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公开(公告)号:ES2072689T3
公开(公告)日:1995-07-16
申请号:ES92121741
申请日:1992-12-21
Applicant: BASF AG
Inventor: LIEDEK EGON DR , KNITTEL HELMUT DR , REISACHER HANS-ULRICH DR , MRONGA NORBERT DR , OCHMANN HARALD DR , WIENAND HENNING DR
Abstract: Essentially monoclinic, according to X-ray crystallography, bismuth vanadate having the formula Bi[(V1-xPx)O4] in which x is from 0 to 0.1, characterised by a chroma of >/=85, a lightness of >/=80, a hue angle of from 89 to 95 and a photochromaticity having a DELTA E value of
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公开(公告)号:DE4326889A1
公开(公告)日:1995-02-16
申请号:DE4326889
申请日:1993-08-11
Applicant: BASF AG
Inventor: CLOSS FRIEDRICH DR , ALBERT BERNHARD DR , WIENAND HENNING DR
IPC: B44F1/12 , C09B23/01 , C09B23/08 , C09B69/06 , C09D11/328 , C09B63/00 , B41M3/14 , C08J3/20 , C09D11/02 , C09D17/00 , D06P1/42
Abstract: In laked tris- or tetracationic polymethine dyes the variables have the following meanings: A is the radical of a substituted or unsubstituted benzene or naphthalene nucleus which is fused onto the heterocycle; Y is nitrogen or phosphorus; R comprises identical or different members of the following radicals: C1-C18-alkyl groups whose carbon chain may be interrupted by oxygen atoms in ether function and which may carry up to three of the following substituents: carboxyl, C1-C4-alkanoyl, C1-C4-alkoxycarbonyl, C1-C4-alkanoylamino, C1-C4-alkoxycarbonylamino, acryloyloxy, methacryloyloxy, phenyl, amino, cyano, hydroxyl or halogen; and phenyl or C5-C7-cycloalkyl groups which may each carry up to three of the following substituents: C1-C4-alkyl, C1-C4-alkoxy or halogen; Z is -NR -; -O-; -S-; -C(CH3)2- or -CH=CH-, where R is a radical as defined for R; D is or where X is aryloxy or arylthio each of which may carry up to five of the following substituents: amino, halogen, nitro, cyano, isocyanato, isothiocyanato, hydroxyl, carboxyl, acryloyloxy, methacryloyloxy, C1-C12-alkyl, C2-C12-alkenyl, C1-C12-alkoxy, C1-C12- alkanoyl, C1-C12-alkanoyloxy, C1-C12-alkoxycarbonyl, C1-C12-alkoxycarbonyloxy, mono-(C1-C12-alkyl)amino and/or di-(C1-C12-alkyl)amino, in which the carbon chain of the alkyl radicals may be interrupted by oxygen atoms in ether function, and the alkyl radicals... Original abstract incomplete.
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公开(公告)号:DE3462018D1
公开(公告)日:1987-02-19
申请号:DE3462018
申请日:1984-03-21
Applicant: BASF AG
Inventor: OSTERTAG WERNER DR , WIENAND HENNING DR , LACH DIETRICH DR , HAHN ERWIN DR
Abstract: The invention relates to basic chromium aluminum sulfates which are soluble in cold water and are of the general formula CrxAl2-x(OH)2y. (SO4)3-y.n H2O where x is from 0.1 to 1.9, y is from 0.01 to 2 and n is from 4 to 24, and a process for the preparation thereof. The process comprises reacting chromium (III)-containing waste sulfuric acid having a water content of 20-50% by weight with aluminum oxide and/or aluminum oxide hydroxide and/or aluminum hydroxide at a temperature of 100 DEG to 200 DEG C. The molten product is converted to droplet form and allowed to solidify in free fall.
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公开(公告)号:ES2154762T3
公开(公告)日:2001-04-16
申请号:ES96112493
申请日:1996-08-02
Applicant: BASF AG
Inventor: OCHMANN HARALD DR , REISACHER HANSULRICH DR , KNITTEL HELMUT , MRONGA NORBERT DR , ETZRODT GUNTER DR , WIENAND HENNING DR
IPC: C01G49/00 , C08K3/18 , C08K3/28 , C08K3/32 , C09C1/00 , C09C1/02 , C09C1/04 , C09C1/22 , C09C1/28 , C09D7/12 , C09D11/02
Abstract: Bi vanadate pigments of the formula BixFeyEvV(1-w)PwOz (I) are new; in which E = Ca, Zn, Ce, Pr and/or Si; x = 0.8-1.2; y > 0 to 0.1 if v > 0 and y ≥ 0.035 to 0.1 if v = 0; v ≥ 0 to 0.2; w > 0 to 0.1; z = the no. of O atoms to satisfy the valencies of the cations.
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公开(公告)号:DE59400978D1
公开(公告)日:1996-12-12
申请号:DE59400978
申请日:1994-03-24
Applicant: BASF AG
Inventor: KLINGELHOEFER PAUL DR , SCHWIDETZKY CHRISTOPH DR , WIENAND HENNING DR , MRONGA NORBERT DR , SCHWAB EKKEHARD DR , NEBEL MICHAEL
Abstract: Preparation of transparent yellow iron oxide pigments by precipitation of iron(II) hydroxide by addition of an inorganic base to an iron(II) salt solution and subsequent oxidation to FeOOH, in which a) an aqueous iron(II) salt solution having a molarity of at least 0.5 is first admixed at from 25 to 45@C in the presence of dissolved phosphates and, if desired, zinc salts with sufficient base for from 50 to 70% of the iron(II) ions used to be precipitated as hydroxide, then oxidising gas is passed through the mixture obtained until the pH has dropped to a value
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公开(公告)号:DE59202344D1
公开(公告)日:1995-06-29
申请号:DE59202344
申请日:1992-12-21
Applicant: BASF AG
Inventor: LIEDEK EGON DR , KNITTEL HELMUT DR , REISACHER HANS-ULRICH DR , MRONGA NORBERT DR , OCHMANN HARALD DR , WIENAND HENNING DR
Abstract: Essentially monoclinic, according to X-ray crystallography, bismuth vanadate having the formula Bi[(V1-xPx)O4] in which x is from 0 to 0.1, characterised by a chroma of >/=85, a lightness of >/=80, a hue angle of from 89 to 95 and a photochromaticity having a DELTA E value of
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公开(公告)号:DE4311723A1
公开(公告)日:1994-10-13
申请号:DE4311723
申请日:1993-04-08
Applicant: BASF AG
Inventor: CLOSS FRIEDRICH DR , ALBERT BERNHARD DR , WIENAND HENNING DR
IPC: C09B23/01 , C09B23/08 , C09B69/06 , C09D11/037 , C09B63/00 , C08K5/3417 , C09D11/02 , C09D17/00
Abstract: Laked triscationic polymethine dyes I where A is the radical of a benzene or naphthalene nucleus which is fused to the heterocycle and which can carry up to three of the following substituents: C1-C12-alkyl groups whose carbon chain can be interrupted by oxygen atoms in ether function, C1-C12-alkoxy, phenyl, phenoxy, phenylthio, cyano, amino, mono(C1-C12-alkyl)amino, di(C1-C12-alkyl)amino, hydroxyl or halogen; Y is nitrogen or phosphorus; R denotes identical or different ones of the following radicals: C1-C18-alkyl groups whose carbon chain can be interrupted by oxygen atoms in ether function and which can carry up to three of the following substituents: carboxyl, C1-C4-alkanoyl, C1-C4-alkoxycarbonyl, C1-C4-alkanoylamino, C1-C4-alkoxycarbonylamino, acryloyloxy, methacryloyloxy, phenyl, amino, cyano, hydroxyl or halogen; phenyl or C5-C7-cycloalkyl groups which can each carry up to three of the following substituents: C1-C4-alkyl, C1-C4-alkoxy or halogen; m is from 1 to 10; Z is -NR -; -O-; -S-; -C(CH3)2- or -CH=CH; where R is one of the radicals R of the type defined; D is -CX =; -CH=CX -CH=; where X is nitrogen, chlorine, bromine or C1-C6-alkyl; X is chlorine, cyano, C1-C12-alkoxy or C1-C12-alkylthio; X is hydrogen or C1-C6-alkyl; Het is the equivalent of a heteropolyacid anion.
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公开(公告)号:DE3671002D1
公开(公告)日:1990-06-13
申请号:DE3671002
申请日:1986-06-25
Applicant: BASF AG
Inventor: OSTERTAG WERNER DR , WIENAND HENNING DR , BAUER ROLAND
Abstract: Magnetite pigments are prepared from iron(II) salt solutions by a process in which the mean particle size can be brought to a value within the range from 0.06 to 0.5 mu m by means of a residence stage between the precipitation stage and the oxidation stage.
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公开(公告)号:DE3643247A1
公开(公告)日:1988-06-30
申请号:DE3643247
申请日:1986-12-18
Applicant: BASF AG
Abstract: Thermostable bismuth vanadate/molybdate pigments are prepared by precipitating onto a pigment, obtained by calcination, of the formula Bi VO4.Bi2Mo O6 where n is 0.2-2.5, in aqueous suspension at 70 DEG -100 DEG C. within the pH range from 4 to 9.5 a first SiO2-containing layer using an alkali metal silicate solution of a magnesium hexafluorosilicate solution, maintaining the suspension at 70 DEG -100 DEG C. for not less than 1 hour, producing a thick coating on the precoated pigment by adding further alkali metal silicate solution, magnesium hexafluorosilicate solution or a mixture of the two within the pH range from 4 to 9.5, and finally depositing wax on the SiO2-containing layer by means of a waxing emulsion/dispersion, the products showing, compared with the starting pigment, an appreciably improved thermal stability in plastics.
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公开(公告)号:DE3260275D1
公开(公告)日:1984-07-26
申请号:DE3260275
申请日:1982-08-30
Applicant: BASF AG
Inventor: WIENAND HENNING DR , OSTERTAG WERNER DR , BITTLER KNUT DR
IPC: C09C1/00
Abstract: Yellow pigments containing bismuth vanadate and having the composition BiVO4.xBi2MoO6.yBi2WO6 where x is from 0.6 to 2.25 and y is from 0 to 0.1, are prepared by a process in which a solution containing a bismuth(III) salt, a vanadate and a molybdate is acidified until the pH is
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