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公开(公告)号:JPH1087620A
公开(公告)日:1998-04-07
申请号:JP22346097
申请日:1997-08-20
Applicant: BASF AG
Inventor: JULIUS MANFRED DR , HERMELING DIETER DR , SIEGEL HARDO DR , HARDER WOLFGANG DR
IPC: B01J31/02 , C07B61/00 , C07D211/74
Abstract: PROBLEM TO BE SOLVED: To provide a method, esp. continuous method, for affording 2,2,6,6- tetramethylpiperidin-4-one (TAA) in high yield and also in a shortened time under reduced labor. SOLUTION: The objective 2,2,6,6-tetramethylpiperidin-4-one (TTA) is obtained by reaction of mixture of acetone and/or acetone condensate and ammonia in the molar ratio of (20:1) to (3:1) at 50-130 deg.C in the presence of dimethyl sulfate at 0.5-5mol% based on the acetone.
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公开(公告)号:JP2002265423A
公开(公告)日:2002-09-18
申请号:JP2001395336
申请日:2001-12-26
Applicant: BASF AG
Inventor: FUNKE FRANK DR , STEINBRENNER ULRICH , ZEHNER PETER , BOEHLING RALF , HARDER WOLFGANG DR
IPC: C07C209/68 , C07B61/00 , C07C209/60 , C07C209/70 , C07C211/02 , C07C211/07 , C07C211/09 , C07C211/21
Abstract: PROBLEM TO BE SOLVED: To provide a process for preparing n-butylamines by which the defects in the prior art are overcome, and the desired n-butylamine, or two or more desired n-butylamines can be produced in a high space time yield and selectivity. SOLUTION: An n-butenyl amine is produced by reacting 1,3-butadiene in a shape of a 1,3-butadiene-containing mixture obtained when cracking a petroleum fragment, or when dehydrogenating LPG or LNG, or obtained by a GTL (gas to liquid) technique, with a primary amine and/or a secondary amine under a hydroamination condition, and the provided butenylamine(s) is reacted with hydrogen under an alkyl-exchanging reaction condition at the second process step to provide the objective n-butylamines.
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公开(公告)号:JPH10174875A
公开(公告)日:1998-06-30
申请号:JP29688697
申请日:1997-10-29
Applicant: BASF AG
Inventor: WULFF-DOERING JOACHIM DR , MELDER JOHANN-PETER DR , SCHULZ GERHARD DR , VOIT GUIDO DR , GUTSCHOVEN FRANK , HARDER WOLFGANG DR
IPC: B01J23/89 , B01J37/18 , C07B61/00 , C07C209/16 , C07C211/00 , C07C211/10
Abstract: PROBLEM TO BE SOLVED: To provide an amination catalyst small in the content of nickel and/or cobalt and having high selectivity and high stability about ethylene diamine obtained by aminating monoethanol amine with ammonia. SOLUTION: The catalyst is obtained by carrying 6-50wt.% cobalt, nickel or the mixture, 0.001-25wt.% ruthenium, 0-10wt.% copper and 0-5wt.% accelerator per total weight of the catalyst on a porous metal oxide carrier. In such a case, the catalyst is produced by (a) impregnating the carrier with the metal and the accelerator or the compound, (b) drying and calcining and (c) reducing with hydrogen flow, where without impregnating the carrier with a halogen compound.
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公开(公告)号:DE19723949A1
公开(公告)日:1998-12-10
申请号:DE19723949
申请日:1997-06-06
Applicant: BASF AG
Inventor: GROSCH GEORG HEINRICH DR , MUELLER ULRICH DR , WALCH ANDREAS DR , RIEBER NORBERT DR , HARDER WOLFGANG DR
IPC: B01J29/90 , B01J38/12 , B01J38/20 , C07B41/00 , C07C29/48 , C07C45/27 , C07C51/265 , C07D301/12
Abstract: The invention relates to a method for regenerating a zeolitic catalyst, comprising the following steps: (I) at least one partially deactivated catalyst is heated to a temperature ranging from 250 to 600 DEG C in an atmosphere containing less than 2 vol. % oxygen; (II) the catalyst is impinged upon by a gas flow at a temperature ranging from 250 to 800 DEG C, preferably 350 to 600 DEG C, said gas flow having an oxygen-delivering substance content or an oxygen content or a mixture of two or more thereof ranging from 0.1 to 4 vol. % and (III) the catalyst is impinged upon by a gas flow at a temperature ranging from 250 to 800 DEG C, preferably 350 to 600 DEG C, said gas flow having an oxygen-delivering substance content or an oxygen content or a mixture of two or more thereof ranging from over 4 to 100 vol. %.
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公开(公告)号:DE59405751D1
公开(公告)日:1998-05-28
申请号:DE59405751
申请日:1994-06-20
Applicant: BASF AG
Inventor: WITZEL TOM DR , KUMMER RUDOLF DR , MERGER FRANZ DR , VOIT GUIDO DR , BRUDERMUELLER MARTIN DR , PRIESTER CLAUS-ULRICH DR , HARDER WOLFGANG DR
IPC: C07C253/18 , C07C253/30 , C07C255/24
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公开(公告)号:CZ9701977A3
公开(公告)日:1998-03-18
申请号:CZ197797
申请日:1995-12-16
Applicant: BASF AG
Inventor: SCHNURR WERNER DR , FISCHER ROLF DR , BASSLER PETER DR , HARDER WOLFGANG DR
IPC: C07B61/00 , C07C253/30 , C07C255/24
CPC classification number: C07C253/30
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公开(公告)号:DE19634157A1
公开(公告)日:1998-02-26
申请号:DE19634157
申请日:1996-08-23
Applicant: BASF AG
Inventor: JULIUS MANFRED DR , HERMELING DIETER DR , SIEGEL HARDO DR , HARDER WOLFGANG DR
IPC: B01J31/02 , C07B61/00 , C07D211/74
Abstract: Preparation of 2,2,6,6-tetramethylpiperidin-4-one (TAA) comprises reacting a mixture of acetone and/or acetone condensate and ammonia (NH3) in (20-3):1 molar ratio at 50-130 degrees C in the presence of 0.5-5 mole-% dimethyl sulphate (DMS) w.r.t. acetone. Preferably the molar ratio of acetone and/or acetone condensate to NH3 is (10-3):1. The reaction is carried out continuously and the reaction mixture is in liquid form. The acetone condensate is mesityl oxide, diacetone alcohol, diacetone-amine, acetonine or phorone.
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公开(公告)号:DE19600708A1
公开(公告)日:1997-07-17
申请号:DE19600708
申请日:1996-01-11
Applicant: BASF AG
Inventor: MUELLER ULRICH DR , SCHULZ MICHAEL DR , GEHRER EUGEN DR , GROSCH GEORG HEINRICH DR , HARDER WOLFGANG DR , DEMBOWSKI JUERGEN DR
IPC: B01J29/04 , B01J29/89 , C01B15/029 , C07D301/04 , C07D301/06 , C07D303/04
Abstract: An oxidation catalyst based on titanium or vanadium silicalites with zeolith structure is characterised in that it contains 0.01-20 wt % of one or more lanthanide metals from the group lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium.
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公开(公告)号:ES2085066T3
公开(公告)日:1996-05-16
申请号:ES93105619
申请日:1993-04-05
Applicant: BASF AG
Inventor: GEHRER EUGEN DR , HARDER WOLFGANG DR , EBEL KLAUS DR , MELDER JOHANN-PETER DR , TELES JOAQUIM HENRIQUE DR
IPC: B01J31/02 , C07B61/00 , C07C45/75 , C07C47/19 , C07D233/88 , C07D249/14 , C07D277/42
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公开(公告)号:DE59301775D1
公开(公告)日:1996-04-11
申请号:DE59301775
申请日:1993-04-05
Applicant: BASF AG
Inventor: GEHRER EUGEN DR , HARDER WOLFGANG DR , EBEL KLAUS DR , MELDER JOHANN-PETER DR , TELES JOAQUIM HENRIQUE DR
IPC: B01J31/02 , C07B61/00 , C07C45/75 , C07C47/19 , C07D233/88 , C07D249/14 , C07D277/42
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