Abstract:
An electrolyte sheet (10) comprises a substantially non-porous body and has at least one stress-relief area on at least a portion of the electrolyte sheet. The stress-relief area has a surface with a plurality of smoothly domed cells (30).
Abstract:
A solid oxide fuel cell device incorporates a sealing material resistant to hydrogen gas permeation at a sealing temperature in the intermediate temperature range of 600°C -900°C, the seal having a CTE in the 100x10- 7 /°C to 120x10- 7 /°C , wherein the sealing material comprises in weight %, of: (i) a 80 wt% to 100 wt % glass frit, the glass frit itself having a composition comprising in mole percent of : SiO 2 15-65 ; Li 2 O 0-5; Na 2 O 0-5; K 2 O 0-10; MgO 0-5; CaO 0-32; A1 2 O 3 0-10; B 2 O 3 0-50; SrO 0 to 25, wherein the total amount of alkalis is less than 10 mole%; and (ii) zirconia or leucite addition 0 wt % to 30 wt.
Abstract translation:固体氧化物燃料电池装置包括在600℃-900℃的中间温度范围内的密封温度下耐氢气渗透的密封材料,该密封具有100×10 -7 /℃的CTE, /℃至120×10 -7 /℃,其中所述密封材料以重量%计包含:(i)80重量%至100重量%的玻璃料,所述玻璃料本身具有组成 以摩尔百分比计包含:SiO 2 15-65; Li 2 SUB> 0 0-5; Na 2 O 0-5; K <2> 0 0-10; MgO 0-5; CaO 0-32; A1 2 SUB> O 3 SUB> 0-10; B 2 SUB> 0 3 SUB> 0-50; SrO 0至25,其中碱的总量小于10摩尔%; 和(ii)添加0重量%至30重量%的氧化锆或白榴石。
Abstract:
A stress reducing mounting for an electrolyte sheet assembly in a solid electrolyte fuel cell includes a support frame or manifold that supports a peripheral portion of the sheet assembly, a seal that affixes an edge to the frame or manifold, and a stress reducer disposed around the peripheral portion of the electrolyte sheet and the frame or manifold that reduces tensile stress in the peripheral portion of the electrolyte sheet when the peripheral portion is bent by pressure differentials or thermal differential expansion and mounting reduces cracking in the electrolyte sheet at the peripheral portions due to tensile forces. The stress reducer is either a convex curved surface on the frame or manifold that makes area contact with the peripheral portion when it bends or a stiffening structure on the sheet peripheral portion that renders the ceramic sheet material forming the peripheral portion more resistant to bending.
Abstract:
An exemplary fuel cell device assembly is a fuel cell stack assembly comprising: (i) a plurality of fuel cell packets, each of the packets comprising (a) a frame and (b) two planar electrolyte-supported fuel cell arrays, the fuel cell arrays arranged such that anode side of one fuel cell array faces the anode side of another fuel cell array, and the frame in combination with the fuel cell arrays defines a fuel chamber; (ii) a main enclosure enclosing the plurality of packets, such that the plurality of packets form a plurality of oxidant channels; (iii) a removable restrictor plate forming, in conjunction with the main enclosure, the plurality of oxidant channels; (iv) an inlet oxidant plenum manifold connected to one side of the oxidant channels; (v) an outlet oxidant plenum manifold connected to the other side of the oxidant channels; (vi) an inlet fuel manifold connected to one side of each of the fuel chambers; and (vii) an outlet fuel manifold connected to the other side of each of the fuel chambers.
Abstract:
A portable solid oxide fuel cell assembly comprising: (i) at least one multi-cell device formed at least in part by a compliant electrolyte sheet; (ii) a frame module supporting the device, said frame module providing air and fuel to the device, the frame forming, in conjunction with the device at least one of: a single fuel chamber, a single air chamber adjacent to the active area of the at least one multi-cell device; wherein said at least one multi-cell device generates more than 5V of electricity and has a maximum dimension of no more than 0.5 meter.
Abstract:
A solid oxide fuel cell device incorporates a sealing material resistant to hydrogen gas permeation at a sealing temperature in the intermediate temperature range of 600°C -800°C, the seal having a CTE in the 100x10 -7 /°C to 120x10 -7 /°C , wherein the sealing material comprises in weight %, of: (i) a 80 to 95 wt % of glass frit, the glass frit itself having a composition in mole percent of : SiO 2 70-85%; Al 2 O 3 0-5%; Na 2 O 3 0-8%; K 2 O 10-25%; ZnO 0-10%; ZrO 2 0-6%; MgO 0-7%; TiO 2 0-2%; and (ii) and 5wt % to 25wt% of addition comprising at least one of: alumina, zirconia or leucite.
Abstract translation:固体氧化物燃料电池装置在600℃-800℃的中间温度范围内的密封温度下结合有耐氢气渗透的密封材料,该密封件具有100×10 -7 /℃的CTE, /℃至120×10 -7 /℃,其中所述密封材料以重量百分比计包含:(i)80至95重量%的玻璃料,所述玻璃料本身具有 摩尔百分比:SiO 2 2 70-85%; 人 2 SUB> 0 3 SUB> 0-5%; Na 2 3 SUB> 0-8%; K <2> O 10-25%; ZnO 0-10%; ZrO <2> 0-6%; MgO 0-7%; TiO 2 0-2%; 和(ii)以及5重量%至25重量%的包含氧化铝,氧化锆或白榴石中的至少一种的添加剂。
Abstract:
A stress reducing mounting for an electrolyte sheet assembly in a solid electrolyte fuel cell is provided that includes a support frame or manifold having an inner edge portion that supports a peripheral portion of the sheet assembly, a seal that affixes an edge of the peripheral portion to the frame or manifold, and a stress reducer disposed around the peripheral portion of the electrolyte sheet and the frame or manifold that reduces tensile stress in the peripheral portion of the electrolyte sheet when the peripheral portion is bent by pressure differentials or thermal differential expansion. The stress reducer is at least one of a convex curved surface on the inner edge portion of the frame or manifold that makes area contact with the peripheral portion when it bends in response to a pressure differential or thermal differential expansion, and a stiffening structure on the sheet peripheral portion that renders the ceramic sheet material forming the peripheral portion more resistant to bending. The stress reducing mounting reduces cracking in the electrolyte sheet at the peripheral portions due to tensile forces.
Abstract:
A portable solid oxide fuel cell assembly comprising: (i) at least one multi-cell device formed at least in part by a compliant electrolyte sheet; (ii) a frame module supporting the device, said frame module providing air and fuel to the device, the frame forming, in conjunction with the device at least one of: a single fuel chamber, a single air chamber adjacent to the active area of the at least one multi-cell device; wherein said at least one multi-cell device generates more than 5V of electricity and has a maximum dimension of no more than 0.5 meter.
Abstract:
Solid oxide fuel cell assemblies comprise packets of multi-cell-sheet devices based on compliant solid oxide electrolyte sheets that form a fuel chamber and support anodes interiorly and cathodes exteriorly of the chamber that can be electrically interconnected to provide a compact, high voltage power-generating unit; added frames can support the oxide sheets and incorporate fuel supply and air supply conduits or manifolds permitting stacking of the assemblies into fuel cell stacks of any required size and power-generating capacity.