公开(公告)号：JPS63191670A

公开(公告)日：1988-08-09

申请号：JP2438287

申请日：1987-02-04

Applicant: DAICEL CHEM

Inventor： KAGOTANI MASAHIRO ,  AIZAWA KATSUMI

IPC: B41M5/00 ,  B41M5/50 ,  B41M5/52 ,  D21H27/00

Abstract: PURPOSE:To prevent an ink from bleeding upon recording, prevent the ink from bleeding even when a paper is wetted after recording and prevent a record from being lost, by incorporating a quaternary ammonium salt of carboxymethyl cellulose into recording paper. CONSTITUTION:A quaternary ammonium salt of carboxymethyl cellulose (CMC) can be synthesized from sodium salt of CMC and a quaternary ammonium salt such as a quaternary ammonium halide salt. As CMC, one having a degree of substitution by carboxymethyl of at least 1.5, and preferably at least 2.0, is used. The quaternary ammonium salt may be a lauryltrimethylammonium salt, a cetyltrimethylammonium salt or the like, and the anion constituting the salt is suitably a halide ion such as chloride, bromide and fluoride ion, sulfate ion, nitrate ion, phosphate ion or the like. Recording paper comprising the quaternary ammonium salt of CMC can be produced by providing the paper with a solution of the salt in an organic solvent by spraying, coating, immersion or impregnation, followed by removing the solvent.

公开(公告)号：JPH08259848A

公开(公告)日：1996-10-08

申请号：JP9154495

申请日：1995-03-24

Applicant: DAICEL CHEM

Inventor： OTSUKA YOSHIHIRO ,  AIZAWA KATSUMI ,  OSHINO YASUHIRO

IPC: C08F297/04 ,  C08G59/34 ,  C09D5/00 ,  C09D163/00 ,  C09D163/08

Abstract: PURPOSE: To obtain a primer composition containing a prescribed epoxy modified block copolymer, providing a resin molding of a polyolefin, etc., with a primer layer having excellent adhesiveness without pretreatment with a chlorine- based solvent. CONSTITUTION: This composition is obtained by blending (A) 100 pts.wt. of an epoxy modified block copolymer prepared by epoxidizing a conjugated diene- derived double bond of a block copolymer comprising a block composed of an aromatic vinyl compound (preferably styrene) structural unit and a block composed of a conjugated diene block (preferably butadiene and/or isoprene) structural unit with (B) 50-10,000 pts.wt., preferably 200-2,000 pts.wt. of an organic solvent (preferably toluene). To be concrete, a partially hydrogenated styrene-isoprene block copolymer is preferably used as the block copolymer of the component A. The degree of the epoxidation of the component A is preferably 1-5wt.% of oxirane oxygen concentration.

公开(公告)号：JPH08259747A

公开(公告)日：1996-10-08

申请号：JP9154395

申请日：1995-03-24

Applicant: DAICEL CHEM

Inventor： OTSUKA YOSHIHIRO ,  AIZAWA KATSUMI ,  OSHINO YASUHIRO

IPC: C08L23/04 ,  C08L63/00 ,  C08L63/08 ,  C08L101/00

Abstract: PURPOSE: To obtain a reclaimed thermoplastic resin composition excellent in flowability, strength properties, moldability, etc., by using a scrap of a structure constituted by laminating thermoplastic resins. CONSTITUTION: The reclaimed thermoplastic resin composition comprises 20-67wt.% flexible polyethylene resin, 30-77wt.% scrap of a structure prepared by laminating at least two thermoplastic resins being a combinations of materials selected from among a polyamide resin, a polyester resin, a polypropylene resin, a polyethylene resin, etc., and 3-20wt.% epoxidized (partially hydrogenated) diene polymer.

公开(公告)号：JPH0859958A

公开(公告)日：1996-03-05

申请号：JP22549894

申请日：1994-08-26

Applicant: DAICEL CHEM

Inventor： OTSUKA YOSHIHIRO ,  AIZAWA KATSUMI ,  WATANABE NOBUYUKI

IPC: C08L63/00 ,  C08G59/34 ,  C08L53/02 ,  C08L67/00 ,  C08L67/04

Abstract: PURPOSE: To obtain a polymer composition having excellent mechanical balance among rigidity, strength and impact resilience, meltable and moldable at a low temperature, having excellent moldability of mold release, adhesiveness, hydrolytic resistance and oil resistance. CONSTITUTION: This polymer composition comprises (a) 5-90wt.% of a caprolactam polymer having 1,000-200,000 number-average molecular weight and (b) 95-10wt.% of an epoxy modified block copolymer composed of an aromatic vinyl compound polymer block and a partially epoxy-added conjugated diene compound polymer block and/or a partially epoxy-added hydrogenated conjugated diene compound polymer block in the same molecule (100wt.% of total amount of the components (a) and (b)).

公开(公告)号：JPH0810615A

公开(公告)日：1996-01-16

申请号：JP14425494

申请日：1994-06-27

Applicant: DAICEL CHEM

Inventor： OTSUKA YOSHIHIRO ,  AIZAWA KATSUMI

IPC: B01J20/26 ,  C08G59/20 ,  C08G59/32 ,  C08L53/00 ,  C08L53/02 ,  C08L63/00

Abstract: PURPOSE:To obtain a water absorbing compsn. excellent in water absorbing, water swelling property, water retention and mechanical strength by constituting a principal part of a specific epoxy-modified block polymer and a highly water- absorbing resin to specify the water absorption thereof. CONSTITUTION:A water absorbing compsn. is constituted of an epoxy-modified block polymer (a) obtained by epoxidizing the unsaturated carbon-carbon double bond of the conjugated diene compd. of a block copolymer consisting of a polymer block based on a vinyl aromatic compd. and a polymer block based on a conjugated diene compd. and a highly water-absorbing resin (b) and the water absorption thereof is set to 5-100wt.%. By this constitution, the water absorbing compsn. excellent in water absorbency, water swelling property, water retention and mechanical strength is obtained.

公开(公告)号：JPH07206986A

公开(公告)日：1995-08-08

申请号：JP563894

申请日：1994-01-24

Applicant: DAICEL CHEM

Inventor： AIZAWA KATSUMI ,  OTSUKA YOSHIHIRO

IPC: C08F283/01 ,  C08G59/20 ,  C08G59/34 ,  C08G59/42 ,  C08L63/00 ,  C08L67/06

Abstract: PURPOSE:To obtain an unsaturated polyester resin composition composed of an unsaturated polyester resin, a specific polymer, a vinyl monomer and a curing agent and useful for the production of an automobile part, etc., excellent in shock resistance surface properties, weatherability, heat resistance and dimensional stability. CONSTITUTION:This unsaturated polyester resin composition is composed of (A) an unsaturated polyester resin in an amount of, preferably, 20-60 pts.wt., (B) an epoxy-modified block polymer obtained by the epoxidation of the double bonds of a conjugate diene-containing unsaturated-hydrocarbon moieties of a block copolymer comprising polymer blocks mainly containing vinyl aromatic compounds and polymer blocks mainly containing conjugate diene compounds in a molecule (an epoxy equivalent is preferably 140--10000), in an amount of, preferably, 5-40 pts.wt., (C) a vinyl monomer, e.g. styrene in an amount of, preferably, 20-70 pts.wt. and (D) a curing agent, e.g. dicumyl peroxide in an amount of, preferably, 0.5-3 pts.wt. (based on the total of the components A to C of 100 pts.wt.).

公开(公告)号：JPH10251357A

公开(公告)日：1998-09-22

申请号：JP8330597

申请日：1997-03-17

Applicant: DAICEL CHEM

Inventor： AIZAWA KATSUMI ,  OTSUKA YOSHIHIRO

IPC: C08F297/04 ,  C08F8/08 ,  C08F8/42 ,  C09J153/00

Abstract: PROBLEM TO BE SOLVED: To obtain the subject elastomer useful as a hot-melt adhesive excellent in initial bond strength, cohesive strength and heat resistance by modifying a specific epoxidized styrene-based thermoplastic elastomer with a specified silane compound. SOLUTION: This silane-modified thermoplastic elastomer is obtained by modifying (A) an epoxidixed styrene-based thermoplastic elastomer prepared by epoxidizing double bonds derived from a block copolymer comprising a polymer block consisting essentially of a styrene-based compound and a polymer block consisting essentially of a conjugated diene compound (a partial hydrogenated substance) with (B) (i) a silane compound (an acid anhydride) represented by the formula R -Si-Y3 (R is a carboxyl-containing hydrocarbon or a hydrocarbonoxy; Ys may receptively be different and at least one is a hydrolyzable organic functional group) or (ii) a silane compound represented by the formula R -Si-Y3 (R is a carboxylic acid anhydride group-containing hydrocarbon; Ys may respectively be different and at least one is a hydrolyzable organic functional group).

公开(公告)号：JPH08259822A

公开(公告)日：1996-10-08

申请号：JP9154695

申请日：1995-03-24

Applicant: DAICEL CHEM

Inventor： OTSUKA YOSHIHIRO ,  AIZAWA KATSUMI ,  OSHINO YASUHIRO

IPC: C08K5/098 ,  C08K5/09 ,  C08K5/45 ,  C08K5/46 ,  C08L25/04 ,  C08L25/12 ,  C08L53/00 ,  C08L101/00

Abstract: PURPOSE: To obtain a thermoplastic resin composition convertible into a molded and processed product having the homogeneously and closely matte surface thereof. CONSTITUTION: This component comprises (A) 100 pts.wt. amorphous resin (except a rubber-like polymer), (B) 0.01-20 pts.wt. epoxidized diene-based block copolymer and (C) a polyfunctional compound containing at least two same or different functional groups selected from carboxyl, amino and carboxylic acid anhydride groups and units of the formula C(=X)-NH-C(=Y) (X and Y denote each oxygen or sulfur atom or either thereof denotes oxygen atom and the other denotes sulfur atom) and/or (D) a metallic carboxylate in an amount of 0.01-20 pts.wt.

公开(公告)号：JPH08259811A

公开(公告)日：1996-10-08

申请号：JP9154795

申请日：1995-03-24

Applicant: DAICEL CHEM

Inventor： OTSUKA YOSHIHIRO ,  AIZAWA KATSUMI ,  OSHINO YASUHIRO

IPC: C08L9/00 ,  C08F8/08 ,  C08G59/34 ,  C08L21/00 ,  C08L23/00 ,  C08L33/04 ,  C08L33/06 ,  C08L53/00 ,  C08L53/02 ,  C08L63/08 ,  C08L81/02 ,  C08L87/00

Abstract: PURPOSE: To obtain a composition, containing a polyphenylene sulfide resin an epoxidized diene-based block copolymer, another hydrogenated conjugated diene-based polymer, etc., excellent in toughness such as impact strength or tensile elongation and moldability and moldable without causing an increase in viscosity and gelation. CONSTITUTION: This composition contains (A) a polyphenylene sulfide resin, (B) an epoxidized diene type block copolymer obtained by epoxidizing double bonds derived from a conjugated diene compound of a block copolymer comprising at least one polymer block consisting essentially of an aromatic vinyl compound and at least one polymer block consisting essentially of a conjugated diene compound and (C) one or more polymers selected from a hydrogenated conjugated diene-based polymer other than the component (B), an olefinic copolymer and an acrylic rubber.

公开(公告)号：JPH08245756A

公开(公告)日：1996-09-24

申请号：JP7945795

申请日：1995-03-10

Applicant: DAICEL CHEM

Inventor： OTSUKA YOSHIHIRO ,  AIZAWA KATSUMI ,  OSHINO YASUHIRO

IPC: C08J11/06 ,  B29B17/00 ,  B29B17/04 ,  B29K105/26 ,  C08G59/34 ,  C08L25/04 ,  C08L55/00 ,  C08L55/02 ,  C08L67/00 ,  C08L69/00 ,  C08L71/00 ,  C08L71/12 ,  C08L77/00 ,  C08L81/02

Abstract: PURPOSE: To obtain the subject composition, excellent in various physical properties such as impact resistance and molding processability, capable of recarrying out the molding processing and useful for countermeasures for environmental problems by crushing a molded and processed product and melt kneading the crushed product with an epoxidized (partially hydrogenated)diene-based polymer. CONSTITUTION: (A) A molded and processed product comprising (i) a thermoplastic resin (preferably a saturated polyester resin or a polycarbonate resin) or (ii) a thermoplastic resin composition (preferably comprising at least two selected from the saturated polyester resin, the polycarbonate resin, a polyamide resin, an ABS-based resin, a polystyrene-based resin, an As resin, a polyarylene sulfide resin, a polyarylene ester resin and polyphenylene ether resin) is crushed. The resultant resin pieces in an amount of 100 pts.wt. are then melt kneaded with (B) 0.1-30 pts.wt. epoxidized (partially hydrogenated)diene-based polymer to afford the objective composition. Furthermore, the component (A) is preferably a crushed product of a bottle, etc., made of polyethylene terephthalate resin.