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公开(公告)号：CA2662782A1
公开(公告)日：2008-03-13
申请号：CA2662782
申请日：2007-09-04
Applicant: CERION TECHNOLOGY INC
Inventor： LANGNER ANDREAS , REED KENNETH J , HAILSTONE RICHARD K , DIFRANCESCO ALBERT GARY
Abstract: A method of making cerium dioxide nanoparticles includes: a) providing an aqueous reaction mixture having a source of cerous ion, a source of hydroxi de ion, a nanoparticle stabilizer, and an oxidant at an initial temperature no higher than about 2O°C; b) mechanically shearing the mixture and causing it to pass through a perforated screen, thereby forming a suspension of ceri um hydroxide nanoparticles; and c) raising the initial temperature to achiev e oxidation of cerous ion to eerie ion and thereby form cerium dioxide nanop articles having a mean diameter in the range of about 1 nm to about 15 nm. T he cerium dioxide nanoparticles may be formed in a continuous process.
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12.发明专利
公开(公告)号：BRPI0823310A2
公开(公告)日：2015-06-23
申请号：BRPI0823310
申请日：2008-12-17
Applicant: CERION TECHNOLOGY INC
Inventor： DIFRANCESCO ALBERT GARY , ALLSTON THOMAS D , HAILSTONE RICHARD K , LANGNER ANDREAS , REED KENNETH J
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13.发明专利
公开(公告)号：MX2011006461A
公开(公告)日：2011-11-18
申请号：MX2011006461
申请日：2008-12-17
Applicant: CERION TECHNOLOGY INC
Inventor： DIFRANCESCO ALBERT GARY , ALLSTON THOMAS D , HAILSTONE RICHARD K , LANGNER ANDREAS , REED KENNETH J
Abstract: Un proceso para hacer nanopartículas de dióxido de cerio que contienen al menos un material de transición (M) que comprende (a) proporcionar una mezcla de reacción acuosa que contiene una fuente de ión ceroso, una fuente de uno o más iones metálicos de transición (M), una fuente de ión de hidróxido, al menos un estabilizador de nanopartículas, y un oxidante a una temperatura inicial en un rango de alrededor de 200C alrededor de 950C; (b) cortar mecánicamente la mezcla y provocar que pase a través de una pantalla perforada, formando así una suspensión homogéneamente distribuída de nanopartículas de hidróxido de cerio; y (c) proporcionar condiciones de temperatura efectivas para lograr la oxidación de ión ceroso a ión cérico, formando así una corriente de producto que contiene nanopartículas de dióxido de cerio que contienen metal de transición, Ce1-xMxO2, en donde "x" tiene un valor de alrededor de 0.3 a alrededor de 0.8. Las nanopartículas así obtenidas, tienen una estructura de fluorita cúbica, una media de diámetro hidrodinámico en un rango de alrededor de 1 nm a alrededor de 10nm, y un diámetro geométrico menor a alrededor de 4 nm. Las nanopartículas cristalinas de dióxido de cerio que contienen metal de transición pueden usarse para preparar una dispersión de las partículas en un medio no polar.
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公开(公告)号：CA2662782C
公开(公告)日：2015-05-12
申请号：CA2662782
申请日：2007-09-04
Applicant: CERION TECHNOLOGY INC
Inventor： DIFRANCESCO ALBERT GARY , HAILSTONE RICHARD K , LANGNER ANDREAS , REED KENNETH J
Abstract: A method of making cerium dioxide nanoparticles includes: a) providing an aqueous reaction mixture having a source of cerous ion, a source of hydroxide ion, a nanoparticle stabilizer, and an oxidant at an initial temperature no higher than about 2O°C; b) mechanically shearing the mixture and causing it to pass through a perforated screen, thereby forming a suspension of cerium hydroxide nanoparticles; and c) raising the initial temperature to achieve oxidation of cerous ion to eerie ion and thereby form cerium dioxide nanoparticles having a mean diameter in the range of about 1 nm to about 15 nm. The cerium dioxide nanoparticles may be formed in a continuous process.
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公开(公告)号：CA2662769A1
公开(公告)日：2008-03-13
申请号：CA2662769
申请日：2007-09-04
Applicant: CERION TECHNOLOGY INC
Inventor： REED KENNETH J
Abstract: A method of Improving the efficiency of a diesel engine provided with a s ource of diesel fuel includes the steps of: a) adding to the diesel fuel a r everse-micellar composition having an aqueous first disperse phase that incl udes a free radical initiator and a first continuous phase that includes a f irst hydrocarbon liquid, a first surfactant, and optionally a co-surfactant, thereby producing a modified diesel fuel; and b) operating the engine, ther eby combusting the modified diesel fuel. The efficiency of a diesel engine p rovided with a source of diesel fuel and a source of lubricating oil can als o be improved by modifying the lubricating oil by the addition of a stabiliz ed nanoparticulate composition of cerium dioxide. The efficiency of a diesel engine can also be improved by adding to the diesel fuel a reverse-micellar composition that includes an aqueous disperse phase containing boric acid o r a borate salt.
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Patent Agency Ranking
公开(公告)号：CA2662765A1
公开(公告)日：2008-03-13
申请号：CA2662765
申请日：2007-09-04
Applicant: CERION TECHNOLOGY INC
Inventor： REED KENNETH J
Abstract: A fuel additive composition includes: a) a reverse-micellar composition h aving an aqueous disperse phase that includes cerium dioxide nanoparticles i n a continuous phase that includes a hydrocarbon liquid, a surfactant, and o ptionally a co-surfactant and b) a reverse micellar composition having an aq ueous disperse phase that includes a cetane improver effective for improving engine power during fuel combustion. A method of making a cerium-containing fuel additive includes the steps of: a) providing a mixture of a nonpolar s olvent, a surfactant, and a co-surfactant; and b) combining the mixture with an aqueous suspension of stabilized cerium dioxide nanoparticles.
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公开(公告)号：WO2011142834A8
公开(公告)日：2012-07-12
申请号：PCT/US2011000858
申请日：2011-05-13
Applicant: CERION TECHNOLOGY INC , REED KENNETH J , DIFRANCISCO ALBERT GARY , PROK GARY R , HAILSTONE RICHARD K
Inventor： REED KENNETH J , DIFRANCISCO ALBERT GARY , PROK GARY R , HAILSTONE RICHARD K
CPC classification number: C10L1/1233 , B01J13/0034 , B01J13/0047 , B82Y30/00 , C01F17/00 , C01F17/0043 , C01G25/00 , C01G25/02 , C01G49/0054 , C01G49/009 , C01G49/02 , C01G55/00 , C01P2002/30 , C01P2002/52 , C01P2002/72 , C01P2004/04 , C01P2004/51 , C01P2004/52 , C01P2004/64 , C01P2006/90 , C10G25/02 , C10L1/10 , C10L1/1881 , C10L10/02 , C10L10/06 , C10L2200/0222 , C10L2200/024 , C10L2200/0245 , C10L2200/0254 , C10L2230/22 , C10L2250/06 , C10L2270/026 , Y10T428/2982
Abstract: A process for making cerium-containing oxide nanoparticles includes providing an aqueous reaction mixture containing a source of cerous ion, optionally a source of one or more metal ions (M) other than cerium, a source of hydroxide ion, at least one monoether carboxylic acid nanoparticle stabilizer wherein the molar ratio of said monoether carboxylic acid nanoparticle stabilizers to total metal ions is greater than 0.2, and an oxidant at an initial temperature in the range of about 20°C to about 95°C. Temperature conditions are provided effective to enable oxidation of cerous ion to ceric ion, thereby forming a product dispersion of cerium-containing oxide nanoparticles, optionally containing one or more metal ions (M), Ce1-xMxO2-d, wherein "x" has a value from about 0.0 to about 0.95. The nanoparticles may have a mean hydrodynamic diameter from about 1 nm to about 50 nm, and a geometric diameter of less than about 45 nm.
Abstract translation: 制备含铈氧化物纳米颗粒的方法包括提供含有铈离子源的水性反应混合物，任选地除了铈以外的一种或多种金属离子（M）的源，氢氧根离子源，至少一种单醚羧酸 纳米粒子稳定剂，其中所述单醚羧酸纳米粒子稳定剂与总金属离子的摩尔比大于0.2，氧化剂在约20℃至约95℃范围内的初始温度。 提供温度条件有效地使铈离子氧化成铈离子，从而形成含铈氧化物纳米颗粒的产品分散体，任选地含有一种或多种金属离子（M），Ce1-xMxO2-d，其中“x”具有 值为约0.0至约0.95。 纳米颗粒可以具有约1nm至约50nm的平均流体动力学直径和小于约45nm的几何直径。
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公开(公告)号：EP2066767A4
公开(公告)日：2011-12-07
申请号：EP07814656
申请日：2007-09-04
Applicant: CERION TECHNOLOGY INC
Inventor： REED KENNETH J
IPC: C10L1/10 , B01F3/00 , B01F3/08 , B01F5/00 , B01F7/00 , B01F7/16 , B01F17/00 , B01J13/00 , C01F17/00 , C10L10/02 , C10L10/08 , C10L10/12 , C10M125/10
CPC classification number: B01J23/10 , B01F3/0807 , B01F7/164 , B01J13/0047 , B01J13/0086 , B82Y30/00 , C10L1/10 , C10L1/103 , C10L1/1233 , C10L1/125 , C10L1/1258 , C10L1/1608 , C10L1/1616 , C10L1/1811 , C10L1/1824 , C10L1/1881 , C10L1/1883 , C10L1/19 , C10L1/1985 , C10L1/2222 , C10L1/2437 , C10L10/02 , C10L10/08 , C10L10/12 , C10M2201/062 , C10N2230/06 , C10N2240/10 , Y02T50/678 , C10N2210/03 , C10N2220/082
Abstract: A method of making cerium dioxide nanoparticles includes: a) providing an aqueous reaction mixture having a source of cerous ion, a source of hydroxide ion, a nanoparticle stabilizer, and an oxidant at an initial temperature no higher than about 20° C.; b) mechanically shearing the mixture and causing it to pass through a perforated screen, thereby forming a suspension of cerium hydroxide nanoparticles; and c) raising the initial temperature to achieve oxidation of cerous ion to eerie ion and thereby form cerium dioxide nanoparticles having a mean diameter in the range of about 1 nm to about 15 nm. The cerium dioxide nanoparticles may be formed in a continuous process.
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公开(公告)号：EP2074201A4
公开(公告)日：2011-09-14
申请号：EP07814661
申请日：2007-09-04
Applicant: CERION TECHNOLOGY INC
Inventor： REED KENNETH J
IPC: C10L1/10 , B01F3/00 , B01F3/08 , B01F5/00 , B01F7/00 , B01F7/16 , B01F17/00 , B01J13/00 , C10L10/02 , C10L10/08 , C10L10/12 , C10M125/10
CPC classification number: B01J23/10 , B01F3/0807 , B01F7/164 , B01J13/0047 , B01J13/0086 , B82Y30/00 , C10L1/10 , C10L1/103 , C10L1/1233 , C10L1/125 , C10L1/1258 , C10L1/1608 , C10L1/1616 , C10L1/1811 , C10L1/1824 , C10L1/1881 , C10L1/1883 , C10L1/19 , C10L1/1985 , C10L1/2222 , C10L1/2437 , C10L10/02 , C10L10/08 , C10L10/12 , C10M2201/062 , C10N2230/06 , C10N2240/10 , Y02T50/678 , C10N2210/03 , C10N2220/082
Abstract: A method of making cerium dioxide nanoparticles includes: a) providing an aqueous reaction mixture having a source of cerous ion, a source of hydroxide ion, a nanoparticle stabilizer, and an oxidant at an initial temperature no higher than about 20° C.; b) mechanically shearing the mixture and causing it to pass through a perforated screen, thereby forming a suspension of cerium hydroxide nanoparticles; and c) raising the initial temperature to achieve oxidation of cerous ion to eerie ion and thereby form cerium dioxide nanoparticles having a mean diameter in the range of about 1 nm to about 15 nm. The cerium dioxide nanoparticles may be formed in a continuous process.
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20.发明公开FUEL ADDITIVE CONTAINING LATTICE ENGINEERED CERIUM DIOXIDE NANOPARTICLES 审中-公开燃油添加剂含有纳米颗粒的离网技术改进的氧化铈
公开(公告)号：EP2379221A4
公开(公告)日：2013-05-15
申请号：EP08879024
申请日：2008-12-17
Applicant: CERION TECHNOLOGY INC
Inventor： DIFRANCESCO ALBERT GARY , ALLSTON THOMAS D , HAILSTONE RICHARD K , LANGNER ANDREAS , REED KENNETH J
IPC: B01J23/00 , B01J23/10 , B01J23/22 , B01J23/24 , B01J23/34 , B01J23/72 , B01J23/74 , B01J23/745 , B01J35/00 , B82Y30/00 , C01F17/00 , C01G3/00 , C01G25/00 , C01G49/00 , C10L1/10 , C10L1/12 , C10L10/00 , C10L10/08 , C10M125/10
CPC classification number: B01J35/0013 , B01J23/002 , B01J23/10 , B01J23/22 , B01J23/24 , B01J23/34 , B01J23/72 , B01J23/74 , B01J23/745 , B01J37/03 , B01J2523/00 , B82Y30/00 , C01F17/0018 , C01F17/0043 , C01G3/00 , C01G25/00 , C01G49/0054 , C01G49/009 , C01P2002/30 , C01P2002/52 , C01P2002/70 , C01P2002/72 , C01P2004/04 , C01P2004/51 , C01P2004/64 , C10L1/10 , C10L1/1233 , C10L1/125 , C10L1/1608 , C10L1/1616 , C10L1/1824 , C10L1/1852 , C10L1/1881 , C10L1/1883 , C10L1/2222 , C10L10/00 , C10L10/08 , C10M125/10 , C10N2210/03 , C10N2220/082 , C10N2230/06 , C10N2240/10 , C10N2240/102 , B01J2523/3712 , B01J2523/48 , B01J2523/17 , B01J2523/842
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