公开(公告)号：JPH10182996A

公开(公告)日：1998-07-07

申请号：JP34510997

申请日：1997-12-15

Applicant: BASF AG

Inventor： SCHUETZE ANDREA BIRGIT ,  SCHERHAG FRANK ,  KLOPP INGO ,  HARTMANN ANETTE

IPC: C09B47/067 ,  C09B47/22 ,  C09B47/24 ,  C09B47/26 ,  C09B47/30 ,  C09B67/50 ,  C09D11/02

Abstract: PROBLEM TO BE SOLVED: To simply prepare the subject polymorph, having a desired particle size and a desired particle size distribution and useful as a pigment for coloring coating materials, etc., by reductively cyclizing phthalonitrile in the presence of an aliphatic alcohol, a redox catalyst, an inorganic base and a specific phthalocyanine derivative. SOLUTION: Phthalonitrile is reductively cyclized in the presence of an aliphatic alcohol, a redox catalyst, an inorganic base and a phthalocyanine derivative (phthalocyanine-sulfonic acid, phthalocyanine-carboxylic acid, an aminomethylated phthalocyanine, a halogenated phthalocyanine, etc.). Thereby, the subject phthalocyanine directly usable as a pigment for coloring printing inks, coating materials and plastics is obtained without passing the phthalonitrile through finishing steps (grinding and/or solvent treatment).

公开(公告)号：WO2004050770A8

公开(公告)日：2005-06-09

申请号：PCT/EP0313464

申请日：2003-11-28

Applicant: BASF AG ,  KLOPP INGO ,  GONZALEZ GOMEZ JUAN ANTONIO ,  MAUTHE UWE ,  REISACHER HANSULRICH ,  STOHR ANDREAS

Inventor： KLOPP INGO ,  GONZALEZ GOMEZ JUAN ANTONIO ,  MAUTHE UWE ,  REISACHER HANSULRICH ,  STOHR ANDREAS

IPC: C08K9/08 ,  C09B67/00 ,  C09B67/20 ,  C09B67/22 ,  C09D7/12 ,  C09D11/02 ,  C08K9/04 ,  C09C3/08

CPC classification number: C09D11/03 ,  C08K9/08 ,  C08K2201/014 ,  C09B67/0034 ,  C09B67/006 ,  C09B67/0092 ,  C09D7/41 ,  C09D17/003

Abstract: Solid pigment preparations containing the following ingredients as substantial components: (A) 60 - 85 wt. % of at least one organic pigment, (B) 0.1 - 15 wt. % of at least one pigment derivative of general formula I wherein the variables have the following meanings: P is the radical of the parent substance of an organic pigment; T , T independently represent a chemical bond, -CONR - or -SO2NR -; B , B independently represent a chemical bond, C1-C8-alkylene or phenylene;X, Y independently represent similar or different groups -SO3- Ka or -COO- Ka ; m, n represent a rational number from 0 to 3, whereby 1 = m+n = 4; Ka H , Li , Na , K , N R R R R or a mixture of said cations; R represents hydrogen; C1-C4-alkyl; phenyl or naphthyl which can be respectively substituted by C1-C18-alkyl; R , R , R , R independently represent hydrogen; C1-C30-alkyl; C3-C30-alkenyl; C5-C6-cycloalkyl which can be substituted by C1-C24-alkyl; phenyl or naphthyl which can be respectively substituted by C1-C24-alkyl or C2-C24-alkenyl; a radical of formula -[CHR -CHR -O]x-R , wherein the repeating units -[CHR -CHR -O] for x > 1 can vary; R , R , R independently represent hydrogen or C1-C6-alkyl; x is a whole number = 1,and (C) 14.9 39.9 wt. % of at least one surface active additive from the group of non-ionic polyethers containing no primary amino groups, the acidic phosphoric acid esters,phosphonic acid esters, sulphuric acid esters and/or sulfonic acid esters thereof, the salts thereof and the condensation produces thereof with formaldehyde.

Abstract translation: 固体颜料制剂，其包括作为主要成分的（A）60至85重量％的至少一种有机颜料，（B）的％0.1至15重量通式I：其中各变量具有以下含义的至少一种颜料衍生物的％：P 有机颜料的身体的其余部分; T'>，T <2>独立地为化学键，-CONR <1> - 或-SO 2 NR <1> - ; 乙<1>，B <2>独立地为化学键，C 1 -C 8 - 亚烷基或亚苯基; X，Y彼此独立地相同或不同的基团-SO 3 - 嘉<+>或-COO-嘉<+>; M，N为有理数从0到3，其中1 <= M + N？ 4; KA <+>ħ<+>，锂<+>，的Na <+>，K <+>，N <+> - [R <2> [R <3> [R <4> - [R <5>或这些阳离子的混合物; [R <1>氢; C1-C4烷基; 苯基或可被C1-C18烷基取代的萘基; [R <2>，R <3>，R <4>，R <5>独立地为氢; C1-C30烷基; C3-C30烯基; C5-C6环烷基，其可被C 1 -C 24 - 烷基取代; 苯基或可被C1-C24烷基或C2-C24链烯基被取代的萘基; 一个式的基团 - [CHR <6>是-CHR <7> -O]×-R <8>，其中，所述重复单元 - [CHR <6> <7> -O -CHR]可以对于x> 1变化; [R <6> - [R <7> - [R <8>独立地是氢或C1-C6烷基; x是整数> = 1，和（C）14.9〜39.9重量选自非离子，不含伯氨基的聚醚，其酸性磷酸，膦酸，硫酸中的至少一种表面活性添加剂的％和 /或磺酸酯，这些酯的盐和烷基 - 和烷基芳基磺酸，它们的盐和它们的缩合产物与甲醛。

公开(公告)号：WO2007057370A3

公开(公告)日：2007-08-09

申请号：PCT/EP2006068376

申请日：2006-11-13

Applicant: BASF AG ,  KLOPP INGO ,  ETZBACH KARL-HEINZ ,  REICHELT HELMUT

Inventor： KLOPP INGO ,  ETZBACH KARL-HEINZ ,  REICHELT HELMUT

IPC: C09B67/26 ,  C09B67/22 ,  D21H21/28

CPC classification number: C09B67/0046 ,  C09B67/0073 ,  C09B67/0083

Abstract: The invention relates to aqueous liquid formulations containing 5 to 30 percent by weight of a dye composition that comprises 25 to 85 percent by weight of direct brown 44, 15 to 75 percent by weight of direct yellow 11 and/or a dye obtained by reducing or thermally treating direct yellow 11, 0 to 15 percent by weight of one or several direct blue dyes, and 0 to 10 percent by weight of one or several direct red dyes, the percentages being relative to the dye composition, 0.5 to 15 percent by weight of one or several alkylamines, the one, two, or three alkyl radicals of which can be substituted by one or two hydroxyl groups and/or amino groups and/or be interrupted by one or two oxygen atoms having an ether function, said percentages being in relation to the total weight of the aqueous liquid formulation, the Na concentration of the liquid formulation not exceeding 0.3 percent by weight. Also disclosed is the use of the inventive aqueous liquid formulations for dyeing cellulose material, especially paper.

Abstract translation: 本发明涉及含水包含5-30重量的染料组合物的％的液体制剂，其包含25-85重量％直接棕44 15-75重量％直接黄11和/或通过还原或直接进行热处理而得到的染料的 具有一个，两个黄11 0-15重量的一种或多种蓝色直接染料和0-10重量的一种或多种红色各自基于0.5-15重量的一种或多种烷基胺的％染料组合物直接染料％的％ 可以是或三个烷基各自被一个或两个羟基和/或氨基基团取代和/或中断通过在乙醚功能的一个或两个氧原子，基于含水液体制剂的总重量计，其中所述液体制剂0.3重量％的Na含量 不超过，以及它们用于染色纤维素材料，特别是纸张的用途。

公开(公告)号：WO2004046251A3

公开(公告)日：2004-07-29

申请号：PCT/EP0312554

申请日：2003-11-11

Applicant: BASF AG ,  REISACHER HANSULRICH ,  KLOPP INGO ,  HUEFFER STEPHAN ,  KLUEGLEIN MATTHIAS

Inventor： REISACHER HANSULRICH ,  KLOPP INGO ,  HUEFFER STEPHAN ,  KLUEGLEIN MATTHIAS

IPC: C08J3/20 ,  C09B20060101 ,  C09B67/00 ,  C09B67/20 ,  C09B69/10 ,  C09D17/00

CPC classification number: C09B67/0063

Abstract: Disclosed are solid pigment preparations containing (A) 60 to 95 per weight of at least one pigment, (B) 5 to 40 percent by weight of at least one water-soluble anionic surface-active additive from the group of the homopolymers and copolymers of ethylenically unsaturated monocarboxylic acids and/or ethylenically unsaturated dicarboxylic acids which can additionally contain monopolymerized vinyl monomers having no acid function, the alkoxylation products of said homopolymers and copolymers, and the salts of said homopolymers and copolymers and the alkoxylation products thereof, and (C) 0 to 20 percent by weight of at least one nonionic surface-active polyether-based additive as essential components. Also disclosed are a method for the production thereof and methods for dyeing macromolecular organic and inorganic materials.

Abstract translation: 固体颜料制剂选自均聚物，其包括作为主要成分的（A）0至95重量％的至少一种颜料，（B）5〜40重量％的至少一种水溶性阴离子表面活性添加剂的和烯属不饱和单羧酸的共聚物和 /或烯属不饱和二羧酸，乙烯基单体，另外包括无酸功能可以包含共聚形式，这些均聚物的烷氧基化产物和共聚物以及这些均聚物和共聚物以及它们的烷氧基化产物和（C）0至20重量％的至少一种非离子型表面活性添加剂的％的盐 Polyethernund过程的基础它们的制备方法和用于大分子有机和无机材料的着色上。

公开(公告)号：CA2458812C

公开(公告)日：2010-05-04

申请号：CA2458812

申请日：2002-08-29

Applicant: BASF AG

Inventor： KLOPP INGO ,  BOGENSTAETTER THOMAS ,  FRANKE DIRK ,  MUNZINGER MANFRED

IPC: B01J8/08 ,  B01J8/20 ,  B01J8/00 ,  B01J8/06 ,  B01J19/00 ,  B01J19/24 ,  C07F9/141 ,  C07F9/38 ,  C07F9/40

Abstract: The invention relates to a method for carrying out a solid-liquid reaction, according to which a) a reaction suspension is prepared, containing a first reactant which is suspended in a suspension medium and a second reactant which is dissolved in the same, one of the reaction products being insoluble in the suspension medium, b) the reaction suspension is guided through a longish reaction zone, the Reynolds number of the flow being less than 20,000, and c) the insoluble reaction product formed is separated. The method is advantageous in that the insoluble reaction product is obtained in a form which is easy to filter.

公开(公告)号：AT385249T

公开(公告)日：2008-02-15

申请号：AT03795855

申请日：2003-11-28

Applicant: BASF AG

Inventor： KLOPP INGO ,  GONZALEZ GOMEZ JUAN ANTONIO ,  MAUTHE UWE ,  REISACHER HANSULRICH ,  STOHR ANDREAS

IPC: C09B67/20 ,  C08K9/04 ,  C08K9/08 ,  C09B67/00 ,  C09B67/22 ,  C09C3/08 ,  C09D7/12 ,  C09D11/02

Abstract: Solid pigment preparations containing the following ingredients as substantial components: (A) 60-85 wt. % of at least one organic pigment, (B) 0.1-15 wt. % of at least one pigment derivative of general formula I wherein the variables have the following meanings: P is the radical of the parent substance of an organic pigment; T 1 , T 2 independently represent a chemical bond, -CONR 1 - or -SO 2 NR 1 -; B 1 , B 2 independently represent a chemical bond, C1-C8-alkylene or phenylene;X, Y independently represent similar or different groups -SO 3 - Ka + or -COO- Ka + ; m, n represent a rational number from 0 to 3, whereby 1=m+n=4; Ka + H + , Li + , Na + , K + , N + R 2 R 3 R 4 R 5 or a mixture of said cations; R 1 represents hydrogen; C 1 -C 4 -alkyl; phenyl or naphthyl which can be respectively substituted by C 1 -C 18 -alkyl; R 2 , R 3 , R 4 , R 5 independently represent hydrogen; C 1 -C 30 -alkyl; C 3 -C 30 -alkenyl; C 5 -C 6 -cycloalkyl which can be substituted by C 1 -C 24 -alkyl; phenyl or naphthyl which can be respectively substituted by C 1 -C 24 -alkyl or C 2 -C 24 -alkenyl; a radical of formula -[CHR 6 -CHR 7 -O]x-R 8 , wherein the repeating units -[CHR 6 -CHR 7 -O] for x> 1 can vary; R 6 , R 7 , R 8 independently represent hydrogen or C 1 -C 6 -alkyl; x is a whole number= 1 , and (C) 14.9 39.9 wt. % of at least one surface active additive from the group of non-ionic polyethers containing no primary amino groups, the acidic phosphoric acid esters,phosphonic acid esters, sulphuric acid esters and/or sulfonic acid esters thereof, the salts thereof and the condensation produces thereof with formaldehyde.

公开(公告)号：IN1211CH2004A

公开(公告)日：2006-02-10

申请号：IN1211CH2004

申请日：2004-06-01

Applicant: BASF AG

Inventor： KLOPP INGO ,  BOGENSTAETTER THOMAS ,  FRANKE DIRK

IPC: C07C51/41 ,  C07C20060101 ,  C07C63/00 ,  C07C63/04 ,  C07C63/08

Abstract: A process is described for preparing ammonium salts of aromatic carboxylic acids by reacting an aromatic carboxylic acid with ammonia in an aprotic solvent, which comprises carrying out the reaction in a closed vessel by continuously introducing a solution of the aromatic carboxylic acid in the aprotic solvent and passing in gaseous ammonia so that an ammonia partial pressure in the range from 0.1 to 3 bar is maintained in the gas space of the vessel, and discharging a suspension of the ammonium salt in the aprotic solvent. The process allows the preparation of ammonium salts of defined crystal size having a narrow size distribution.

公开(公告)号：IN432CH2004A

公开(公告)日：2005-12-23

申请号：IN432CH2004

申请日：2004-03-01

Applicant: BASF AG

Inventor： KLOPP INGO ,  BOGENSTAETTER THOMAS ,  FRANKE DIRK ,  MUNZINGER MANFRED

IPC: B01J8/08 ,  B01J8/00 ,  B01J8/06 ,  B01J8/20 ,  B01J19/00 ,  B01J19/24 ,  C07F9/141 ,  C07F9/38 ,  C07F9/40

Abstract: A process for carrying out a liquid/solid reaction comprises a) preparing a reaction suspension in which a first reactant is present in suspended form and a second reactant is present in dissolved form in a suspension medium, where one of the reaction products is insoluble in the suspension medium, b) passing the reaction suspension through an elongated reaction zone so that the Reynolds number of the stream is less than 20,000 and c) separating off the insoluble reaction product formed. The process has the advantage that the insoluble reaction product is obtained in a readily filterable form.

公开(公告)号：SI1423187T1

公开(公告)日：2005-08-31

申请号：SI200230122

申请日：2002-08-29

Applicant: BASF AG

Inventor： KLOPP INGO ,  BOGENSTAETTER THOMAS ,  FRANKE DIRK ,  MUNZINGER MANFRED

IPC: B01J8/00 ,  B01J8/06 ,  B01J8/20 ,  B01J19/00 ,  B01J19/24 ,  B01J8/08 ,  C07F9/141 ,  C07F9/38 ,  C07F9/40

Abstract: A process for carrying out a liquid/solid reaction comprises a) preparing a reaction suspension in which a first reactant is present in suspended form and a second reactant is present in dissolved form in a suspension medium, where one of the reaction products is insoluble in the suspension medium, b) passing the reaction suspension through an elongated reaction zone so that the Reynolds number of the stream is less than 20,000 and c) separating off the insoluble reaction product formed. The process has the advantage that the insoluble reaction product is obtained in a readily filterable form.

公开(公告)号：DK1423187T3

公开(公告)日：2005-06-27

申请号：DK02767452

申请日：2002-08-29

Applicant: BASF AG

Inventor： KLOPP INGO ,  MUNZINGER MANFRED ,  BOGENSTAETTER THOMAS ,  FRANKE DIRK

IPC: B01J8/08 ,  B01J8/00 ,  B01J8/06 ,  B01J8/20 ,  B01J19/00 ,  B01J19/24 ,  C07F9/141 ,  C07F9/38 ,  C07F9/40

Abstract: A process for carrying out a liquid/solid reaction comprises a) preparing a reaction suspension in which a first reactant is present in suspended form and a second reactant is present in dissolved form in a suspension medium, where one of the reaction products is insoluble in the suspension medium, b) passing the reaction suspension through an elongated reaction zone so that the Reynolds number of the stream is less than 20,000 and c) separating off the insoluble reaction product formed. The process has the advantage that the insoluble reaction product is obtained in a readily filterable form.