Laked tris- or tetracationic polymethine dyes

    公开(公告)号:DE4326889A1

    公开(公告)日:1995-02-16

    申请号:DE4326889

    申请日:1993-08-11

    Applicant: BASF AG

    Abstract: In laked tris- or tetracationic polymethine dyes the variables have the following meanings: A is the radical of a substituted or unsubstituted benzene or naphthalene nucleus which is fused onto the heterocycle; Y is nitrogen or phosphorus; R comprises identical or different members of the following radicals: C1-C18-alkyl groups whose carbon chain may be interrupted by oxygen atoms in ether function and which may carry up to three of the following substituents: carboxyl, C1-C4-alkanoyl, C1-C4-alkoxycarbonyl, C1-C4-alkanoylamino, C1-C4-alkoxycarbonylamino, acryloyloxy, methacryloyloxy, phenyl, amino, cyano, hydroxyl or halogen; and phenyl or C5-C7-cycloalkyl groups which may each carry up to three of the following substituents: C1-C4-alkyl, C1-C4-alkoxy or halogen; Z is -NR -; -O-; -S-; -C(CH3)2- or -CH=CH-, where R is a radical as defined for R; D is or where X is aryloxy or arylthio each of which may carry up to five of the following substituents: amino, halogen, nitro, cyano, isocyanato, isothiocyanato, hydroxyl, carboxyl, acryloyloxy, methacryloyloxy, C1-C12-alkyl, C2-C12-alkenyl, C1-C12-alkoxy, C1-C12- alkanoyl, C1-C12-alkanoyloxy, C1-C12-alkoxycarbonyl, C1-C12-alkoxycarbonyloxy, mono-(C1-C12-alkyl)amino and/or di-(C1-C12-alkyl)amino, in which the carbon chain of the alkyl radicals may be interrupted by oxygen atoms in ether function, and the alkyl radicals... Original abstract incomplete.

    PROCESS FOR THE PRODUCTION OF BASIC CHROMIUM-ALUMINIUM SULFATES

    公开(公告)号:DE3462018D1

    公开(公告)日:1987-02-19

    申请号:DE3462018

    申请日:1984-03-21

    Applicant: BASF AG

    Abstract: The invention relates to basic chromium aluminum sulfates which are soluble in cold water and are of the general formula CrxAl2-x(OH)2y. (SO4)3-y.n H2O where x is from 0.1 to 1.9, y is from 0.01 to 2 and n is from 4 to 24, and a process for the preparation thereof. The process comprises reacting chromium (III)-containing waste sulfuric acid having a water content of 20-50% by weight with aluminum oxide and/or aluminum oxide hydroxide and/or aluminum hydroxide at a temperature of 100 DEG to 200 DEG C. The molten product is converted to droplet form and allowed to solidify in free fall.

    Laked triscationic polymethine dyes

    公开(公告)号:DE4311723A1

    公开(公告)日:1994-10-13

    申请号:DE4311723

    申请日:1993-04-08

    Applicant: BASF AG

    Abstract: Laked triscationic polymethine dyes I where A is the radical of a benzene or naphthalene nucleus which is fused to the heterocycle and which can carry up to three of the following substituents: C1-C12-alkyl groups whose carbon chain can be interrupted by oxygen atoms in ether function, C1-C12-alkoxy, phenyl, phenoxy, phenylthio, cyano, amino, mono(C1-C12-alkyl)amino, di(C1-C12-alkyl)amino, hydroxyl or halogen; Y is nitrogen or phosphorus; R denotes identical or different ones of the following radicals: C1-C18-alkyl groups whose carbon chain can be interrupted by oxygen atoms in ether function and which can carry up to three of the following substituents: carboxyl, C1-C4-alkanoyl, C1-C4-alkoxycarbonyl, C1-C4-alkanoylamino, C1-C4-alkoxycarbonylamino, acryloyloxy, methacryloyloxy, phenyl, amino, cyano, hydroxyl or halogen; phenyl or C5-C7-cycloalkyl groups which can each carry up to three of the following substituents: C1-C4-alkyl, C1-C4-alkoxy or halogen; m is from 1 to 10; Z is -NR -; -O-; -S-; -C(CH3)2- or -CH=CH; where R is one of the radicals R of the type defined; D is -CX =; -CH=CX -CH=; where X is nitrogen, chlorine, bromine or C1-C6-alkyl; X is chlorine, cyano, C1-C12-alkoxy or C1-C12-alkylthio; X is hydrogen or C1-C6-alkyl; Het is the equivalent of a heteropolyacid anion.

    18.
    发明专利
    未知

    公开(公告)号:DE3671002D1

    公开(公告)日:1990-06-13

    申请号:DE3671002

    申请日:1986-06-25

    Applicant: BASF AG

    Abstract: Magnetite pigments are prepared from iron(II) salt solutions by a process in which the mean particle size can be brought to a value within the range from 0.06 to 0.5 mu m by means of a residence stage between the precipitation stage and the oxidation stage.

    19.
    发明专利
    未知

    公开(公告)号:DE3643247A1

    公开(公告)日:1988-06-30

    申请号:DE3643247

    申请日:1986-12-18

    Applicant: BASF AG

    Abstract: Thermostable bismuth vanadate/molybdate pigments are prepared by precipitating onto a pigment, obtained by calcination, of the formula Bi VO4.Bi2Mo O6 where n is 0.2-2.5, in aqueous suspension at 70 DEG -100 DEG C. within the pH range from 4 to 9.5 a first SiO2-containing layer using an alkali metal silicate solution of a magnesium hexafluorosilicate solution, maintaining the suspension at 70 DEG -100 DEG C. for not less than 1 hour, producing a thick coating on the precoated pigment by adding further alkali metal silicate solution, magnesium hexafluorosilicate solution or a mixture of the two within the pH range from 4 to 9.5, and finally depositing wax on the SiO2-containing layer by means of a waxing emulsion/dispersion, the products showing, compared with the starting pigment, an appreciably improved thermal stability in plastics.

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