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公开(公告)号：EP1637219B1
公开(公告)日：2017-11-29
申请号：EP05021595.3
申请日：2000-08-15
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： Wang, Yong , Vanderwiel, David, P. , Tonkovich, Anna, Lee, Y. , Gao, Yufei , Baker, Edddie, G.
IPC: C10G2/00 , C07C1/04 , B01J19/00 , B01J37/02 , B01J35/00 , B01J35/10 , B01J8/02 , B01J12/00 , B01J19/24 , B01J23/89
CPC classification number: C10G2/332 , B01J8/0285 , B01J12/007 , B01J19/0093 , B01J19/248 , B01J19/249 , B01J19/2495 , B01J23/8913 , B01J35/0006 , B01J35/04 , B01J35/10 , B01J35/1076 , B01J37/0217 , B01J37/0225 , B01J37/0238 , B01J37/0244 , B01J37/0248 , B01J2219/00783 , B01J2219/00822 , B01J2219/00835 , B01J2219/00844 , B01J2219/0086 , B01J2219/00873 , B01J2219/00984 , B01J2219/2453 , B01J2219/2458 , B01J2219/2462 , B01J2219/32244 , B01J2219/32293 , B01J2219/32296 , B01J2219/32408 , B01J2219/32466 , B01J2219/32475 , C07C1/041 , C07C1/0425 , C07C1/0455 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C10G2/32 , C10G2/33 , C10G2/34 , C10G2/341
Abstract: The present invention relates to a method of hydrogenating carbon monoxide. The method comprises providing a catalyst, passing a feed stream of carbon monoxide and hydrogen gases through the catalyst and heating the catalyst. The invention provides the ability to hydrogenate carbon monoxide with low contact times, good conversion rates and low methane selectivities. In a preferred method, the catalyst comprises a Fischer-Tropsch catalytic metal.
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公开(公告)号：EP2264128B1
公开(公告)日：2017-10-25
申请号：EP10012645.7
申请日：2000-08-15
Inventor： Wang, Yong , Vanderwiel, David P. , Tonkovich, Anna Lee Y , Gao, Yufei , Baker, Eddie G.
CPC classification number: C10G2/332 , B01J8/0285 , B01J12/007 , B01J19/0093 , B01J19/248 , B01J19/249 , B01J19/2495 , B01J23/8913 , B01J35/0006 , B01J35/04 , B01J35/10 , B01J35/1076 , B01J37/0217 , B01J37/0225 , B01J37/0238 , B01J37/0244 , B01J37/0248 , B01J2219/00783 , B01J2219/00822 , B01J2219/00835 , B01J2219/00844 , B01J2219/0086 , B01J2219/00873 , B01J2219/00984 , B01J2219/2453 , B01J2219/2458 , B01J2219/2462 , B01J2219/32244 , B01J2219/32293 , B01J2219/32296 , B01J2219/32408 , B01J2219/32466 , B01J2219/32475 , C07C1/041 , C07C1/0425 , C07C1/0455 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C10G2/32 , C10G2/33 , C10G2/34 , C10G2/341
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3.发明公开
公开(公告)号：EP2295140A1
公开(公告)日：2011-03-16
申请号：EP10012516.0
申请日：2001-01-26
Inventor： Tonkovich, Anna Lee, Y. , Wang, Yong , Gao, Yufei , Baker, Eddie, G.
CPC classification number: B01J37/0244 , B01J35/04 , B01J37/0225 , B01J2219/00835 , Y10T29/49345
Abstract: The present invention provides a process in which a reactant is converted to a product by passing though a reaction chamber containing a catalyst, having a layered structure with, (1) a porous support, (2) a buffer layer, (3) an interfacial layer, and optionally (4) a catalyst layer.
Abstract translation: 本发明提供了一种方法，其中的反应物是通过使虽然反应室含有催化剂，具有层状结构，（1）的多孔载体，（2）的缓冲层转换为产物，（3）的界面 层，和任选的（4）的催化剂层。
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4.发明公开A chemical reactor and method for gas phase reactant catalytic reactions 无效Verfahren zur Dampfreformierung von Kohlenwasserstoffen
公开(公告)号：EP1568412A1
公开(公告)日：2005-08-31
申请号：EP05007860.9
申请日：2000-08-17
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： Tonkovich, Anna Lee Y. , Wang, Yong , Fitzgerald, Sean P. , Marco, Jennifer L. , Roberts, Gary L. , Vanderwiel, David P. , Wegeng, Robert S.
CPC classification number: C01B3/384 , B01J12/007 , B01J19/0093 , B01J23/58 , B01J23/60 , B01J35/04 , B01J37/0215 , B01J37/031 , B01J2219/00159 , B01J2219/00783 , B01J2219/00822 , B01J2219/00824 , B01J2219/00835 , B01J2219/00844 , B01J2219/00873 , B01J2219/00907 , B01J2219/00984 , B01J2219/2453 , B01J2219/2465 , B01J2219/2474 , B01J2219/2475 , B01J2219/2479 , B01J2219/2482 , B01J2219/2497 , C01B3/38 , C01B3/501 , C01B13/0251 , C01B2203/0233 , C01B2203/0283 , C01B2203/0405 , C01B2203/041 , C01B2203/044 , C01B2203/047 , C01B2203/065 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0833 , C01B2203/0838 , C01B2203/1005 , C01B2203/1011 , C01B2203/1029 , C01B2203/1035 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1094 , C01B2203/1217 , C01B2203/1223 , C01B2203/1241 , C01B2203/1258 , C01B2203/1276 , C01B2203/1288 , C01B2203/148 , C01B2203/1604 , C01B2203/1619 , C01B2203/1652 , C01B2203/1676 , C01B2210/0046 , H01M8/0612 , Y02P20/128 , Y02P20/52
Abstract: The present invention relates to methods for gas phase reactant catalytic reactions. In particular the present invention relates to a method of hydrocarbon steam reforming, comprising:
passing a reactant stream comprising steam and hydrocarbon into at least one reaction chamber;
wherein the reaction chamber has an internal volume having dimensions of chamber height, chamber width and chamber length;
wherein the chamber has a length of greater than 1 cm;
wherein the chamber height or chamber width is 2 mm or less;
wherein the reaction chamber is in thermal contact through a reaction chamber wall with an exothermic reaction chamber;
transferring heat from the exothermic reaction chamber to the reaction chamber through the reaction chamber wall at a rate such that heat flux between the reaction chamber and the exothermic reaction chamber is at least 0.6 W per cubic centimeter of the reaction chamber wall;
wherein the method is controlled under conditions such that the hydrocarbon has a contact time of less than 300 ms;
wherein the reactant stream is converted to a product stream; and
wherein at least 70% of the equilibrium conversion of the hydrocarbon entering the reaction chamber is converted to hydrogen, carbon monoxide or carbon dioxide.Abstract translation: 本发明涉及气相反应物催化反应的方法。 特别地，本发明涉及一种烃蒸汽重整方法，包括：将包含蒸汽和烃的反应物流通入至少一个反应室中; 其中所述反应室具有具有室高度，室宽度和室长度的尺寸的内部容积; 其中所述腔室具有大于1cm的长度; 其中室高度或室宽度为2mm或更小; 其中所述反应室通过反应室壁与放热反应室热接触; 通过反应室壁将热量从放热反应室传递到反应室，反应室和放热反应室之间的热通量至少为每立方厘米反应室壁0.6W; 其中所述方法在使得所述烃具有小于300ms的接触时间的条件下进行控制; 其中所述反应物流被转化成产物流; 并且其中进入反应室的烃的至少70％的平衡转化率转化为氢气，一氧化碳或二氧化碳。
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公开(公告)号：EP1568412B1
公开(公告)日：2012-05-09
申请号：EP05007860.9
申请日：2000-08-17
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： Tonkovich, Anna Lee Y. , Wang, Yong , Fitzgerald, Sean P. , Marco, Jennifer L. , Roberts, Gary L. , Vanderwiel, David P. , Wegeng, Robert S.
CPC classification number: C01B3/384 , B01J12/007 , B01J19/0093 , B01J23/58 , B01J23/60 , B01J35/04 , B01J37/0215 , B01J37/031 , B01J2219/00159 , B01J2219/00783 , B01J2219/00822 , B01J2219/00824 , B01J2219/00835 , B01J2219/00844 , B01J2219/00873 , B01J2219/00907 , B01J2219/00984 , B01J2219/2453 , B01J2219/2465 , B01J2219/2474 , B01J2219/2475 , B01J2219/2479 , B01J2219/2482 , B01J2219/2497 , C01B3/38 , C01B3/501 , C01B13/0251 , C01B2203/0233 , C01B2203/0283 , C01B2203/0405 , C01B2203/041 , C01B2203/044 , C01B2203/047 , C01B2203/065 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0833 , C01B2203/0838 , C01B2203/1005 , C01B2203/1011 , C01B2203/1029 , C01B2203/1035 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1094 , C01B2203/1217 , C01B2203/1223 , C01B2203/1241 , C01B2203/1258 , C01B2203/1276 , C01B2203/1288 , C01B2203/148 , C01B2203/1604 , C01B2203/1619 , C01B2203/1652 , C01B2203/1676 , C01B2210/0046 , H01M8/0612 , Y02P20/128 , Y02P20/52
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Patent Agency Ranking
公开(公告)号：EP2210875A1
公开(公告)日：2010-07-28
申请号：EP10004431.2
申请日：2002-06-17
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： Werpy, Todd A. , Frye, John G Jr. , Wang, Yong , Zacher, Alan H.
IPC: C07D201/02 , C07D201/08 , C07D207/267
CPC classification number: C07D207/267 , C07D201/02 , C07D201/08
Abstract: The present invention provides methods for making N-methylpyrrolidine and analogous compounds via hydrogenation. Novel catalysts for this process, and novel conditions/yields are also described. Other process improvements may include extraction and hydrolysis steps. Some preferred reactions take place in the aqueous phase. Starting materials for making N-methylpyrrolidine may include succinic acid, N-methylsuccinimide, and their analogs.
Abstract translation: 本发明提供通过氢化制备N-甲基吡咯烷和类似化合物的方法。 还描述了用于该方法的新型催化剂和新的条件/收率。 其他工艺改进可以包括提取和水解步骤。 一些优选的反应发生在水相中。 用于制备N-甲基吡咯烷的原料可包括琥珀酸，N-甲基琥珀酰亚胺及其类似物。
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公开(公告)号：EP1637222A3
公开(公告)日：2006-06-07
申请号：EP05021599.5
申请日：1998-06-19
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： Tonkovich, Anna Lee Y. , Roberts, Gary L. , Call, Charles J. , Wegeng, Robert S. , Wang, Yong
CPC classification number: H01M8/0631 , B01J19/0013 , B01J19/0093 , B01J2219/00103 , B01J2219/00783 , B01J2219/00822 , B01J2219/00824 , B01J2219/00835 , B01J2219/00844 , B01J2219/0086 , B01J2219/00869 , B01J2219/00873 , B01J2219/00891 , F28D9/00 , F28F2260/02 , H01M8/04074 , H01M8/0612 , H01M8/0662
Abstract: The present invention relates to an active microchannel heat exchanger, comprising a plurality of assemblies comprising microchannels, each of said plurality of assemblies comprising an exothermic reaction chamber, an exhaust chamber, and a heat exchanger chamber and a plurality of valves that permit taking at least one of said plurality of assemblies off line for clean up or regeneration while the remaining assemblies or units continue operation.
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公开(公告)号：EP1637222A2
公开(公告)日：2006-03-22
申请号：EP05021599.5
申请日：1998-06-19
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： Tonkovich, Anna Lee Y. , Roberts, Gary L. , Call, Charles J. , Wegeng, Robert S. , Wang, Yong
CPC classification number: H01M8/0631 , B01J19/0013 , B01J19/0093 , B01J2219/00103 , B01J2219/00783 , B01J2219/00822 , B01J2219/00824 , B01J2219/00835 , B01J2219/00844 , B01J2219/0086 , B01J2219/00869 , B01J2219/00873 , B01J2219/00891 , F28D9/00 , F28F2260/02 , H01M8/04074 , H01M8/0612 , H01M8/0662
Abstract: The present invention relates to an active microchannel heat exchanger, comprising a plurality of assemblies comprising microchannels, each of said plurality of assemblies comprising an exothermic reaction chamber, an exhaust chamber, and a heat exchanger chamber and a plurality of valves that permit taking at least one of said plurality of assemblies off line for clean up or regeneration while the remaining assemblies or units continue operation.
Abstract translation: 本发明涉及一种活性微通道热交换器，其包括多个包括微通道的组件，所述多个组件中的每个组件包括放热反应室，排气室和热交换器室以及允许至少取出至少 所述多个组件中的一个离线地进行清理或再生，而剩余的组件或单元继续操作。
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9.发明公开
公开(公告)号：EP2264128A2
公开(公告)日：2010-12-22
申请号：EP10012645.7
申请日：2000-08-15
Inventor： Wang, Yong , Vanderwiel, David P. , Tonkovich, Anna Lee Y , Gao, Yufei , Baker, Eddie G.
CPC classification number: C10G2/332 , B01J8/0285 , B01J12/007 , B01J19/0093 , B01J19/248 , B01J19/249 , B01J19/2495 , B01J23/8913 , B01J35/0006 , B01J35/04 , B01J35/10 , B01J35/1076 , B01J37/0217 , B01J37/0225 , B01J37/0238 , B01J37/0244 , B01J37/0248 , B01J2219/00783 , B01J2219/00822 , B01J2219/00835 , B01J2219/00844 , B01J2219/0086 , B01J2219/00873 , B01J2219/00984 , B01J2219/2453 , B01J2219/2458 , B01J2219/2462 , B01J2219/32244 , B01J2219/32293 , B01J2219/32296 , B01J2219/32408 , B01J2219/32466 , B01J2219/32475 , C07C1/041 , C07C1/0425 , C07C1/0455 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C10G2/32 , C10G2/33 , C10G2/34 , C10G2/341
Abstract: The present invention relates to a method of hydrogenating carbon monoxide. The method comprises providing a catalyst, passing a feed stream of carbon monoxide and hydrogen gases through the catalyst and heating the catalyst. The invention provides the ability to hydrogenate carbon monoxide with low contact times, good conversion rates and low methane selectivities. In a preferred method, the catalyst comprises a Fischer-Tropsch catalytic metal.
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公开(公告)号：EP2210877A1
公开(公告)日：2010-07-28
申请号：EP10004429.6
申请日：2002-06-17
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： Werpy, Todd A. , Frye, John G Jr. , Wang, Yong , Zacher, Alan H.
IPC: C07D207/267 , C07D201/02 , C07D201/08
CPC classification number: C07D207/267 , C07D201/02 , C07D201/08
Abstract: The present invention provides methods for making N-methylpyrrolidine and analogous compounds via hydrogenation. Novel catalysts for this process, and novel conditions/yields are also described. Other process improvements may include extraction and hydrolysis steps. Some preferred reactions take place in the aqueous phase. Starting materials for making N-methylpyrrolidine may include succinic acid, N-methylsuccinimide, and their analogs.
Abstract translation: 本发明提供通过氢化制备N-甲基吡咯烷和类似化合物的方法。 还描述了用于该方法的新型催化剂和新的条件/收率。 其他工艺改进可以包括提取和水解步骤。 一些优选的反应发生在水相中。 用于制备N-甲基吡咯烷的原料可包括琥珀酸，N-甲基琥珀酰亚胺及其类似物。
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