公开(公告)号：EP1637219A2

公开(公告)日：2006-03-22

申请号：EP05021595.3

申请日：2000-08-15

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： Wang, Yong ,  Vanderwiel, David, P. ,  Tonkovich, Anna, Lee, Y. ,  Gao, Yufei ,  Baker, Edddie, G.

IPC: B01J8/02 ,  B01J12/00 ,  B01J19/24 ,  B01J23/89 ,  B01J35/00 ,  B01J35/10 ,  C07C1/04 ,  C10G2/00

CPC classification number: C10G2/332 ,  B01J8/0285 ,  B01J12/007 ,  B01J19/0093 ,  B01J19/248 ,  B01J19/249 ,  B01J19/2495 ,  B01J23/8913 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/10 ,  B01J35/1076 ,  B01J37/0217 ,  B01J37/0225 ,  B01J37/0238 ,  B01J37/0244 ,  B01J37/0248 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  B01J2219/00984 ,  B01J2219/2453 ,  B01J2219/2458 ,  B01J2219/2462 ,  B01J2219/32244 ,  B01J2219/32293 ,  B01J2219/32296 ,  B01J2219/32408 ,  B01J2219/32466 ,  B01J2219/32475 ,  C07C1/041 ,  C07C1/0425 ,  C07C1/0455 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C10G2/32 ,  C10G2/33 ,  C10G2/34 ,  C10G2/341

Abstract: The present invention relates to a method of hydrogenating carbon monoxide. The method comprises providing a catalyst, passing a feed stream of carbon monoxide and hydrogen gases through the catalyst and heating the catalyst. The invention provides the ability to hydrogenate carbon monoxide with low contact times, good conversion rates and low methane selectivities. In a preferred method, the catalyst comprises a Fischer-Tropsch catalytic metal.

Abstract translation: 本发明涉及一氧化碳氢化方法。 该方法包括提供催化剂，使一氧化碳和氢气的进料流通过催化剂并加热催化剂。 本发明提供了以低接触时间，良好的转化率和低的甲烷选择性氢化一氧化碳的能力。 在优选的方法中，催化剂包括费 - 托催化金属。

公开(公告)号：EP2208525A3

公开(公告)日：2012-04-25

申请号：EP10003851.2

申请日：2001-01-24

Applicant: Battelle Memorial Institute

Inventor： Tonkovich, Anna Lee Y ,  Wang, Yong ,  Wegeng, Robert S. ,  Gao, Yufei

IPC: B01J8/02 ,  B01J12/00 ,  C01B3/38

CPC classification number: B01J19/0093 ,  B01J8/0285 ,  B01J8/067 ,  B01J12/007 ,  B01J19/249 ,  B01J2208/00194 ,  B01J2208/00212 ,  B01J2208/00309 ,  B01J2219/00783 ,  B01J2219/00788 ,  B01J2219/00822 ,  B01J2219/00835 ,  B01J2219/0086 ,  B01J2219/00873 ,  B01J2219/00984 ,  B01J2219/2453 ,  B01J2219/2454 ,  B01J2219/2458 ,  B01J2219/2465 ,  B01J2219/2481 ,  B01J2219/2497 ,  C01B3/16 ,  C01B3/38 ,  C01B3/384 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/0495 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/0833 ,  C01B2203/1005 ,  C01B2203/1023 ,  C01B2203/1029 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/1288 ,  C01B2203/1619 ,  C01B2203/1633 ,  C01B2203/1652 ,  C01B2203/1676 ,  C01B2203/169 ,  F28D7/00 ,  Y02P20/52

Abstract: The present invention relates to a process for the steam reforming of a hydrocarbon, comprising: passing a feed stream comprising hydrocarbon gas and steam into at least one reaction chamber; said reaction chamber comprising a catalyst that catalyzes the reaction of said hydrocarbon gas and steam to produce a gaseous mixture comprising at least carbon monoxide and hydrogen gas; wherein the contact time of the reactant with the catalyst is less than 0.3 seconds; transferring heat from at least one heat exchanger into the at least one reaction chamber; and producing more than 0.01 SLPM of hydrogen gas per cubic centimeter of reactor volume, where reactor volume is defined as the sum of the volume of the reaction chamber(s) and heat exchange chamber(s) including the volume of chamber walls.

公开(公告)号：EP2264128A3

公开(公告)日：2011-04-27

申请号：EP10012645.7

申请日：2000-08-15

Applicant: BATTELLE MEMORIAL INSTITUTE Pacific Northwest Division Intellectual Property Services

Inventor： Wang, Yong ,  Vanderwiel, David P. ,  Tonkovich, Anna Lee Y ,  Gao, Yufei ,  Baker, Eddie G.

IPC: C10G2/00 ,  B01J37/02 ,  B01J35/00 ,  B01J35/10

CPC classification number: C10G2/332 ,  B01J8/0285 ,  B01J12/007 ,  B01J19/0093 ,  B01J19/248 ,  B01J19/249 ,  B01J19/2495 ,  B01J23/8913 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/10 ,  B01J35/1076 ,  B01J37/0217 ,  B01J37/0225 ,  B01J37/0238 ,  B01J37/0244 ,  B01J37/0248 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  B01J2219/00984 ,  B01J2219/2453 ,  B01J2219/2458 ,  B01J2219/2462 ,  B01J2219/32244 ,  B01J2219/32293 ,  B01J2219/32296 ,  B01J2219/32408 ,  B01J2219/32466 ,  B01J2219/32475 ,  C07C1/041 ,  C07C1/0425 ,  C07C1/0455 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C10G2/32 ,  C10G2/33 ,  C10G2/34 ,  C10G2/341

Abstract: The present invention relates to a method of hydrogenating carbon monoxide. The method comprises providing a catalyst, passing a feed stream of carbon monoxide and hydrogen gases through the catalyst and heating the catalyst. The invention provides the ability to hydrogenate carbon monoxide with low contact times, good conversion rates and low methane selectivities. In a preferred method, the catalyst comprises a Fischer-Tropsch catalytic metal.

Abstract translation: 本发明涉及一氧化碳氢化方法。 该方法包括提供催化剂，使一氧化碳和氢气的进料流通过催化剂并加热催化剂。 本发明提供了以低接触时间，良好的转化率和低的甲烷选择性氢化一氧化碳的能力。 在优选的方法中，催化剂包括费 - 托催化金属。

公开(公告)号：EP2210874A1

公开(公告)日：2010-07-28

申请号：EP10004430.4

申请日：2002-06-17

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： Werpy, Todd A. ,  Frye, John G Jr. ,  Wang, Yong ,  Zacher, Alan H.

IPC: C07D201/02 ,  C07D201/08 ,  C07D207/26

CPC classification number: C07D207/267 ,  C07D201/02 ,  C07D201/08

Abstract: The present invention provides methods for making N-methylpyrrolidine and analogous compounds via hydrogenation. Novel catalysts for this process, and novel conditions/yields are also described. Other process improvements may include extraction and hydrolysis steps. Some preferred reactions take place in the aqueous phase. Starting materials for making N-methylpyrmlidine may include succinic acid. N-methylsuccinimide, and their analogs.

Abstract translation: 本发明提供了通过氢化制备N-甲基吡咯烷和类似化合物的方法。 还描述了用于该方法的新型催化剂以及新的条件/产率。 其他工艺改进可能包括提取和水解步骤。 一些优选的反应发生在水相中。 制备N-甲基吡啶的原料可以包括琥珀酸。 N-甲基琥珀酰亚胺及其类似物。

公开(公告)号：EP2208525A2

公开(公告)日：2010-07-21

申请号：EP10003851.2

申请日：2001-01-24

Applicant: Battelle Memorial Institute

Inventor： Tonkovich, Anna Lee Y ,  Wang, Yong ,  Wegeng, Robert S. ,  Gao, Yufei

IPC: B01J8/02 ,  B01J12/00 ,  C01B3/38

CPC classification number: B01J19/0093 ,  B01J8/0285 ,  B01J8/067 ,  B01J12/007 ,  B01J19/249 ,  B01J2208/00194 ,  B01J2208/00212 ,  B01J2208/00309 ,  B01J2219/00783 ,  B01J2219/00788 ,  B01J2219/00822 ,  B01J2219/00835 ,  B01J2219/0086 ,  B01J2219/00873 ,  B01J2219/00984 ,  B01J2219/2453 ,  B01J2219/2454 ,  B01J2219/2458 ,  B01J2219/2465 ,  B01J2219/2481 ,  B01J2219/2497 ,  C01B3/16 ,  C01B3/38 ,  C01B3/384 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/0495 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/0833 ,  C01B2203/1005 ,  C01B2203/1023 ,  C01B2203/1029 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/1288 ,  C01B2203/1619 ,  C01B2203/1633 ,  C01B2203/1652 ,  C01B2203/1676 ,  C01B2203/169 ,  F28D7/00 ,  Y02P20/52

Abstract: The present invention relates to a process for the steam reforming of a hydrocarbon, comprising: passing a feed stream comprising hydrocarbon gas and steam into at least one reaction chamber; said reaction chamber comprising a catalyst that catalyzes the reaction of said hydrocarbon gas and steam to produce a gaseous mixture comprising at least carbon monoxide and hydrogen gas; wherein the contact time of the reactant with the catalyst is less than 0.3 seconds; transferring heat from at least one heat exchanger into the at least one reaction chamber; and producing more than 0.01 SLPM of hydrogen gas per cubic centimeter of reactor volume, where reactor volume is defined as the sum of the volume of the reaction chamber(s) and heat exchange chamber(s) including the volume of chamber walls.

Abstract translation: 本发明涉及一种用于烃的蒸汽重整的方法，包括：将包含烃气体和蒸汽的进料流通入至少一个反应室中; 所述反应室包括催化剂，所述催化剂催化所述烃气体和蒸汽的反应，以产生至少包含一氧化碳和氢气的气态混合物; 其中反应物与催化剂的接触时间小于0.3秒; 将热量从至少一个热交换器传递到所述至少一个反应室中; 并且每立方厘米反应器体积产生大于0.01SLPM的氢气，其中反应器体积被定义为包括室壁体积的反应室和热交换室的总和的总和。

公开(公告)号：EP1961724A3

公开(公告)日：2008-11-19

申请号：EP08009880.9

申请日：2006-12-16

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： Hu, Jianli ,  Wang, Yong ,  Dagle, Robert A. ,  Cao, Chunshe ,  Elliot, Douglas C. ,  Stevens, Don J. ,  White, James F. ,  Holladay, Jamelyn D.

IPC: C07C29/152 ,  C07C29/157 ,  B01J19/00

CPC classification number: C07C29/152 ,  B01J19/0093 ,  B01J2219/00835 ,  B01J2219/00873 ,  B01J2219/00961 ,  B01J2219/00984 ,  C07C29/157 ,  Y02P20/52 ,  C07C31/04 ,  C07C31/08 ,  C07C31/02

Abstract: Methods of synthesising C 2 + oxygenates from hydrogen and C 1 + oxygenate using Fisher-Tropsch catalysts are described. The catalysts are 100µm or less and may be formed from Rh or Pd containing composition subject to a RedOx reaction.

公开(公告)号：EP1950267A1

公开(公告)日：2008-07-30

申请号：EP07022855.6

申请日：2005-05-13

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： Herling, Darrell R. ,  Aardahl, Chris L. ,  Rozmiarek, Robert T. ,  Rappe, Kenneth G. ,  Wang, Yong ,  Holladay, Jamelyn D.

IPC: C10G2/00 ,  C07C41/01 ,  C01B3/38 ,  C10G31/06

CPC classification number: B01D3/06 ,  C01B3/386 ,  C01B2203/0261 ,  C01B2203/061 ,  C01B2203/085 ,  C01B2203/1047 ,  C01B2203/107 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/1288 ,  C01B2203/1619 ,  C07C29/1518 ,  C07C41/01 ,  C10G2/30 ,  C10G31/06 ,  C07C43/043 ,  C07C31/04 ,  C07C31/08 ,  C07C31/10 ,  C07C31/12 ,  C07C31/125

Abstract: The present invention provides a process for producing reagents for a chemical reaction by introducing a fuel containing hydrocarbons into a flash distillation process wherein the fuel is separated into a first component having a lower average molecular weight and a second component having a higher average molecular weight. The first component is then reformed to produce synthesis gas wherein the synthesis gas is reacted catalytically to produce the desire reagent.

Abstract translation: 本发明提供了生产试剂通过将含烃进闪蒸过程worin燃料被分离成具有较低平均分子量和具有较高平均分子量的第二组分的第一组分的燃料的化学反应的方法。 然后，将第一部件被重整以产生worin合成气被催化反应以产生所述愿望试剂的合成气。

公开(公告)号：EP1637219A3

公开(公告)日：2007-03-14

申请号：EP05021595.3

申请日：2000-08-15

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： Wang, Yong ,  Vanderwiel, David, P. ,  Tonkovich, Anna, Lee, Y. ,  Gao, Yufei ,  Baker, Edddie, G.

IPC: C10G2/00 ,  C07C1/04 ,  B01J19/00 ,  B01J37/02 ,  B01J35/00 ,  B01J35/10 ,  B01J8/02 ,  B01J12/00 ,  B01J19/24 ,  B01J23/89

CPC classification number: C10G2/332 ,  B01J8/0285 ,  B01J12/007 ,  B01J19/0093 ,  B01J19/248 ,  B01J19/249 ,  B01J19/2495 ,  B01J23/8913 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/10 ,  B01J35/1076 ,  B01J37/0217 ,  B01J37/0225 ,  B01J37/0238 ,  B01J37/0244 ,  B01J37/0248 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  B01J2219/00984 ,  B01J2219/2453 ,  B01J2219/2458 ,  B01J2219/2462 ,  B01J2219/32244 ,  B01J2219/32293 ,  B01J2219/32296 ,  B01J2219/32408 ,  B01J2219/32466 ,  B01J2219/32475 ,  C07C1/041 ,  C07C1/0425 ,  C07C1/0455 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C10G2/32 ,  C10G2/33 ,  C10G2/34 ,  C10G2/341

Abstract: The present invention relates to a method of hydrogenating carbon monoxide. The method comprises providing a catalyst, passing a feed stream of carbon monoxide and hydrogen gases through the catalyst and heating the catalyst. The invention provides the ability to hydrogenate carbon monoxide with low contact times, good conversion rates and low methane selectivities. In a preferred method, the catalyst comprises a Fischer-Tropsch catalytic metal.

Abstract translation: 本发明涉及氢化一氧化碳的方法。 该方法包括提供催化剂，使一氧化碳和氢气的进料流通过催化剂并加热催化剂。 本发明提供了以低接触时间氢化一氧化碳的能力，良好的转化率和低的甲烷选择性。 在优选的方法中，催化剂包含费 - 托催化金属。

公开(公告)号：EP1632282A2

公开(公告)日：2006-03-08

申请号：EP05077433.0

申请日：2001-01-24

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： Tonkovich, Anna Lee Y. ,  Wang, Yong ,  Wegeng, Robert S. ,  Gao, Yufel

IPC: B01J19/00 ,  C01B3/16 ,  C01B3/38

CPC classification number: B01J19/0093 ,  B01J8/0285 ,  B01J8/067 ,  B01J12/007 ,  B01J19/249 ,  B01J2208/00194 ,  B01J2208/00212 ,  B01J2208/00309 ,  B01J2219/00783 ,  B01J2219/00788 ,  B01J2219/00822 ,  B01J2219/00835 ,  B01J2219/0086 ,  B01J2219/00873 ,  B01J2219/00984 ,  B01J2219/2453 ,  B01J2219/2454 ,  B01J2219/2458 ,  B01J2219/2465 ,  B01J2219/2481 ,  B01J2219/2497 ,  C01B3/16 ,  C01B3/38 ,  C01B3/384 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/0495 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/0833 ,  C01B2203/1005 ,  C01B2203/1023 ,  C01B2203/1029 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/1288 ,  C01B2203/1619 ,  C01B2203/1633 ,  C01B2203/1652 ,  C01B2203/1676 ,  C01B2203/169 ,  F28D7/00 ,  Y02P20/52

Abstract: The present invention relates to a method and apparatus for thermal chemical reactions. The method and apparatus can provide an enhanced reaction rates for thermal chemical reactions. A microchannel apparatus comprising: a header; at least two flow microchannels, at least two orifices; wherein an orifice connects said header with each flow microchannel; and wherein the ratio of the cross-sectional area of each of said at least two orifices to the cross-sectional area of the flow microchannels connected to said orifices is between 0.0005 and 0.1.

Abstract translation: 本发明涉及一种用于热化学反应的方法和装置。 该方法和装置可以提供增强的反应速率进行热化学反应。 微通道设备，包括：一首标; 至少两个流动微流道，至少两个孔; 孔口的worin连接所述头部与每个流动微; 和worin每个所述的横截面面积之比至少两个孔，以连接到微流动通道的横截面面积所述孔为0.0005至0.1之间。