VERFAHREN ZUR HERSTELLUNG VON N-VINYLCARBONSÄUREAMIDEN
    11.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON N-VINYLCARBONSÄUREAMIDEN 有权
    工艺生产N-乙烯基羧

    公开(公告)号:EP2376426A1

    公开(公告)日:2011-10-19

    申请号:EP09764823.2

    申请日:2009-12-04

    Applicant: BASF SE

    CPC classification number: C07C231/12 C07C233/03

    Abstract: The invention relates to a method for producing N-vinylcarboxamides by pyrolyzing a compound of the formula (I), in which R and R
    1 stand for H or C
    1 to C
    6 alkyl, in the presence of solids that are doped with alkali metal or alkaline-earth metal ions under reduced pressure at a temperature of 330 to 750°C by splitting off hydrogen cyanide and cooling, separating, and isolating the reaction products, wherein a solid arranged in a tubular reactor is treated with a solution of an alkali metal and/or alkaline-earth metal base at a temperature in the range of 0 to 250°C, the solution is discharged, the remaining solvent, which adheres to the catalyst that can be obtained in such away, is evaporated, and afterwards the catalyst is heated to a temperature of at least 380°C in order to activate the catalyst.

    VERFAHREN ZUR HERSTELLUNG CHLORIDFREIER POLYETHYLENIMINE
    13.
    发明公开
    VERFAHREN ZUR HERSTELLUNG CHLORIDFREIER POLYETHYLENIMINE 审中-公开
    用于生产氯化聚乙烯免费

    公开(公告)号:EP2931788A1

    公开(公告)日:2015-10-21

    申请号:EP13798349.0

    申请日:2013-12-02

    Applicant: BASF SE

    Abstract: The invention relates to methods for producing polyalkylene imines from alkylene imines in the presence of a liquid solvent and a catalyst, wherein the production occurs semi-discontinuously in a reaction vessel. Optionally, the production occurs in the presence of additional additives. The invention further relates to polyalkylene imines produced in accordance with such methods and formulations thereof, in particular such having a low content of chloride-containing compounds. Such polyalkylene imines are used in the fields of medical equipment, pressure media, wastewater treatment, surface treatment, cosmetics, detergents, biotechnology, packaging, electronics, paper, construction chemistry, textiles, chromatography, ion exchangers, the oil industry, ceramics, glass, membrane technology, catalysts, electroplating applications, biocides, or wood protection. Applications as corrosion inhibitors, dispersants, additives in oils, to formulate pharmaceuticals, hair-care agents, fragrances, and aromas, to produce gene vectors, to functionalize and modify surfaces in electroplating and medical equipment, or to produce cleaning systems for the semiconductor industry and lithium batteries are also possible.

    VERFAHREN ZUR HYDROLYSE VON VINYLCARBONSÄUREAMIDEINHEITEN ENTHALTENDEN POLYMEREN
    14.
    发明公开
    VERFAHREN ZUR HYDROLYSE VON VINYLCARBONSÄUREAMIDEINHEITEN ENTHALTENDEN POLYMEREN 有权
    乙烯基羧酰胺含聚合物的方法水解

    公开(公告)号:EP2346907A1

    公开(公告)日:2011-07-27

    申请号:EP09744405.3

    申请日:2009-11-02

    Applicant: BASF SE

    CPC classification number: C08F8/12 C08F126/06

    Abstract: A process for hydrolyzing polymers containing vinylcarboxamide units by heating polymers containing vinylcarboxamide units in an aqueous medium in the presence of acids or bases, wherein an aqueous solution or dispersion of a polymer containing vinylcarboxamide units and an aqueous solution of an acid or base are supplied continuously to a tubular reactor under elevated pressure, and 0.05 to less than one equivalent of an acid or base is used per vinylcarboxamide equivalent, and the mixture is passed through the tubular reactor at a temperature of >100°C up to 250°C, decompressed and cooled.

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