公开(公告)号：DE3926769A1

公开(公告)日：1991-02-14

申请号：DE3926769

申请日：1989-08-12

Applicant: BASF AG

Inventor： ZIPPLIES MATTHIAS DR ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR

IPC: C07D307/94 ,  C07D317/72 ,  C07D405/06 ,  C07D411/06

Abstract: Piperidinomethyl-spiroheterocyclic cpds. (I) and their addn. salts are new. R1 = H; alkyl; or opt. substd. cyclohexyl or phenyl; R2 = hydroxy; acyloxy; alkoxy; opt. substd. benzoyloxy; opt. substd.: benzyloxy; alkyl or alkenyl opt. substd. by hydroxy, acyloxy, alkoxy, benzoyloxy, benzyloxy or opt. substd. aryl; aryl; halo-aryl; or alkyl-aryl; X = O, S or CH2; Y = H or hydroxy. USE - Cpds. (I) are fungicides which can be used to treat plants, materials, seeds or soil. They are formulated conventionally and can be applied in amts. of e.g. 0.02-3 kg/ha.

公开(公告)号：DE3812945A1

公开(公告)日：1989-11-02

申请号：DE3812945

申请日：1988-04-19

Applicant: BASF AG

Inventor： ZIPPLIES MATTHIAS DR ,  SAUTER HUBERT DR ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR

IPC: A01N47/44 ,  C07C279/12

Abstract: Guanidiniumdodecylbenzene sulfonates of the formula I where R is the group -H, -CH3 or and X is 1, 2, 3 or 4, and fungicides containing these compounds.

公开(公告)号：DE3732930A1

公开(公告)日：1989-04-20

申请号：DE3732930

申请日：1987-09-30

Applicant: BASF AG

Inventor： ZIPPLIES MATTHIAS DR ,  SAUTER HUBERT DR ,  ROEHL FRANZ DR ,  HIMMELE WALTER DR ,  AMMERMANN EBERHARD DR ,  POMMER ERNST-HEINRICH DR

IPC: A01N43/36 ,  C07D207/06 ,  C07D207/08 ,  C07D405/04 ,  C07D405/08 ,  C07F7/08

Abstract: N-Substituted 3-arylpyrrolidine derivatives of the formula where R1 is 2,2-dimethylpropyl, 3,3-dimethylbutyl, 4,4-dimethylpentyl, 2,4,4-trimethylpentyl, 6-methylhept-2-yl, 3,5,5-trimethylhexyl, 6,10-dimethylundec-2-yl, 3-methylcyclohexyl, 3,3-dimethylcyclohexyl, 3,3,5-trimethylcyclohexyl, 3,3,5,5-tetramethylcyclohexyl, 4-methylcyclohexyl, 4-ethylcyclohexyl, 4-propylcyclohexyl, 4-isopropylcyclohexyl, 4-tert.-butylcyclohexyl, trans-4-tert.-butylcyclohexyl, 4(2-methylbut-2-yl)cyclohexyl, 4(2,4,4-trimethylpent-2-yl)-cyclohexyl, cyclododecanyl, C3-C9-trialkylsilyl-substituted C4-C12-cycloalkyl, 4-hydroxycyclohexyl, 4-hydroxy-3-methylcyclohexyl, 4-hydroxy-3,5-dimethylcyclohexyl, 4-hydroxy-3,3-dimethylcyclohexyl, 4-hydroxy-3,3,5-trimethylcyclohexyl, unsubstituted or hydroxy-, C1-C9-alkyl-, C1-C5-alkoxy- or C3-C9-trialkylsilyl-substituted C5-C12-cycloalkenyl, R1 is further bicycloalkyl, R1 is further 4-tert.-butyl-benzyl, 4-chlorobenzyl, 4-tert.-butoxybenzyl, 1,4-dioxaspiro[4,5]decan-8-yl, 5 to 7-membered heterocycloalkyl, 5 to 7-membered heterocycloalkylmethyl, R2 is alkyl, alkoxy or trialkylsilyl, R3 is alkyl, alkenyl, alkynyl or arylalkyl, X- is a plant-tolerated anion, n is 0 or 1, and plant-tolerated salts thereof, and fungicides containing these compounds.

公开(公告)号：DE3732910A1

公开(公告)日：1989-04-20

申请号：DE3732910

申请日：1987-09-30

Applicant: BASF AG

Inventor： ZIPPLIES MATTHIAS DR ,  SAUTER HUBERT DR ,  HIMMELE WALTER DR ,  AMMERMANN EBERHARD DR ,  POMMER ERNST-HEINRICH DR

IPC: A01N43/36 ,  A01N49/00 ,  C07D207/06 ,  C07D207/08 ,  C07D405/04

Abstract: 3-Alkyl-4-arylpyrrolidine derivatives of the formula where R1 is alkenyl, alkynyl, cycloalkyl, cycloalkenyl, alkyl-cycloalkyl, cycloalkyl-alkyl, alkyl-cycloalkyl-alkyl, cycloalkenyl-alkyl, alkyl-cycloalkenyl, bicycloalkyl, bicycloalkylalkyl, alkyl-bicycloalkyl, heterocycloalkyl, heterocycloalkylmethyl, aryl, arylalkyl, alkylary, alkyl-aryl-alkyl, R2 is alkyl, alkoxy, R3 is alkyl R4 is alkyl, alkenyl, alkynyl and phenylalkyl, X- is a plant-tolerated anion, and n is 0 or 1, their plant-tolerated salts, and fungicides containing these compounds.

公开(公告)号：ES2060260T3

公开(公告)日：1994-11-16

申请号：ES91113556

申请日：1991-08-13

Applicant: BASF AG

Inventor： MUELLER THOMAS DR ,  ZIPPLIES MATTHIAS DR ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR

IPC: A01N43/48 ,  A01N43/50 ,  A01N43/54 ,  A01N47/44 ,  C07C279/04 ,  C07C279/08 ,  C07C279/12 ,  C07C279/16 ,  C07D233/48 ,  C07D239/14 ,  C07D243/04 ,  C07D245/02 ,  C07D247/02

Abstract: Bis-guanidines of formula (I) their plant-tolerable acid addn. salts and metal complexes are new: R1 and R2 = H, 5-10C alkyl, 3-10C alkenyl, or alkynyl, 1-8C alkoxy- (2-8C) alkyl, 3-10C haloalkenyl, 5-12C cycloalkyl (opt. with up to 3 of OH, 1-10C alkyl, haloalkyl or alkoxy, or 1-8C alkoxy (1-8C) alkyl as substits). or benzyl (opt. substd. by 1-3 1-10C alkyl or alkoxy (themselves opt. substd. by OH or 1-6C alkoxy) or by one 1-10C haloalkyl) but not both H, or R1 and R2 can together complete a 5-11 membered heterocycle opt. substd. by 1-3 of 1-10C alkyl or 1-8C alkoxy (1-8C) alkyl, X = CH2, O, C-C single bond, NH, N(1-10C alkyl) or N-benzyl (opt. ring-substd. by 1-3 of 1-10C alkyl, alkoxy or haloalkyl or halo), m = 5-8.

公开(公告)号：ES2056087T3

公开(公告)日：1994-10-01

申请号：ES88115569

申请日：1988-09-22

Applicant: BASF AG

Inventor： ZIPPLIES MATTHIAS DR ,  SAUTER HUBERT DR ,  ROEHL FRANZ DR ,  HIMMELE WALTER DR ,  AMMERMANN EBERHARD DR ,  POMMER ERNST-HEINRICH DR

IPC: A01N43/36 ,  C07D207/06 ,  C07D207/08 ,  C07D405/04 ,  C07D405/08 ,  C07F7/08

Abstract: N-Substituted 3-arylpyrrolidine derivatives of the formula where R1 is 2,2-dimethylpropyl, 3,3-dimethylbutyl, 4,4-dimethylpentyl, 2,4,4-trimethylpentyl, 6-methylhept-2-yl, 3,5,5-trimethylhexyl, 6,10-dimethylundec-2-yl, 3-methylcyclohexyl, 3,3-dimethylcyclohexyl, 3,3,5-trimethylcyclohexyl, 3,3,5,5-tetramethylcyclohexyl, 4-methylcyclohexyl, 4-ethylcyclohexyl, 4-propylcyclohexyl, 4-isopropylcyclohexyl, 4-tert.-butylcyclohexyl, trans-4-tert.-butylcyclohexyl, 4(2-methylbut-2-yl)cyclohexyl, 4(2,4,4-trimethylpent-2-yl)-cyclohexyl, cyclododecanyl, C3-C9-trialkylsilyl-substituted C4-C12-cycloalkyl, 4-hydroxycyclohexyl, 4-hydroxy-3-methylcyclohexyl, 4-hydroxy-3,5-dimethylcyclohexyl, 4-hydroxy-3,3-dimethylcyclohexyl, 4-hydroxy-3,3,5-trimethylcyclohexyl, unsubstituted or hydroxy-, C1-C9-alkyl-, C1-C5-alkoxy- or C3-C9-trialkylsilyl-substituted C5-C12-cycloalkenyl, R1 is further bicycloalkyl, R1 is further 4-tert.-butyl-benzyl, 4-chlorobenzyl, 4-tert.-butoxybenzyl, 1,4-dioxaspiro[4,5]decan-8-yl, 5 to 7-membered heterocycloalkyl, 5 to 7-membered heterocycloalkylmethyl, R2 is alkyl, alkoxy or trialkylsilyl, R3 is alkyl, alkenyl, alkynyl or arylalkyl, X- is a plant-tolerated anion, n is 0 or 1, and plant-tolerated salts thereof, and fungicides containing these compounds.

公开(公告)号：DE3850206D1

公开(公告)日：1994-07-21

申请号：DE3850206

申请日：1988-09-22

Applicant: BASF AG

Inventor： ZIPPLIES MATTHIAS DR ,  SAUTER HUBERT DR ,  ROEHL FRANZ DR ,  HIMMELE WALTER DR ,  AMMERMANN EBERHARD DR ,  POMMER ERNST-HEINRICH DR

IPC: A01N43/36 ,  C07D207/06 ,  C07D207/08 ,  C07D405/04 ,  C07D405/08 ,  C07F7/08

Abstract: N-Substituted 3-arylpyrrolidine derivatives of the formula where R1 is 2,2-dimethylpropyl, 3,3-dimethylbutyl, 4,4-dimethylpentyl, 2,4,4-trimethylpentyl, 6-methylhept-2-yl, 3,5,5-trimethylhexyl, 6,10-dimethylundec-2-yl, 3-methylcyclohexyl, 3,3-dimethylcyclohexyl, 3,3,5-trimethylcyclohexyl, 3,3,5,5-tetramethylcyclohexyl, 4-methylcyclohexyl, 4-ethylcyclohexyl, 4-propylcyclohexyl, 4-isopropylcyclohexyl, 4-tert.-butylcyclohexyl, trans-4-tert.-butylcyclohexyl, 4(2-methylbut-2-yl)cyclohexyl, 4(2,4,4-trimethylpent-2-yl)-cyclohexyl, cyclododecanyl, C3-C9-trialkylsilyl-substituted C4-C12-cycloalkyl, 4-hydroxycyclohexyl, 4-hydroxy-3-methylcyclohexyl, 4-hydroxy-3,5-dimethylcyclohexyl, 4-hydroxy-3,3-dimethylcyclohexyl, 4-hydroxy-3,3,5-trimethylcyclohexyl, unsubstituted or hydroxy-, C1-C9-alkyl-, C1-C5-alkoxy- or C3-C9-trialkylsilyl-substituted C5-C12-cycloalkenyl, R1 is further bicycloalkyl, R1 is further 4-tert.-butyl-benzyl, 4-chlorobenzyl, 4-tert.-butoxybenzyl, 1,4-dioxaspiro[4,5]decan-8-yl, 5 to 7-membered heterocycloalkyl, 5 to 7-membered heterocycloalkylmethyl, R2 is alkyl, alkoxy or trialkylsilyl, R3 is alkyl, alkenyl, alkynyl or arylalkyl, X- is a plant-tolerated anion, n is 0 or 1, and plant-tolerated salts thereof, and fungicides containing these compounds.

公开(公告)号：DE4211713A1

公开(公告)日：1993-10-14

申请号：DE4211713

申请日：1992-04-08

Applicant: BASF AG

Inventor： SCHNEIDER JUERGEN DR ,  OFTRING ALFRED DR ,  ZIPPLIES MATTHIAS DR ,  WIDDER RUDI DR ,  BRAUN GEROLD DR ,  WILD JOCHEN DR ,  POTTHOFF-KARL BIRGIT DR ,  BAUR RICHARD DR

IPC: B01D53/52 ,  B01D53/56 ,  C02F5/12 ,  C07C227/26 ,  C07C229/16 ,  C07C255/25 ,  C11D3/33 ,  C11D3/39 ,  C23G1/14 ,  D06L3/02 ,  D06L4/12 ,  D06P1/647 ,  C07C253/30

Abstract: New aminodicarboxylic acid-N,N-diacetic acids of formula (I) are prepd. by reacting aminodicarboxylic acids of formula XOOC-(CH2)n-CH-COOX (II), in water and/or an organic solvent, with 2-2.6 mols of HCHO and 2-2.3 mols of liq. HCN at 0-150 deg. C., or with 2-2.3 moles of alkali metal cyanide at 40-100 deg. C., and hydrolysing amide or CN gps. formed, in presence of an acid or a base. Aminodicarboxylic acid-N,N-diacetonitriles of formula XOOC- (CH2)n-CH (N(CH2CN)2 COOX (III), formed as intermediates, are also claimed. In the formulae, X = H, alkali metal, NH4 or ammonium gp. substd. with 1-4C alkyl or hydroxyalkyl; and n = 1-4. USE/ADVANTAGE - (I) are prepd. in high purity and good yield, from easily available cpds., by a simple, efficient process applicable on the large scale and giving almost no loading with inorganic salt. (I) can be used in alkaline media, overcoming corrosion problems. (I) are complex-formers, esp. for alkaline earth and heavy metal ions, and can be used in washing compsns. and solns. to control the content of free heavy metal ions, as bleach stabilisers, e.g. for NaBO3, as builders, and in bleaching textiles, cellulose or paper pulp, to prevent destruction of the bleach system, enzymes, optical bleaches and perfumes by heavy metal ions.

公开(公告)号：DE59001732D1

公开(公告)日：1993-07-22

申请号：DE59001732

申请日：1990-01-20

Applicant: BASF AG

Inventor： ZIPPLIES MATTHIAS DR ,  SAUTER HUBERT DR ,  GOLD RANDALL EVAN DR ,  AKERS ALAN ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR

IPC: A01N33/06 ,  A01N43/40 ,  A01N43/84

Abstract: Fungicidal composition containing a) a compound of the formula I in which R represents tridecyl-3-(p-tert-butyl(phenyl)-2-methylpropyl, R represents H or CH3 and X represents O or CH2, and b) a compound of the formula II in which R represents optionally substituted phenyl, naphthyl, tetrahydronaphthyl, benzothiophenyl, benzofuranyl, anthracenyl, acenaphthenyl, hexahydroindacenyl, tetrahydrophenanthrenyl, stilbenyl, benzodioxolanyl, R represents hydrogen or methyl R represents hydrogen, R represents alkyl, cyclopropyl, haloalkyl or alkenyl, W represents an alkenylene radical, fluoroalkenylene radical or a single bond, R represents optionally substituted phenyl, naphthyl, optionally substituted alkenyl or alkynyl, where the radical can also represent the acenaphthenyl radical and the radical can also be part of a heterocyclic ring.

公开(公告)号：DE58901104D1

公开(公告)日：1992-05-14

申请号：DE58901104

申请日：1989-01-30

Applicant: BASF AG

Inventor： ZIPPLIES MATTHIAS DR ,  SAUTER HUBERT DR ,  ROEHL FRANZ DR ,  KUEKENHOEHNER THOMAS DR ,  JANITSCHKE LOTHAR DR ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR

IPC: C07D295/02 ,  A01N43/60 ,  C07D295/00 ,  C07D295/03 ,  C07D295/033 ,  C07D295/067 ,  C07D295/08

Abstract: N,N'-disubstituted piperazines of the general formula I (1) where the group is unsaturated (=) or saturated (-) and the substituents R1, R2 and A have the following meanings: A is -, -CH=, -CH2-, -CH2-CH2-, R1 is alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, alkylcycloalkyl, cycloalkenylalkyl, alkylcycloalkenyl, bicycloalkyl, bicycloalkylalkyl or alkylbicycloalkyl, these radicals being unsubstituted or substituted by hydroxy, halogen, alkoxy or trialkylsilyl, R1 is further heterocycloalkyl with oxygen and/or sulfur, heterocycloalkylmethyl with oxygen and/or sulfur, alkyl-substituted heterocycloalkylmethyl with oxygen and/or sulfur, and R2 is alkyl, alkoxy, trimethylsilyl, cycloalkyl, alkylthio, and plant-physiologically tolerated salts thereof, and fungicides containing these compounds.