公开(公告)号：WO2010066601A3

公开(公告)日：2011-06-16

申请号：PCT/EP2009066063

申请日：2009-11-30

Applicant: BASF SE ,  SCHLIEPHAKE VOLKER ,  FRIESE THORSTEN ,  BOTT KLAUS ,  BLECHSCHMITT MICHAEL ,  BLUM TILL ,  MUELLER-ENGEL KLAUS JOACHIM

Inventor： SCHLIEPHAKE VOLKER ,  FRIESE THORSTEN ,  BOTT KLAUS ,  BLECHSCHMITT MICHAEL ,  BLUM TILL ,  MUELLER-ENGEL KLAUS JOACHIM

IPC: C07C51/42

CPC classification number: C07C51/42 ,  C07C57/04

Abstract: The invention relates to a method for cleaving Michael adducts that are contained in a fluid F at a weight proportion of = 10 wt % and that were formed in the production of acrylic acid or esters thereof, in a cleaving device, which comprises a pump P and a separation column K having installations that effect separation and a recirculation heat exchanger UW, wherein for the purpose of feeding the cleaving energy, the pump P draws sump fluid from the sump chamber of the separation column K and continuously feeds said sump fluid back into the sump chamber above the level of the sump fluid through the recirculation heat exchanger UW, and wherein the pump P is a radial centrifugal pump having an open impeller.

Abstract translation: 已经形成在制备丙烯酸或其酯的一种的流体F的裂解具有以重量计= 10重量％含有迈克尔加成物的比例的方法，用分离的背间隙装置，包括一个泵P，分离塔K 内部和循环热交换器UW，其特征在于，用于供给所述间隙能量的目的，泵P吸入ķ从分离塔的底部空间底部液体并经由再循环热交换器UW在底部空间底部液体的对象的上方连续地循环，并且所述泵P的径向离心泵开 是叶轮。

公开(公告)号：WO2014095437A3

公开(公告)日：2014-10-09

申请号：PCT/EP2013075875

申请日：2013-12-09

Applicant: BASF SE

Inventor： KORN TOBIAS JOHANNES ,  ZUROWSKI PETER ,  FRIESE THORSTEN ,  HAREMZA SYLKE ,  JÄGER ULRICH ,  RISSEL STEFFEN ,  SCHLIEPHAKE VOLKER

IPC: C07C69/54 ,  C07C57/04

CPC classification number: C07C51/50 ,  C07C67/62 ,  C07C57/04 ,  C07C69/54

Abstract: The invention relates to a method for stabilising acrylic compounds, wherein a liquid phase, which contains at least one acrylic compound from the group acrylic acid, methacrylic acid and their respective esters, is mixed with at least one metal from the group copper, manganese and cerium and at least one ligand from the group consisting of a) quinoline compounds of formula (I), wherein the symbols have the following meanings: X is OH, NH2, O-C1-C4-alkyl, preferably OCH3, O-C(O)-C1-C4-alkyl, preferably O-C(O)-CH3, O-C(O)-C2H5 or O-C(O)-phenyl; R1 is H, or (C1-C4)-alkyl, preferably methyl; R2 is H, C1-C4-alkyl, preferably methyl, Cl, Br or SO3H and R3 is H, Cl or Br; and N-oxides of compounds of formula (I), b) 2,2'-bis(2,3-dihydro-3-oxoindolylides) and c) aliphatic y-dentate ligands where y = 2-6, containing at least two nitrogen atoms and y-2 further coordinating aliphatic or aromatic C1-C4 carbon bridges containing nitrogen atoms or heteroatoms.

Abstract translation: 一种用于丙烯酸类化合物的稳定化处理，以得到包含含有选自丙烯酸，甲基丙烯酸及其各自的酯的选择，混合与选自铜，锰的至少一种金属和铈和选自以下组成的组中的至少一种配体的至少一种丙烯酸类化合物的液相 a）式（I）的喹啉化合物其中的符号具有以下含义：X是OH，NH 2，-O-C1-C4烷基，优选OCH 3，OC（O）-C 1 -C 4 - 烷基，优选-OC（O） - CH 3，OC（O）-C 2 H 5或OC（O） - 苯基; R1是H或（C1-C4） - 烷基，优选甲基; R2是H，C1-C4烷基，优选甲基，Cl，Br或SO3H，R3是H，Cl或Br; 和式（I），B）2,2'-双（2,3-二氢-3- oxoindolyliden）和c）的脂族，其中y = 2-6的y齿配体的化合物的N-氧化物，含有至少两个氮原子 和y-2是进一步配位的含氮或杂原子的脂族或芳族C 1 -C 4碳桥。

公开(公告)号：WO2011000808A2

公开(公告)日：2011-01-06

申请号：PCT/EP2010059161

申请日：2010-06-29

Applicant: BASF SE ,  BLUM TILL ,  ZUROWSKI PETER ,  RISSEL STEFFEN ,  HAREMZA SYLKE ,  FRIESE THORSTEN ,  JAEGER ULRICH ,  SCHLIEPHAKE VOLKER ,  MUELLER-ENGEL KLAUS JOACHIM ,  HAMMON ULRICH ,  HOEFER FRANK

Inventor： BLUM TILL ,  ZUROWSKI PETER ,  RISSEL STEFFEN ,  HAREMZA SYLKE ,  FRIESE THORSTEN ,  JAEGER ULRICH ,  SCHLIEPHAKE VOLKER ,  MUELLER-ENGEL KLAUS JOACHIM ,  HAMMON ULRICH ,  HOEFER FRANK

IPC: C07C51/25

CPC classification number: C07C51/252 ,  C07C51/44 ,  C07C57/04

Abstract: The invention relates to a method for separating a raw acrylic acid from a product gas mixture comprising glyoxal as auxiliary product of a heterogeneously catalyzed partial gas phase oxidation of at least one C3-precursor compound, comprising the absorption of the acrylic acid in a high-boiling absorption agent and the rectificative processing of the resulting absorbent, and wherein, in a distillation unit, an absorption agent contained in the sump fluid that has been removed from the sump chamber of the absorption column is distilled and is fed back into the absorption before remaining high-boiling components are removed, and wherein the glyoxal content of the raw acrylic acid is reduced by limiting the duration of the high-boiling components in the distillation unit.

Abstract translation: 从乙二醛作为分离粗丙烯酸的方法的副含有产物的至少一种C3-前体化合物的非均相催化部分气相氧化，其包括在所得到的吸收物的高沸点吸收剂和整流后处理丙烯酸的吸收的产物气体混合物，并且在从底部空间中的 包含在蒸馏装置的液体除去塔底的吸收柱在其中吸收剂蒸馏除去而剩余的高沸点组分被除去之前再循环到吸收，并通过在粗丙烯酸在乙二醛含量的蒸馏单元限制Schwersiederverweilzeit降低。

公开(公告)号：WO2009133042A3

公开(公告)日：2010-01-14

申请号：PCT/EP2009055014

申请日：2009-04-27

Applicant: BASF SE ,  BLUM TILL ,  ZUROWSKI PETER ,  RISSEL STEFFEN ,  HAREMZA SYLKE ,  FRIESE THORSTEN ,  JAEGER ULRICH ,  SCHLIEPHAKE VOLKER ,  MUELLER-ENGEL KLAUS JOACHIM ,  RUMPF BERND

Inventor： BLUM TILL ,  ZUROWSKI PETER ,  RISSEL STEFFEN ,  HAREMZA SYLKE ,  FRIESE THORSTEN ,  JAEGER ULRICH ,  SCHLIEPHAKE VOLKER ,  MUELLER-ENGEL KLAUS JOACHIM ,  RUMPF BERND

IPC: B01J19/00 ,  C07C57/04

CPC classification number: B01J19/0013 ,  B01J2219/00094

Abstract: A method is disclosed for transferring heat to a liquid F containing dissolved monomeric acrylic acid, acrylic acid oligomers obtained by Michael addition, and acrylic acid polymer with the help of an indirect heat exchanger to which the liquid F is fed at a temperature TF = 150°C and a heat transfer fluid W is fed at a temperature Tw > TF. In said method, gas bubbles or thin layers of liquid F bordering a gas phase are generated in the liquid F while said liquid F flows through the heat exchanger.

Abstract translation: 一种用于将热量传递至单体丙烯酸的方法，丙烯酸迈克尔低聚物和丙烯酸聚合物溶解使用间接换热器，其是具有温度TF = 150℃，用一个温度Tw的流体热载体W上的液体含有F F型液状 > TF，供给气体的气泡或邻近F液的薄层气相的通过热交换器的流动期间，在液F被实现的形成。

公开(公告)号：CA2885926A1

公开(公告)日：2014-04-10

申请号：CA2885926

申请日：2013-09-23

Applicant: BASF SE

Inventor： JAGER ULRICH ,  SCHLIEPHAKE VOLKER ,  LANG ORTMUND ,  PETZOLDT JOCHEN ,  KORN TOBIAS JOHANNES ,  BETTE VIRGINIE ,  HECHLER CLAUS

IPC: C07C67/08 ,  C07C67/54

Abstract: A continuous method for producing (meth)acrylates from C10 alcohol mixtures by reacting pure (meth)acrylic acid with an isomeric mixture of C10 alcohols of 2-propylheptanol as main isomer and at least one of the C10 alcohols 2-propyl-4-methylhexanol, 2-propyl-5-methylhexanol, 2-isopropylheptanol, 2-isopropyl-4-methylhexanol, 2-isopropyl-5-methylhexanol and/or 2-propyl-4,4-dimethylpentanol, and the use of a diester of dicarboxylic acids which are esterified with N-oxyl group containing compounds, as polymerisation inhibitors in such a method.

公开(公告)号：BRPI0721107A2

公开(公告)日：2014-03-04

申请号：BRPI0721107

申请日：2007-12-11

Applicant: BASF SE

Inventor： LIPOWSKY GUNTER ,  SCHLIEPHAKE VOLKER ,  RISSEL STEFFEN ,  JAEGER ULRICH ,  HOEFER FRANK ,  HAREMZA SYLKE ,  ZUROWSKI PETER ,  MUELLER-ENGEL KLAUS JOACHIM

IPC: C08K5/17 ,  C08F220/00 ,  F28D1/00

Abstract: Process for transferring heat to a liquid mixture comprising at least one (meth)acrylic monomer with the aid of an indirect heat exchanger comprises introducing the liquid mixture simultaneously into the primary side of the heat exchanger by a liquid heat carrier and secondary side of the heat exchanger, where: the liquid mixture comprising at least one (meth)acrylic monomer contains at least one added active compound other than (meth)acrylic monomers from tertiary amine or salts formed from a tertiary amine and Bronsted acid, and quaternary ammonium compounds. Process for transferring heat to a liquid mixture comprising at least one (meth)acrylic monomer with the aid of an indirect heat exchanger comprises introducing the liquid mixture simultaneously into the primary side of the heat exchanger by a liquid heat carrier and secondary side of the heat exchanger, where: the liquid mixture comprising at least one (meth)acrylic monomer contains at least one added active compound other than (meth)acrylic monomers from tertiary amine or salts formed from a tertiary amine and Bronsted acid, and quaternary ammonium compounds, with proviso that none of the tertiary and quaternary nitrogen atoms in the active compound bears a phenyl group, but at least partly contains an alkyl group.

公开(公告)号：ZA201008470B

公开(公告)日：2012-02-29

申请号：ZA201008470

申请日：2010-11-25

Applicant: BASF SE

Inventor： BLUM TILL ,  ZUROWSKI PETER ,  RISSEL STEFFEN ,  HAREMZA SYLKE ,  FRIESE THORSTEN ,  JAGER ULRICH ,  SCHLIEPHAKE VOLKER ,  MULLER-ENGEL KLAUS JOACHIM ,  RUMPF BERND

IPC: B01J20060101 ,  C07C20060101

Abstract: A process for transferring heat to a liquid F comprising dissolved monomeric acrylic acid, Michael acrylic acid oligomers, and acrylic acid polymer with the aid of an indirect heat exchanger to which are supplied the liquid F with a temperature TF of >=150° C. and a fluid heat carrier W with a temperature of TW>TF, wherein the formation of gas bubbles and/or of thin layers of liquid F adjoining a gas phase is brought about in the liquid F during the flow through the heat exchanger.

公开(公告)号：DE102010042216A1

公开(公告)日：2011-06-09

申请号：DE102010042216

申请日：2010-10-08

Applicant: BASF SE

Inventor： BLUM TILL ,  ZUROWSKI PETER ,  KORN TOBIAS JOHANNES ,  HAREMZA SYLKE ,  FRIESE THORSTEN ,  MARTIN FRIEDRICH-GEORG ,  JAEGER ULRICH ,  RISSEL STEFFEN ,  SCHLIEPHAKE VOLKER

IPC: C07C57/075 ,  C07C57/04 ,  C07C57/07

公开(公告)号：BE1018574A3

公开(公告)日：2011-04-05

申请号：BE200800502

申请日：2008-09-11

Applicant: BASF SE

Inventor： HEILEK JUERG ,  HAMMON ULRICH ,  MUELLER-ENGEL KLAUS JOACHIM ,  SCHLIEPHAKE VOLKER ,  BAUMANN DIETER

IPC: B01D9/00 ,  C07C51/42

Abstract: L'invention concerne un procédé de séparation en continu d'un produit cible X sous la forme d'un cristallisat finement divisé à partir d'une phase liquide contenant le produit cible X et des composants différents du cible X par cristallisation d'une suspension de refroidissement dans un échangeur de chaleur indirect, dans lequel la suspension de cristallisat formée est acheminée de l'échangeur de chaleur tout d'abord dans un réservoir tampon mélangé et, de celui-ci, à un dispositif de séparation de la suspension en cristallisat et en phase liquide, et dans lequel, par des mesures externes, la sursaturation de la suspension de cristallisat en produit cible X acheminée au réservoir tampon est supprimée.

公开(公告)号：DE102009000987A1

公开(公告)日：2010-04-15

申请号：DE102009000987

申请日：2009-02-18

Applicant: BASF SE

Inventor： HEILEK JOERG ,  SCHNEIDER WOLFGANG ,  GUNKEL WOLFGANG ,  SCHLIEPHAKE VOLKER ,  MUELLER-ENGEL KLAUS JOACHIM

IPC: B01D9/00 ,  B01D21/06

Abstract: The method involves supplying a suspension stream in a process chamber (7) to a supply-end, and delivering a mother liquor stream (2) from the chamber from a suspension stream under retention of crystals and formation of crystal bed (5). Force that is applied at a drive shaft (18) in a longitudinal direction in normal operation is continuously adjusted upwards. The shaft is rotatably supported around a longitudinal axis in mountings. Two bearings e.g. guiding bearing and radial bearing, are arranged in one of two mountings such that the bearings accommodate the force in one of the mountings.