公开(公告)号：US20180215724A1

公开(公告)日：2018-08-02

申请号：US15746082

申请日：2016-07-01

Applicant: BASF SE

Inventor： Alvaro Gordillo ,  Holger Werhan ,  Richard Dehn ,  Benoit Blank ,  Joaquim Henrique Teles ,  Stephan A Schunk ,  Markus Piepenbrink ,  Rene Backes ,  Lei Zhang

IPC: C07D307/46 ,  B01J23/42 ,  B01J21/18

CPC classification number: C07D307/46 ,  B01J21/18 ,  B01J23/42

Abstract: A process for preparing furan-2,5-dicarboxylic acid is disclosed. The process includes the following steps: preparing or providing a starting mixture including 5-(hydroxy-methyl)furfural (HMF), 5,5′-[oxy-bis(methylene)]bis-2-furfural (di-HMF), and water; subjecting said starting mixture to oxidation conditions in the presence of an oxygen-containing gas and a catalytically effective amount of a heterogeneous catalyst including one or more noble metals on a support so that both HMF and di-HMF react to give furane-2,5-dicarboxylic acid in a product mixture also including water and oxidation by-products. The use of a catalyst is also disclosed, the catalyst including one or more noble metals on a support as an heterogeneous oxidation catalyst for catalyzing in an aqueous starting mixture the reaction of both HMF and di-HMF to furane-2,5-dicarboxylic acid.

公开(公告)号：US09938548B2

公开(公告)日：2018-04-10

申请号：US14974267

申请日：2015-12-18

Applicant: BASF SE

Inventor： Christoph Fleckenstein ,  Mathieu Blanchot ,  Benoit Blank ,  Martin Kaller ,  Ulrik Stengel ,  Andrea Misske ,  Friederike Fleischhaker ,  Ritesh Nair

IPC: C07C47/40 ,  C07C69/54 ,  C12P17/04 ,  C07D307/46 ,  C08F220/28 ,  C09D133/14

CPC classification number: C12P17/04 ,  C07D307/46 ,  C08F220/28 ,  C08F2220/282 ,  C09D133/14

Abstract: The invention relates to a process for preparing a compound of the formula (I), in which R is H or C1-C6 alkyl, by reaction of at least one compound of the formula (II) in which R has the same definition as in the formula (I) and in which R1 is H, C1-C12 alkyl or C3-C12 cycloalkyl, with a compound of the formula (III) in which R2 is H or C(O)R3, in which R3 is H or C1-C12 alkyl, in the presence of at least one enzyme suitable for transesterification.

公开(公告)号：US09169227B2

公开(公告)日：2015-10-27

申请号：US13711717

申请日：2012-12-12

Applicant: BASF SE

Inventor： René Backes ,  Benoit Blank ,  Alois Kindler ,  Carmen Feldner

IPC: C07D307/48 ,  C07D307/46

CPC classification number: C07D307/48 ,  C07D307/46

Abstract: Method for producing 5-hydroxymethylfurfural (HMF), wherein a) solutions (hereinbelow called starting solution) which comprise a hexose and an organic solvent with a boiling point greater than 200° C. (at standard pressure) (for short called high-boiling component), and steam are fed to a reaction vessel, b) in the reaction vessel, a conversion of the hexose to HMF takes place in the presence of steam with the simultaneous distillative removal of the HMF and c) as distillate, an aqueous, HMF-comprising solution (hereinbelow called distillate) is obtained.

Abstract translation: 制备5-羟甲基糠醛（HMF）的方法，其中a）包含己糖和沸点大于200℃的有机溶剂（在标准压力下）（简称为高沸点）的溶液（以下称为起始溶液） 并且蒸汽进料到反应容器中，b）在反应容器中，己糖到HMF的转化在蒸汽存在下进行，同时蒸馏除去HMF，和c）作为馏出物，水， 获得含HMF的溶液（以下称为馏出物）。

公开(公告)号：US20130345450A1

公开(公告)日：2013-12-26

申请号：US13711810

申请日：2012-12-12

Applicant: BASF SE

Inventor： Ralf Böhling ,  Benoit Blank ,  Alois Kindler ,  Carmen Feldner ,  Sandra Umlauf

IPC: C07D307/46 ,  C07D307/68

CPC classification number: C07D307/46 ,  C07D307/68

Abstract: Method for producing solutions which comprise 5-hydroxymethylfurfural (HMF) and have a reduced content of starting materials of the HMF synthesis or a reduced content of by-products of the HMF synthesis (hereinbelow called product solution), which comprises treating solutions which comprise HMF starting materials or by-products of the HMF synthesis and an organic solvent having at least two ether groups (for short polyether) (hereinbelow called starting solution) in an evaporator with steam.

Abstract translation: 制备包含5-羟甲基糠醛（HMF）并且具有降低的HMF合成原料含量或HMF合成副产物含量（以下称为产品溶液）的溶液的方法，其包括处理包含HMF的溶液 在具有蒸汽的蒸发器中，HMF合成的原料或副产物和具有至少两个醚基团（短聚醚）的有机溶剂（以下称为起始溶液）。