СПОСОБ ОЧИСТКИ ГАЗОВОЙ СМЕСИ, СОДЕРЖАЩЕЙ ОКСИД АЗОТА (I)

    公开(公告)号:UA98130C2

    公开(公告)日:2012-04-25

    申请号:UAA200907251

    申请日:2007-12-07

    Applicant: BASF SE

    Abstract: Данноеизобретениеотноситсяк способуочисткигазовойсмеси, содержащейоксидазота (I), которыйвключает, поменьшеймере, введениев контактгазовойсмеси G-0 сосмесьюрастворителей (I), содержащей, поменьшеймере, 50 мас. % водыизрасчетанавсюсмесьрастворителей (I), причемзначениерНсмесирастворителей (I) составляетот 3,5 до 8,0, десорбциюгазовойсмеси G-1 изкомпозиции (А), введениев контактгазовойсмеси G-1 сосмесьюрастворителей (II), содержащей, поменьшеймере, 50 мас. % водыизрасчетанавсюсмесьрастворителей (II), причемзначениерНсмесирастворителей (II) составляетот 2,0 до 8,0, идесорбциюгазовойсмеси G-2 изкомпозиции (В), причемзначениерНсоответственноотноситсяк измерениюстекляннымэлектродом, атакжеприменениегазовыхсмесей, полученныхспособомсогласноизобретению, вкачествеокислителядляолефинов.

    12.
    发明专利
    未知

    公开(公告)号:DE102008042010A1

    公开(公告)日:2009-04-16

    申请号:DE102008042010

    申请日:2008-09-12

    Applicant: BASF SE

    Abstract: The procedure for continuous separation of target product (X) in the form of fine particle of crystallisate from a liquid phase (P) existing from the target product (X) and/or by the target product of different constituents, comprises indirectly operating a heat exchanger having primary and secondary areas, which are spatially separated with one another through a material divider that serves as an area for transmitting heat from the secondary area to the primary area by passing a stream at the liquid phase (P) in the secondary area of the heat exchanger. The procedure for continuous separation of target product (X) in the form of fine particle of crystallisate from a liquid phase (P) existing from the target product (X) and/or by the target product of different constituents, comprises indirectly operating a heat exchanger having primary and secondary areas, which are spatially separated with one another through a material divider that serves as an area for transmitting heat from the secondary area to the primary area by passing a stream at the liquid phase (P) in the secondary area of the heat exchanger during the primary area flows throughable simultaneously to a liquid cooling medium so that it forms fine particles of crystallisate of the target product in the secondary area under disposition of a liquid residual phase from the liquid phase (P). The total mole fraction of the liquid phase has the value of M b, p ges at the constituent (B i). The liquid residual phase (R) contains ingredients with a total mole fraction of M b, r (ges) greater than M b, p (ges) in comparison with the liquid phase (P). The content of residual phase in the target product is 70 wt.%. The cooling medium is suspended by fine particles of crystallisate of the target product in the liquid residual phase under receiving a suspension (S) having a crystallization grade (Y). The secondary area of the heat exchanger continuously takes the suspension with the temperature T s (aus). The suspension of fine particle crystallisate from the extracted suspension in load of discharge device is introduced with temperature (TS) to a mixing buffer container by a pump and the liquid phase is separated from the suspension contained in the discharge device. The temperature of the suspension in the buffer container is elevated from the way of secondary area in the buffer container and/or pipelines of the buffer container by external energy source at a value of T(pu) above of T s(aus) and/or the total mole fraction of the ingredients is increased in the liquid residual phase of the suspension in the buffer container through external additive in the ingredients at a value of M b, p u (ges) above of M b, r (ges). The T(pu)-T s(aus) is greater than or equal to 0.1 K. The increasing of M b, r ges at M b, r (ges) is greater than or equal to 0.1%. The content of the liquid residual phase at the target product is greater than or equal 90 wt.%. The crystallization grade (Y) is 0.20-0.40.

    15.
    发明专利
    未知

    公开(公告)号:BRPI0719326A2

    公开(公告)日:2014-02-04

    申请号:BRPI0719326

    申请日:2007-12-07

    Applicant: BASF SE

    Abstract: The present invention relates to a process for purifying a gas mixture G-0 comprising dinitrogen monoxide, at least comprising the contacting of the gas mixture G-0 with a solvent mixture (I) at least comprising 50% by weight of water based on the overall solvent mixture (I), the pH of the solvent mixture (I) being in the range from 3.5 to 8.0, the desorption of a gas mixture G-1 from a composition (A), the contacting of the gas mixture G-1 with a solvent mixture (II) at least comprising 50% by weight of water based on the overall solvent mixture (II), the pH of the solvent mixture (II) being in the range from 2.0 to 8.0, and the desorption of a gas mixture G-2 from a composition (B), the pH being based in each case on a measurement with a glass electrode, and to the use of gas mixtures obtainable by a process according to the invention as oxidizing agents for olefins.

    Proceso para aislar N2O
    16.
    发明专利

    公开(公告)号:ES2428568T3

    公开(公告)日:2013-11-08

    申请号:ES07847970

    申请日:2007-12-07

    Applicant: BASF SE

    Abstract: Proceso para purificar una mezcla de gases G-0 que contiene monóxido de dinitrógeno y NOx, el cual comprendeal menos las siguientes etapas: A1 poner en contacto la mezcla de gases G-0 con una mezcla de solventes (I) que contiene al menos 50 % en pesode agua respecto de la totalidad de la mezcla de solventes (I), en cuyo caso el valor del pH de la mezcla desolventes (I) se encuentra en el rango de 3,5 a 8,0, para obtener una composición (A); A2 desorber una mezcla de gases G-1 de la composición (A) para obtener una mezcla de solventes (I'); B1 poner en contacto la mezcla de gases G-1 con una mezcla de solventes (II) que contiene al menos 50% en pesode agua respecto de la totalidad de la mezcla de solventes (II), en cuyo caso el valor del pH de la mezcla desolventes (II) se encuentra en el rango de 2,0 a 8,0, para obtener una composición (B); B2 desorber una mezcla de gases G-2 de la composición (B) para obtener una mezcla de solventes (II'); en cuyo caso el valor del pH se refiere respectivamente a una medición con un electrodo de vidrio, en cuyo caso elvalor del pH de la mezcla de solventes (I) o el valor de pH de la mezcla de solventes (II) o el valor de pH de lamezcla de solventes (I) y el valor de pH de la mezcla de solventes (II) se ajusta adicionando una base.

    PROCESS FOR PURIFYING DINITROGEN MONOXIDE

    公开(公告)号:CA2720405A1

    公开(公告)日:2009-10-08

    申请号:CA2720405

    申请日:2009-03-13

    Applicant: BASF SE

    Abstract: The present invention relates to a process for purifying a gas mixture containing dinitrogen monoxide at least comprising the at least in part condensation of a gas mixture G-I containing dinitrogen monoxide with a liquid composition Z-1 containing dinitrogen monoxide being obtained, and contacting the composition Z-1 with a gas mixture S-1, with a composition Z-2 and a gas mixture S-2 being obtained.

    PROCESS FOR ISOLATING N2O
    18.
    发明专利

    公开(公告)号:CA2720403A1

    公开(公告)日:2009-10-08

    申请号:CA2720403

    申请日:2009-03-13

    Applicant: BASF SE

    Abstract: The present invention relates to a process for purifying a gas mixture containing dinitrogen monoxide at least comprising treatment of a gas mixture G-O containing dinitrogen monoxide with a gas mixture G-A being obtained, at least comprising the absorption of the gas mixture G-O in a solvent mixture LM-I with an off-gas stream and a composition Z-A being obtained, and desorption of a gas mixture G-1 from the composition Z-A with a solvent mixture LM-I' being obtained, subsequent condensation of the gas mixture G-A with a liquid composition Z-1 containing dinitrogen monoxide and a gaseous mixture G-K being obtained, wherein the gaseous mixture G-K is recirculated to the process.

    Procedure for continuous separation of target product in the form of fine particle of crystallisate, comprises indirectly operating a heat exchanger having primary and secondary areas, which are spatially separated with one another

    公开(公告)号:DE102007043759A1

    公开(公告)日:2008-09-11

    申请号:DE102007043759

    申请日:2007-09-13

    Applicant: BASF SE

    Abstract: The procedure for continuous separation of target product (X) in the form of fine particle of crystallisate from a liquid phase (P) existing from the target product (X) and/or by the target product of different constituents, comprises indirectly operating a heat exchanger having primary and secondary areas, which are spatially separated with one another through a material divider that serves as an area for transmitting heat from the secondary area to the primary area by passing a stream at the liquid phase (P) in the secondary area of the heat exchanger. The procedure for continuous separation of target product (X) in the form of fine particle of crystallisate from a liquid phase (P) existing from the target product (X) and/or by the target product of different constituents, comprises indirectly operating a heat exchanger having primary and secondary areas, which are spatially separated with one another through a material divider that serves as an area for transmitting heat from the secondary area to the primary area by passing a stream at the liquid phase (P) in the secondary area of the heat exchanger during the primary area flows throughable simultaneously to a liquid cooling medium so that it forms fine particles of crystallisate of the target product in the secondary area under disposition of a liquid residual phase from the liquid phase (P). The total mole fraction of the liquid phase has the value of M b, p ges at the constituent (B i). The liquid residual phase (R) contains ingredients with a total mole fraction of M b, r (ges) greater than M b, p (ges) in comparison with the liquid phase (P). The content of residual phase in the target product is 70 wt.%. The cooling medium is suspended by fine particles of crystallisate of the target product in the liquid residual phase under receiving a suspension (S) having a crystallization grade (Y). The secondary area of the heat exchanger continuously takes the suspension with the temperature T s (aus). The suspension of fine particle crystallisate from the extracted suspension in load of discharge device is introduced with temperature (TS) to a mixing buffer container by a pump and the liquid phase is separated from the suspension contained in the discharge device. The temperature of the suspension in the buffer container is elevated from the way of secondary area in the buffer container and/or pipelines of the buffer container by external energy source at a value of T(pu) above of T s(aus) and/or the total mole fraction of the ingredients is increased in the liquid residual phase of the suspension in the buffer container through external additive in the ingredients at a value of M b, p u (ges) above of M b, r (ges). The T(pu)-T s(aus) is greater than or equal to 0.1 K. The increasing of M b, r ges at M b, r (ges) is greater than or equal to 0.1%. The content of the liquid residual phase at the target product is greater than or equal 90 wt.%. The crystallization grade (Y) is 0.20-0.40.

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