公开(公告)号：JPH09156928A

公开(公告)日：1997-06-17

申请号：JP21287696

申请日：1996-08-12

Applicant: BASF AG

Inventor： OCHMANN HARALD ,  REISACHER HANSULRICH ,  KNITTEL HELMUT ,  MRONGA NORBERT ,  ETZRODT GUENTER ,  WIENAND HENNING

IPC: C01G49/00 ,  C08K3/18 ,  C08K3/28 ,  C08K3/32 ,  C09C1/00 ,  C09C1/02 ,  C09C1/04 ,  C09C1/22 ,  C09C1/28 ,  C09D7/12 ,  C09D11/02

公开(公告)号：GB2118576A

公开(公告)日：1983-11-02

申请号：GB8305190

申请日：1983-02-24

Applicant: BASF AG

Inventor： HABERMANN WOLFGANG ,  HAMMES PETER ,  FELGER JOACHIM ,  HOCK KARL-LUDWIG ,  BRUNNMUELLER FRIEDRICH ,  KNITTEL HELMUT ,  KRANZ JOACHIM ,  SCHNEIDER ROLF ,  THOMA PETER

IPC: C09C1/26 ,  C25B1/00

Abstract: Blue iron hexacyanoferrate-III pigments are produced by a process wherein complex iron-II hexacyanoferrate-II (Berlin white) is prepared by electrolysis of an aqueous catholyte solution containing (a) an iron-II salt, (b) an alkali metal salt, an ammonium salt or a mixture of these, and (c) hydrogen cyanide, in an electrolysis cell in which the anode chamber and cathode chamber are separated by an ion exchange membrane, using an electrically conductive aqueous liquid in the anode chamber, and the iron-II hexacyanoferrate-II obtained is then converted to the blue pigment. The process gives Berlin white, which is substantially free from salt, in high yield and high purity. Pollution caused by the process is very low, since only a small amount of salt is produced. Compared with the corresponding blue pigments produced by prior art processes, the pigments obtained give purer colorations with better gloss, and are of higher color strength.

公开(公告)号：GB2118576B

公开(公告)日：1985-05-15

申请号：GB8305190

申请日：1983-02-24

Applicant: BASF AG

Inventor： HABERMANN WOLFGANG ,  HAMMES PETER ,  FELGER JOACHIM ,  HOCK KARL-LUDWIG ,  BRUNNMUELLER FRIEDRICH ,  KNITTEL HELMUT ,  KRANZ JOACHIM ,  SCHNEIDER ROLF ,  THOMA PETER

IPC: C09C1/26 ,  C25B1/00

Abstract: Blue iron hexacyanoferrate-III pigments are produced by a process wherein complex iron-II hexacyanoferrate-II (Berlin white) is prepared by electrolysis of an aqueous catholyte solution containing (a) an iron-II salt, (b) an alkali metal salt, an ammonium salt or a mixture of these, and (c) hydrogen cyanide, in an electrolysis cell in which the anode chamber and cathode chamber are separated by an ion exchange membrane, using an electrically conductive aqueous liquid in the anode chamber, and the iron-II hexacyanoferrate-II obtained is then converted to the blue pigment. The process gives Berlin white, which is substantially free from salt, in high yield and high purity. Pollution caused by the process is very low, since only a small amount of salt is produced. Compared with the corresponding blue pigments produced by prior art processes, the pigments obtained give purer colorations with better gloss, and are of higher color strength.

公开(公告)号：EP0758670A3

公开(公告)日：1998-06-03

申请号：EP96112493

申请日：1996-08-02

Applicant: BASF AG

Inventor： OCHMANN HARALD DR ,  REISACHER HANSULRICH DR ,  KNITTEL HELMUT ,  MRONGA NORBERT DR ,  ETZRODT GUENTER DR ,  WIENAND HENNING DR

IPC: C01G49/00 ,  C08K3/18 ,  C08K3/28 ,  C08K3/32 ,  C09C1/00 ,  C09C1/02 ,  C09C1/04 ,  C09C1/22 ,  C09C1/28 ,  C09D7/12 ,  C09D11/02

CPC classification number: C09D11/037 ,  C01P2004/84 ,  C01P2006/60 ,  C08K3/013 ,  C08K3/32 ,  C09C1/0006 ,  C09C1/22 ,  C09D7/62

Abstract: Bismutvanadatpigmente I
Bi
x Fe
y E
v V
(1-w) P
w O
z
mit folgender Bedeutung der Variablen:

E

Calcium, Zink, Cer, Praseodym und/oder Silicium;

x

0,8 bis 1,2;

y

> 0 bis 0,1, wenn v > 0 ist, und
≥ 0,035 bis 0,1, wenn v = 0 ist;

v

≥ 0 bis 0,2;

w

> 0 bis 0,1;

z

Zahl der Sauerstoffatome zur Erfüllung der Valenzerfordernisse der Kationen.

sowie Herstellung und Verwendung dieser Pigmente zum Einfärben von Lacken, Druckfarben und Kunststoffen.

公开(公告)号：MX9300173A

公开(公告)日：1993-07-01

申请号：MX9300173

申请日：1993-01-13

Applicant: BASF AG

Inventor： LIEDEK EGON ,  KNITTEL HELMUT ,  REISACHER HANS-ULRICH ,  MRONGA NORBERT ,  OCHMANN HARALD ,  WIENAND HENNING

IPC: C01B25/45 ,  C01G31/00 ,  C09C1/00 ,  C09C1/62

Abstract: Essentially monoclinic, according to X-ray crystallography, bismuth vanadate having the formula Bi[(V1-xPx)O4] in which x is from 0 to 0.1, characterised by a chroma of >/=85, a lightness of >/=80, a hue angle of from 89 to 95 and a photochromaticity having a DELTA E value of

公开(公告)号：DE59606454D1

公开(公告)日：2001-03-29

申请号：DE59606454

申请日：1996-08-02

Applicant: BASF AG

Inventor： OCHMANN HARALD ,  REISACHER HANSULRICH ,  KNITTEL HELMUT ,  MRONGA NORBERT ,  ETZRODT GUENTER ,  WIENAND HENNING

IPC: C01G49/00 ,  C08K3/18 ,  C08K3/28 ,  C08K3/32 ,  C09C1/00 ,  C09C1/02 ,  C09C1/04 ,  C09C1/22 ,  C09C1/28 ,  C09D7/12 ,  C09D11/02

Abstract: Bi vanadate pigments of the formula BixFeyEvV(1-w)PwOz (I) are new; in which E = Ca, Zn, Ce, Pr and/or Si; x = 0.8-1.2; y > 0 to 0.1 if v > 0 and y ≥ 0.035 to 0.1 if v = 0; v ≥ 0 to 0.2; w > 0 to 0.1; z = the no. of O atoms to satisfy the valencies of the cations.

公开(公告)号：DE19529837A1

公开(公告)日：1997-02-13

申请号：DE19529837

申请日：1995-08-12

Applicant: BASF AG

Inventor： OCHMANN HARALD ,  REISACHER HANSULRICH ,  KNITTEL HELMUT ,  MRONGA NORBERT ,  ETZRODT GUENTER ,  WIENAND HENNING DR

IPC: C01G49/00 ,  C08K3/18 ,  C08K3/28 ,  C08K3/32 ,  C09C1/00 ,  C09C1/02 ,  C09C1/04 ,  C09C1/22 ,  C09C1/28 ,  C09D7/12 ,  C09D11/02 ,  C01B25/37 ,  C09D17/00 ,  C08J3/20

Abstract: Bi vanadate pigments of the formula BixFeyEvV(1-w)PwOz (I) are new; in which E = Ca, Zn, Ce, Pr and/or Si; x = 0.8-1.2; y > 0 to 0.1 if v > 0 and y ≥ 0.035 to 0.1 if v = 0; v ≥ 0 to 0.2; w > 0 to 0.1; z = the no. of O atoms to satisfy the valencies of the cations.

公开(公告)号：ES2154762T3

公开(公告)日：2001-04-16

申请号：ES96112493

申请日：1996-08-02

Applicant: BASF AG

Inventor： OCHMANN HARALD DR ,  REISACHER HANSULRICH DR ,  KNITTEL HELMUT ,  MRONGA NORBERT DR ,  ETZRODT GUNTER DR ,  WIENAND HENNING DR

IPC: C01G49/00 ,  C08K3/18 ,  C08K3/28 ,  C08K3/32 ,  C09C1/00 ,  C09C1/02 ,  C09C1/04 ,  C09C1/22 ,  C09C1/28 ,  C09D7/12 ,  C09D11/02

Abstract: Bi vanadate pigments of the formula BixFeyEvV(1-w)PwOz (I) are new; in which E = Ca, Zn, Ce, Pr and/or Si; x = 0.8-1.2; y > 0 to 0.1 if v > 0 and y ≥ 0.035 to 0.1 if v = 0; v ≥ 0 to 0.2; w > 0 to 0.1; z = the no. of O atoms to satisfy the valencies of the cations.

公开(公告)号：MX9603231A

公开(公告)日：1997-07-31

申请号：MX9603231

申请日：1996-08-06

Applicant: BASF AG

Inventor： OCHMANN HARALD ,  REISACHER HANSULRICH ,  KNITTEL HELMUT ,  MRONGA NORBERT ,  ETZRODT GUNTER ,  WIENAND HENNING

IPC: C08K3/18 ,  C01G49/00 ,  C08K3/28 ,  C08K3/32 ,  C09C1/00 ,  C09C1/02 ,  C09C1/04 ,  C09C1/22 ,  C09C1/28 ,  C09D7/12 ,  C09D11/02 ,  C09C01/62

Abstract: El presente invento se refiere a pigmentos de vanadato de bismuto conteniendo hierro que corresponden a la formula general I BixFeyEvV(1-w)PwO2 en la que los variables tienen los siguientes significados: E es calcio, cinc, cerio, praseodimio y/o silicio; X es 0,8 hasta 1,2; y es > 0 hasta 0,1, cuando v es > 0, y > o igual que 0,035 hasta 0,1, cuando V = 0; v es > o igual que 0 hasta 0,2; W ES > 0 hasta 0,1; z; representa el numero de átomos de oxígeno necesario para cumplir las valencias de los cationes.