公开(公告)号：WO2005078023A2

公开(公告)日：2005-08-25

申请号：PCT/EP2005001139

申请日：2005-02-04

Applicant: BASF AG ,  ERK PETER ,  STOHR ANDREAS ,  BOEHM ARNO ,  KURTZ WALTER ,  MIZUGUCHI JIN ,  SENS BENNO

Inventor： ERK PETER ,  STOHR ANDREAS ,  BOEHM ARNO ,  KURTZ WALTER ,  MIZUGUCHI JIN ,  SENS BENNO

IPC: C09B5/62 ,  C09B67/22 ,  C09B5/00

CPC classification number: C09B5/62 ,  C09B67/0034

Abstract: Disclosed are black perylene pigments containing one of the isomers of formula (Ia) or (Ib), wherein the variables have the following meaning: R , R independently represent phenylene, naphthylene, or pyridylene, each of which can be monosubstituted or polysubstituted by C1-C12 alkyl, C1-C6 alkoxy, hydroxy, nitro, and/or halogen; X represents halogen; n represents 0 to 4. The inventive black perylene pigments alternatively contain a mixture of both isomers and are provided with a black number >= 210 in an alkyd/melamine baking enamel.

Abstract translation: 黑色苝颜料，式异构体（Ia）或（Ib）中，其中各变量具有以下含义的一个，R <1>，R <2>独立地为亚苯基，亚萘基或亚吡啶基，其中的每一个单或C1取代 -C12烷基，C1-C6烷氧基，羟基，硝基和/或卤素; X卤素; n 0至4，或两种异构体的混合物，并且在醇酸/三聚氰胺烘烤漆中黑色数>≥210。

公开(公告)号：DE102004007382A1

公开(公告)日：2005-09-01

申请号：DE102004007382

申请日：2004-02-11

Applicant: BASF AG

Inventor： ERK PETER ,  STOHR ANDREAS ,  BOEHM ARNO ,  KURTZ WALTER ,  MIZUGUCHI JIN

IPC: C09B5/62 ,  C09B3/14 ,  C09B67/20

Abstract: Black perylene pigments (I) comprising fused-ring dipyridoperylenedione isomers and having a black number of at least 210 in an alkyd/melamine stoving lacquer are new. Black perylene pigments (I) comprising fused-ring dipyridoperylenedione isomers of formula (Ia) and/or (Ib) and having a black number of at least 210 in an alkyd/melamine stoving lacquer are new. [Image] [Image] R 1>, R 2>phenylene, naphthylene or pyridylene, all optionally substituted with 1-12C alkyl, 1-6C alkoxy, OH, NO 2 and/or halo; X : halo; n : 0-4. Independent claims are also included for: (1) producing the perylene pigments from synthetically produced crude pigments by either comminution and optionally recrystallization from a liquid medium or comminution and simultaneous recrystallization; (2) producing the crude pigments by condensing perylene-3,4;9,10-tetracarboxylic acid dianhydride with an aromatic ortho-diamine and cyclizing the product, where condensation and cyclization are effected in a reaction medium comprising phenol or a non-fused nitrogen-containing heteroaromatic compound; (3) pigment synergists comprising isomers of formula (Ia') or (Ib'). [Image] [Image] R 1>', R 2>' : phenylene, naphthylene or pyridylene, all substituted with COOM, COOR 3>, CONR 3>R 4>, COO -> N +>R 3>R 4>R 5>R 6>, SO 2NR 3>R 4>, CH 2NR 3>R 4>, CH 2N +>R 3>R 4>R 5>R 6> R 3>COO -> and/or CH 2R 7> and optionally substituted with 1-12C alkyl, 1-6C alkoxy, OH, NO 2 and/or halo; R 3>-R 6>H; 1-12C alkyl or 2-12C alkenyl optionally interrupted by O, S, NR 8>, CO or SO 2 and optionally substituted with OH, halo, aryl, 1-4C alkoxy and/or acetyl; or 3-8C cycloalkyl optionally interrupted by O, S, NR 8> or CO and optionally substituted with acetyl; R 7>phthalimidyl; R 8>H or 1-8C alkyl; M : H or metal; X : halo; n : 0-4.

公开(公告)号：DE102004057876A1

公开(公告)日：2006-06-01

申请号：DE102004057876

申请日：2004-11-30

Applicant: BASF AG

Inventor： ERK PETER ,  STOHR ANDREAS ,  BOEHM ARNO ,  KURTZ WALTER ,  SENS BENNO ,  MIZUGUCHI JIN

IPC: C09B5/62 ,  C09B67/22 ,  C09D11/02 ,  D06P1/642 ,  D06P3/32

Abstract: Black perylene pigments (I) comprising fused-ring dipyridoperylenedione isomers and having a black number of at least 210 in an alkyd/melamine stoving lacquer are new. Black perylene pigments (I) comprising fused-ring dipyridoperylenedione isomers of formula (Ia) and/or (Ib) and having a black number of at least 210 in an alkyd/melamine stoving lacquer are new. [Image] [Image] R 1>, R 2>phenylene, naphthylene or pyridylene, all optionally substituted with 1-12C alkyl, 1-6C alkoxy, OH, NO 2 and/or halo; X : halo; n : 0-4. Independent claims are also included for: (1) producing the perylene pigments from synthetically produced crude pigments by either comminution and optionally recrystallization from a liquid medium or comminution and simultaneous recrystallization; (2) producing the crude pigments by condensing perylene-3,4;9,10-tetracarboxylic acid dianhydride with an aromatic ortho-diamine and cyclizing the product, where condensation and cyclization are effected in a reaction medium comprising phenol or a non-fused nitrogen-containing heteroaromatic compound; (3) pigment synergists comprising isomers of formula (Ia') or (Ib'). [Image] [Image] R 1>', R 2>' : phenylene, naphthylene or pyridylene, all substituted with COOM, COOR 3>, CONR 3>R 4>, COO -> N +>R 3>R 4>R 5>R 6>, SO 2NR 3>R 4>, CH 2NR 3>R 4>, CH 2N +>R 3>R 4>R 5>R 6> R 3>COO -> and/or CH 2R 7> and optionally substituted with 1-12C alkyl, 1-6C alkoxy, OH, NO 2 and/or halo; R 3>-R 6>H; 1-12C alkyl or 2-12C alkenyl optionally interrupted by O, S, NR 8>, CO or SO 2 and optionally substituted with OH, halo, aryl, 1-4C alkoxy and/or acetyl; or 3-8C cycloalkyl optionally interrupted by O, S, NR 8> or CO and optionally substituted with acetyl; R 7>phthalimidyl; R 8>H or 1-8C alkyl; M : H or metal; X : halo; n : 0-4.