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    PROCESS FOR PREPARING PROPYLENE OXIDE
    13.
    发明申请
    PROCESS FOR PREPARING PROPYLENE OXIDE 有权
    制备丙烯氧化物的方法

    公开(公告)号：US20160176834A1

    公开(公告)日：2016-06-23

    申请号：US14907998

    申请日：2014-07-16

    Applicant: BASF SE ,  DOW GLOBAL TECHNOLOGIES LLC

    Inventor： Joaquim Henrique TELES ,  Bianca SEELIG ,  Dominic RIEDEL ,  Philip KAMPE ,  Daniel URBANCZYK ,  Markus WEBER ,  Ulrich MUELLER ,  Andrei-Nicolae PARVULESCU ,  Kai GUMLICH ,  Peter BASSLER ,  Christian BARTOSCH ,  Richard JACUBINAS ,  Meinolf WEIDENBACH ,  Werner WITZL

    IPC: C07D301/12 ,  B01J27/188 ,  B01J27/18 ,  B01J29/70

    CPC classification number: C07D301/12 ,  B01J27/18 ,  B01J27/188 ,  B01J29/7038 ,  B01J29/7088 ,  B01J35/002 ,  B01J35/1019 ,  B01J2229/186 ,  Y02P20/52

    Abstract: A continuous process for the preparation of propylene oxide, comprising (i) providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, water, optionally propane, and at least one dissolved potassium salt of a phosphorus oxyacid wherein the molar ratio of potassium relative to phosphorus in the at least one potassium salt of a phosphorus oxyacid is in the range of from 0.6 to 1.4; (ii) passing the liquid feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MVVW comprising zinc, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation reactor, obtaining a reaction mixture comprising propylene oxide, acetonitrile, water, the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane; (iii) removing an effluent stream from the epoxidation reactor, the effluent stream comprising propylene oxide, acetonitrile, water, at least a portion of the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane.

    Abstract translation: 一种用于制备环氧丙烷的连续方法，包括（i）提供包含丙烯，过氧化氢，乙腈，水，任选的丙烷和至少一种溶解的含磷酸钾的液体进料流，其中钾相对的摩尔比 在磷氧基酸的至少一种钾盐中的磷在0.6至1.4的范围内; （ii）将（i）中提供的液体进料流送入包含催化剂的环氧化反应器中，所述催化剂包含含锌的结构型MVVW的钛沸石，并使液体进料流在环氧化反应器中进行环氧化反应条件，得到反应混合物 包括环氧丙烷，乙腈，水，所述至少一种溶解的含磷酸的钾盐，任选的丙烯，以及任选的丙烷; （iii）从环氧化反应器中除去流出物流，所述流出物流包含环氧丙烷，乙腈，水，所述至少一种溶解的含磷酸的钾盐，任选的丙烯和任选的丙烷的至少一部分。

    PART-STREAM DISTILLATION
    14.
    发明申请
    PART-STREAM DISTILLATION 审中-公开

    公开(公告)号：US20160115140A1

    公开(公告)日：2016-04-28

    申请号：US14787956

    申请日：2014-04-28

    Applicant: BASF SE ,  DOW GLOBAL TECHNOLOGIES LLC

    Inventor： Joaquim H. TELES ,  Dominic RIEDEL ,  Bianca SEELIG ,  Philip KAMPE ,  Daniel URBANCZYK ,  Markus WEBER ,  Alexander SCHROEDER ,  Andrei-Nicolae PARVULESCU ,  Ulrich MUELLER ,  Meinolf WEIDENBACH ,  Werner WITZL ,  Holger BAER

    IPC: C07D301/12 ,  B01D3/14 ,  C07D301/32

    CPC classification number: C07D301/12 ,  B01D3/143 ,  C07D301/32

    Abstract: A continuous process for the preparation of propylene oxide, comprising (a) reacting propene, optionally admixed with propane, with hydrogen peroxide in a reaction apparatus in the presence of acetonitrile as solvent, obtaining a stream S0 containing propylene oxide, acetonitrile, water, at least one further component B, optionally propene and optionally propane, wherein the normal boiling point of the at least one component B is higher than the normal boiling point of acetonitrile and wherein the decadic logarithm of the octanol-water partition coefficient (log Kow) of the at least one component B is greater than zero; (b) separating propylene oxide from S0, obtaining a stream S1 containing acetonitrile, water and the at least one further component B; (c) dividing S1 into two streams S2 and S3; (d) subjecting S3 to a vapor-liquid fractionation in a fractionation unit, obtaining a vapor fraction stream S4 being depleted of the at least one component B; (e) recycling at least a portion of S4, optionally after work-up, to (a).

    Abstract translation: 一种用于制备环氧丙烷的连续方法，包括（a）在乙腈作为溶剂的存在下，在反应装置中将丙烯任选与丙烷混合，与过氧化氢反应，得到含有环氧丙烷，乙腈，水的流S0 至少一种另外的组分B，任选的丙烯和任选的丙烷，其中至少一种组分B的标准沸点高于乙腈的标准沸点，其中辛醇 - 水分配系数（log Kow）的十进制对数 所述至少一个组分B大于零; （b）从S0分离环氧丙烷，得到含有乙腈，水和至少一种其它组分B的料流S1; （c）将S1划分成两个流S2和S3; （d）使S3在分馏装置中进行汽 - 液分馏，得到耗尽至少一种B成分的蒸汽馏分流S4; （e）将至少一部分S4，任选地在后处理之后再循环至（a）。

    PROCESS FOR THE PREPARATION OF A LIQUID MIXTURE COMPRISING METHANOL, WATER AND HYDROGEN PEROXIDE
    16.
    发明公开
    PROCESS FOR THE PREPARATION OF A LIQUID MIXTURE COMPRISING METHANOL, WATER AND HYDROGEN PEROXIDE 审中-公开

    公开(公告)号：US20240294483A1

    公开(公告)日：2024-09-05

    申请号：US18572209

    申请日：2022-06-22

    Applicant: BASF SE ,  Dow Global Technologies LLC

    Inventor： Andrei-Nicolae PARVULESCU ,  Joaquim Henrique TELES ,  Dominic RIEDEL ,  Dylan SEGERS ,  Massimo BERGAMO ,  Franciscus Johannes Robertus VAN NEER ,  Meinolf WEIDENBACH

    IPC: C07D301/12

    CPC classification number: C07D301/12

    Abstract: The present invention relates in a first aspect to a process for the preparation of a liquid mixture comprising methanol, water and hydrogen peroxide, the process comprising: (i) providing a feed stream comprising methanol, and a feed stream comprising an aqueous hydrogen peroxide solution; (ii) combining the feed stream comprising the methanol and the feed stream comprising the aqueous hydrogen peroxide solution provided according to (i) at a point in time t1, so that a combined stream comprising methanol, hydrogen peroxide and water is obtained; (iii) filtrating the combined stream obtained according to (ii) at a point in time t2, through a filtration device, thereby obtaining a liquid mixture comprising methanol, hydrogen peroxide and water; wherein the period of time between t1 and t2 is at least 8 seconds. In a second aspect, the invention relates to the use of a liquid mixture obtained or obtainable from the process of the first aspect for the preparation of propylene oxide. A third aspect of the invention is directed to a method for the preparation of propylene oxide comprising: (i) providing a feed stream comprising methanol, a feed stream comprising an aqueous hydrogen peroxide solution and a feed stream comprising propylene; (ii) combining the feed stream comprising the methanol and the feed stream comprising the aqueous hydrogen peroxide solution provided according to (i) at a point in time t1, so that a combined stream comprising methanol, hydrogen peroxide and water is obtained; (iii) filtrating the combined stream obtained according to (ii) at a point in time t2, through a filtration device, thereby obtaining a liquid mixture comprising methanol, hydrogen peroxide and water; (iv) combining the feed stream comprising propylene either with the combined stream obtained in (ii) or with the liquid mixture obtained in (iii), thereby obtaining a liquid mixture comprising methanol, hydrogen peroxide, water and propylene; (v) bringing the liquid mixture obtained according to (iv) in an epoxidation zone in contact with an epoxidation catalyst comprising a zeolitic material having a framework structure comprising Si, O, and Ti under epoxidation reaction conditions, thereby obtaining in the epoxidation zone a mixture comprising propylene oxide, methanol and water; wherein the period of time between t1 and t2 are at least 8 seconds. In a fourth aspect, the invention relates to propylene oxide, obtained or obtainable from the method according to the third aspect.

    ZEOLITE SYNTHESIS IN A CONTINUOUS FLOW REACTOR WITH A PULSATILE FLOW REGIME
    17.
    发明公开
    ZEOLITE SYNTHESIS IN A CONTINUOUS FLOW REACTOR WITH A PULSATILE FLOW REGIME 审中-公开

    公开(公告)号：US20240270584A1

    公开(公告)日：2024-08-15

    申请号：US18569345

    申请日：2022-06-14

    Applicant: BASF SE

    Inventor： Hannah SCHREYER ,  Andrei-Nicolae PARVULESCU ,  Ralf BOEHLING ,  Christian RIEMANN

    IPC: C01B39/06

    CPC classification number: C01B39/06

    Abstract: The present invention relates to a continuous process for the preparation of a zeolitic material comprising SiO2 in its framework structure, said process comprising (i) continuously preparing a mixture comprising one or more solvents, one or more structure directing agents, and one or more sources of SiO2; (ii) continuously feeding the mixture prepared in (i) into one or more continuous flow reactors; and (iii) heating the mixture in the one or more continuous flow reactors for continuously obtaining a zeolitic material comprising SiO2 in its framework structure; wherein the mixture contained in the one or more continuous flow reactors is subject to a pulsatile flow regime. The present invention also relates to a zeolitic material as obtainable and/or obtained according to said process and the use of the zeolite material as a molecular sieve, as an adsorbent, for ion-exchange, or as a catalyst and/or as a catalyst support.

    ZEOLITE CATALYZED PROCESS FOR THE AMINATION OF ALKYLENE OXIDES
    18.
    发明申请
    ZEOLITE CATALYZED PROCESS FOR THE AMINATION OF ALKYLENE OXIDES 有权

    公开(公告)号：US20210214300A1

    公开(公告)日：2021-07-15

    申请号：US15733839

    申请日：2019-05-29

    Applicant: BASF SE

    Inventor： Andrei-Nicolae PARVULESCU ,  Johann-Peter MELDER ,  Ulrich MUELLER ,  Alexander Michael HAYDL ,  Zeljko KOTANJAC ,  Hermann LUYKEN ,  Christian GRUENANGER

    IPC: C07C213/04 ,  B01J29/40 ,  B01J29/70 ,  B01J35/10 ,  B01J37/02 ,  B01J37/00 ,  B01J37/08

    Abstract: The present invention relates to a process for the conversion of ethylene oxide to 2-aminoethanol and/or Di(2-hydroxyethyl)amine comprising (i) providing a catalyst comprising a zeolitic material comprising YO2 and X2O3 in its framework structure, wherein Y is a tetravalent element and X is a trivalent element, wherein the zeolitic material has a framework-type structure selected from the group consisting of MFI and/or MEL, including MEL/MFI intergrowths, and wherein the zeolitic material contains one or more rare earth elements; (ii) providing a mixture in the liquid phase comprising ethylene oxide and ammonia; (iii) contacting the catalyst provided in (i) with the mixture in the liquid phase provided in (ii) for converting ethylene oxide to 2-aminoethanol and/or Di(2-hydroxyethyl)amine, wherein the catalyst provided in (i) is obtained and/or obtainable by a process comprising loading one or more salts of the one or more rare earth elements into the pores of the porous structure of the zeolitic material and optionally on the surface of the zeolitic material.

    PROCESS FOR PREPARING A ZEOLITIC MATERIAL HAVING A FRAMEWORK TYPE FER
    19.
    发明申请
    PROCESS FOR PREPARING A ZEOLITIC MATERIAL HAVING A FRAMEWORK TYPE FER 有权

    公开(公告)号：US20210198114A1

    公开(公告)日：2021-07-01

    申请号：US17058338

    申请日：2019-07-26

    Applicant: BASF SE

    Inventor： Andrei-Nicolae PARVULESCU ,  Robert MCGUIRE ,  Ulrich MUELLER ,  Alexander KROMER

    IPC: C01B39/44 ,  F01N3/20 ,  C01B39/04

    Abstract: The present invention relates to a process for preparing a zeolitic material having a framework type FER and having a framework structure comprising silicon, aluminum, and oxygen, said process comprising (i) preparing an aqueous synthesis mixture comprising water; a zeolitic material having a framework type other than FER and having a framework structure comprising silicon, aluminum, and oxygen; a source of silicon other than the zeolitic material having a framework type other than FER; an organic structure directing agent comprising piperidine; a source of an alkali metal; and a source of a base; (ii) subjecting the aqueous synthesis mixture prepared according to (i) to hydrothermal synthesis conditions comprising heating the synthesis mixture to a temperature in the range of from 140 to 190° C. and keeping the synthesis mixture at a temperature in this range under autogenous pressure, obtaining a mother liquor comprising a solid material which comprises the zeolitic material having a framework type FER.

    A FAST BATCH PROCESS FOR PREPARING A ZEOLITIC MATERIAL HAVING FRAMEWORK TYPE CHA
    20.
    发明申请
    A FAST BATCH PROCESS FOR PREPARING A ZEOLITIC MATERIAL HAVING FRAMEWORK TYPE CHA 有权

    公开(公告)号：US20210031175A1

    公开(公告)日：2021-02-04

    申请号：US16766944

    申请日：2018-12-20

    Applicant: BASF SE ,  The University of Tokyo

    Inventor： Andrei-Nicolae PARVULESCU ,  Ulrich MUELLER ,  Kenta IYOKI ,  Watcharop CHAIKITTISILP ,  Torn WAKIHARA

    IPC: B01J29/70 ,  C01B39/48 ,  B01J35/10 ,  B01J37/00 ,  B01J37/04 ,  B01J37/10 ,  C07C1/04 ,  B01D53/94 ,  F01N3/28 ,  F01N3/20 ,  F01N3/08

    Abstract: A batch process for preparing a zeolitic material having framework type CHA and a framework structure comprising Si, Al, O, and H, comprising (i) providing a seeding material comprising a zeolitic material having framework type CHA and a framework structure comprising Si, Al, O, and H; (ii) preparing a mixture comprising a source of Si, a source of Al, a seeding material provided in (i), a CHA framework structure directing agent comprising a cycloalkylammonium compound, and water, wherein the cycloalkylammonium compound is a compound comprising a cation R1R2R3R4N+ wherein R1, R2, R3 are, independently from one another, an alkyl residue having from 1 to 6 carbon atoms, and R4 is a 5- to 8-membered cycloalkyl residue, wherein in mixture, the molar ratio of water relative to Si comprised in the source of Si and in the seeding material, calculated as SiO2, is in the range of from 5:1 to 15:1, wherein the mixture, the molar ratio of sodium, calculated as Na2O, relative to Si comprised in the source of Si and in the seeding material, calculated as SiO2, is in the range of from 0:1 to 0.1:1; (iii) heating the mixture prepared in (ii) in its liquid state to a temperature of the mixture in the range of from 50 to 90° C. and keeping the liquid mixture at a temperature in this range for 5 to 100 h; (iv) heating the heated mixture of (iii) to a temperature of the mixture in the range of from 190 to 230° C. in a crystallization vessel and keeping the mixture at a temperature in this range under autogenous pressure in the crystallization vessel for 0.5 to 10 h, obtaining a solid material comprising a zeolitic material having framework type CHA and a framework structure comprising Si, Al, O, and H, suspended in its mother liquor.

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