 3 -C 30 -alkenyl; C 5 -C 6 -cycloalkyl which can be substituted by C 1 -C 24 -alkyl; phenyl or naphthyl which can be respectively substituted by C 1 -C 24 -alkyl or C 2 -C 24 -alkenyl; a radical of formula -[CHR 6 -CHR 7 -O]x-R 8 , wherein the repeating units -[CHR 6 -CHR 7 -O] for x> 1 can vary; R 6 , R 7 , R 8 independently represent hydrogen or C 1 -C 6 -alkyl; x is a whole number= 1 , and (C) 14.9 39.9 wt. % of at least one surface active additive from the group of non-ionic polyethers containing no primary amino groups, the acidic phosphoric acid esters,phosphonic acid esters, sulphuric acid esters and/or sulfonic acid esters thereof, the salts thereof and the condensation produces thereof with formaldehyde.

    Black perylene pigments comprising fused-ring dipyridoperylenedione isomers useful for coloring high molecular weight organic material of natural and synthetic origin

    公开(公告)号:DE102004007382A1

    公开(公告)日:2005-09-01

    申请号:DE102004007382

    申请日:2004-02-11

    Applicant: BASF AG

    Abstract: Black perylene pigments (I) comprising fused-ring dipyridoperylenedione isomers and having a black number of at least 210 in an alkyd/melamine stoving lacquer are new. Black perylene pigments (I) comprising fused-ring dipyridoperylenedione isomers of formula (Ia) and/or (Ib) and having a black number of at least 210 in an alkyd/melamine stoving lacquer are new. [Image] [Image] R 1>, R 2>phenylene, naphthylene or pyridylene, all optionally substituted with 1-12C alkyl, 1-6C alkoxy, OH, NO 2 and/or halo; X : halo; n : 0-4. Independent claims are also included for: (1) producing the perylene pigments from synthetically produced crude pigments by either comminution and optionally recrystallization from a liquid medium or comminution and simultaneous recrystallization; (2) producing the crude pigments by condensing perylene-3,4;9,10-tetracarboxylic acid dianhydride with an aromatic ortho-diamine and cyclizing the product, where condensation and cyclization are effected in a reaction medium comprising phenol or a non-fused nitrogen-containing heteroaromatic compound; (3) pigment synergists comprising isomers of formula (Ia') or (Ib'). [Image] [Image] R 1>', R 2>' : phenylene, naphthylene or pyridylene, all substituted with COOM, COOR 3>, CONR 3>R 4>, COO -> N +>R 3>R 4>R 5>R 6>, SO 2NR 3>R 4>, CH 2NR 3>R 4>, CH 2N +>R 3>R 4>R 5>R 6> R 3>COO -> and/or CH 2R 7> and optionally substituted with 1-12C alkyl, 1-6C alkoxy, OH, NO 2 and/or halo; R 3>-R 6>H; 1-12C alkyl or 2-12C alkenyl optionally interrupted by O, S, NR 8>, CO or SO 2 and optionally substituted with OH, halo, aryl, 1-4C alkoxy and/or acetyl; or 3-8C cycloalkyl optionally interrupted by O, S, NR 8> or CO and optionally substituted with acetyl; R 7>phthalimidyl; R 8>H or 1-8C alkyl; M : H or metal; X : halo; n : 0-4.

    Solid pigment preparations containing pigment derivatives and surface-active additives

    公开(公告)号:AU2003298151A8

    公开(公告)日:2004-06-23

    申请号:AU2003298151

    申请日:2003-11-28

    Applicant: BASF AG

    Abstract: Solid pigment preparations containing the following ingredients as substantial components: (A) 60-85 wt. % of at least one organic pigment, (B) 0.1-15 wt. % of at least one pigment derivative of general formula I wherein the variables have the following meanings: P is the radical of the parent substance of an organic pigment; T 1 , T 2 independently represent a chemical bond, -CONR 1 - or -SO 2 NR 1 -; B 1 , B 2 independently represent a chemical bond, C1-C8-alkylene or phenylene;X, Y independently represent similar or different groups -SO 3 - Ka + or -COO- Ka + ; m, n represent a rational number from 0 to 3, whereby 1=m+n=4; Ka + H + , Li + , Na + , K + , N + R 2 R 3 R 4 R 5 or a mixture of said cations; R 1 represents hydrogen; C 1 -C 4 -alkyl; phenyl or naphthyl which can be respectively substituted by C 1 -C 18 -alkyl; R 2 , R 3 , R 4 , R 5 independently represent hydrogen; C 1 -C 30 -alkyl; C 3 -C 30 -alkenyl; C 5 -C 6 -cycloalkyl which can be substituted by C 1 -C 24 -alkyl; phenyl or naphthyl which can be respectively substituted by C 1 -C 24 -alkyl or C 2 -C 24 -alkenyl; a radical of formula -[CHR 6 -CHR 7 -O]x-R 8 , wherein the repeating units -[CHR 6 -CHR 7 -O] for x> 1 can vary; R 6 , R 7 , R 8 independently represent hydrogen or C 1 -C 6 -alkyl; x is a whole number= 1 , and (C) 14.9 39.9 wt. % of at least one surface active additive from the group of non-ionic polyethers containing no primary amino groups, the acidic phosphoric acid esters,phosphonic acid esters, sulphuric acid esters and/or sulfonic acid esters thereof, the salts thereof and the condensation produces thereof with formaldehyde.

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