Production of prepolymer for use in 1-component foam-in-can systems, e.g. for building applications, involves reacting an isocyanate group-containing prepolymer with a silane containing groups which react with isocyanate

    公开(公告)号:DE10347659A1

    公开(公告)日:2005-05-19

    申请号:DE10347659

    申请日:2003-10-09

    Applicant: BASF AG

    Abstract: In a method (M1) for the production of prepolymers (I) by reacting isocyanate group-containing prepolymers (i) with silanes (ii) containing group(s) which react with isocyanate, the mol ratio of isocyanate groups in (i) to silane units in (ii) = (1.01:1)-(10:1). Independent claims are also included for (1) a method (M2) for the production of (I) by reacting (i) with (ii) and a polyol component (iii) which may also contain other substances such as foam stabilisers and/or catalysts, in which (i) is mixed with (ii) at the same time as (iii) or before (iii) (2) a method (M3) for the production of (I) with a free NCO group content of 1-15 wt% and a monomeric isocyanate content of less than 0.4 wt%, by reacting an isocyanate (ia) with polyol(s) (ib) (preferably with a functionality of 3 or less), reacting the unreacted monomeric isocyanate with (ii) and then optionally reacting the product with (iii), optionally in presence of diluents, stabilisers, catalysts and gaseous blowing agents (3) prepolymers (I) obtained by these methods (4) reaction products of (a) isocyanate, (b) polyol and (ii) NCO-reactive silane, with an NCO content of 1-15 wt% and a monomeric isocyanate content of less than 0.4 wt% (5) one- or two-component PUR foam-in-can systems based on (I) .

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