公开(公告)号：DE3673101D1

公开(公告)日：1990-09-06

申请号：DE3673101

申请日：1986-09-04

Applicant: BASF AG

Inventor： GRAF HERMANN DR ,  WAHL PETER DR ,  RENTZEA COSTIN DR ,  SAUTER HUBERT DR ,  AMMERMANN EBERHARD DR ,  POMMER ERNST-HEINRICH DR

IPC: A01N43/90 ,  C07D487/04

公开(公告)号：DE3620841A1

公开(公告)日：1987-12-23

申请号：DE3620841

申请日：1986-06-21

Applicant: BASF AG

Inventor： EICKEN KARL DR ,  WAHL PETER DR ,  AMMERMANN EBERHARD DR ,  POMMER ERNST-HEINRICH DR

IPC: A01N43/54 ,  C07D239/48 ,  C07D401/04 ,  C07D413/04

公开(公告)号：ES2178802T3

公开(公告)日：2003-01-01

申请号：ES98120710

申请日：1998-10-31

Applicant: BASF AG

Inventor： VOIT GUIDO DR ,  WITZEL TOM DR ,  BREITSCHEIDEL BORIS DR ,  LUYKEN HERMANN ,  ROSS KARL-HEINZ DR ,  WAHL PETER DR

IPC: C07C209/26 ,  C07C209/48 ,  C07C209/52 ,  C07C211/36

Abstract: 3-Aminomethyl-3,5,5-trimethyl-cyclohexylamine (IPDA) with a cis:trans isomer ratio of at least 70/30 is obtained by catalytic imination of 3-cyano-3,5,5-trimethyl-cyclohexanone (IPN) followed by catalytic hydrogenation of the resulting imine in presence of an acid. A process for the production of IPDA with a cis:trans isomer ratio of at least 70/30 comprises: (a) imination of IPN with ammonia in presence of an imination catalyst at 20-150 degrees C and 1.5-30 Mpa, and (b) hydrogenation of the resulting imine at 80-160 degrees C and 5-30 Mpa in presence of ammonia on catalysts containing copper and/or a Group VIII metal and also in presence of an acid in amounts corresponding to an acid number of 0.1-2 based on the IPN used.

公开(公告)号：DE59804409D1

公开(公告)日：2002-07-18

申请号：DE59804409

申请日：1998-10-31

Applicant: BASF AG

Inventor： VOIT GUIDO DR ,  WITZEL TOM DR ,  BREITSCHEIDEL BORIS DR ,  LUYKEN HERMANN ,  ROSS KARL-HEINZ DR ,  WAHL PETER DR

IPC: C07C209/26 ,  C07C209/48 ,  C07C209/52 ,  C07C211/36

Abstract: 3-Aminomethyl-3,5,5-trimethyl-cyclohexylamine (IPDA) with a cis:trans isomer ratio of at least 70/30 is obtained by catalytic imination of 3-cyano-3,5,5-trimethyl-cyclohexanone (IPN) followed by catalytic hydrogenation of the resulting imine in presence of an acid. A process for the production of IPDA with a cis:trans isomer ratio of at least 70/30 comprises: (a) imination of IPN with ammonia in presence of an imination catalyst at 20-150 degrees C and 1.5-30 Mpa, and (b) hydrogenation of the resulting imine at 80-160 degrees C and 5-30 Mpa in presence of ammonia on catalysts containing copper and/or a Group VIII metal and also in presence of an acid in amounts corresponding to an acid number of 0.1-2 based on the IPN used.

公开(公告)号：DE19507398C1

公开(公告)日：1996-09-12

申请号：DE19507398

申请日：1995-03-03

Applicant: BASF AG

Inventor： VOIT GUIDO DR ,  WITZEL TOM DR ,  BREITSCHEIDEL BORIS DR ,  HARDER WOLFGANG DR ,  LUYKEN HERMANN ,  PAUL AXEL DR ,  ROS KARL-HEINZ DR ,  WAHL PETER DR

IPC: B01J23/46 ,  B01J23/75 ,  B01J23/755 ,  C07B61/00 ,  C07C209/48 ,  C07C211/36 ,  C07C209/22

Abstract: Prepn. of 3-aminomethyl-3,5,5-trimethylcyclohexylamine (isophorone diamine; IPDA) from 3-cyano-3,5,5-trimethyl-cyclohexanone (isophorone nitrile; IPN) is carried out in three separate reaction zones by: (a) reacting IPN with excess liquid NH3 at 20-150 deg.C and 50-300 bar; (b) hydrogenating the reaction prod. with H2 in the presence of excess NH3 at 50-100 deg.C and 50-300 bar; and (c) hydrogenating the reaction prod. with N2 at 110-160 deg.C and 150-300 bar. Acidic metal oxide catalyst is used in stage (a); and hydrogenation catalyst, opt. with basic components or on neutral or basic supports, in stages (b) and (c).

公开(公告)号：GR3001545T3

公开(公告)日：1992-11-23

申请号：GR910400259

申请日：1991-03-04

Applicant: BASF AG

Inventor： EICKEN KARL DR ,  WAHL PETER DR ,  AMMERMANN EBERHARD DR ,  POMMER ERNST-HEINRICH DR

IPC: A01N43/54 ,  C07D239/48

公开(公告)号：DE3767785D1

公开(公告)日：1991-03-07

申请号：DE3767785

申请日：1987-06-20

Applicant: BASF AG

Inventor： EICKEN KARL DR ,  WAHL PETER DR ,  AMMERMANN EBERHARD DR ,  POMMER ERNST-HEINRICH DR

IPC: A01N43/54 ,  C07D239/48

公开(公告)号：AT55131T

公开(公告)日：1990-08-15

申请号：AT86112217

申请日：1986-09-04

Applicant: BASF AG

Inventor： GRAF HERMANN DR ,  WAHL PETER DR ,  RENTZEA COSTIN DR ,  SAUTER HUBERT DR ,  AMMERMANN EBERHARD DR ,  POMMER ERNST-HEINRICH DR

IPC: A01N43/90 ,  C07D487/04

公开(公告)号：DE3670487D1

公开(公告)日：1990-05-23

申请号：DE3670487

申请日：1986-02-10

Applicant: BASF AG

Inventor： EICKEN KARL DR ,  WAHL PETER DR ,  AMMERMANN EBERHARD DR ,  POMMER ERNST-HEINRICH DR

IPC: A01N43/54 ,  C07D239/46 ,  C07D405/12

公开(公告)号：DE3533050A1

公开(公告)日：1987-03-26

申请号：DE3533050

申请日：1985-09-17

Applicant: BASF AG

Inventor： GRAF HERMANN DR ,  WAHL PETER DR ,  RENTZEA COSTIN DR ,  SAUTER HUBERT DR ,  AMMERMANN EBERHARD DR ,  POMMER ERNST-HEINRICH DR

IPC: A01N43/90 ,  C07D487/04