公开(公告)号：DE69816706D1

公开(公告)日：2003-09-04

申请号：DE69816706

申请日：1998-05-11

Applicant: DAICEL CHEM

Inventor： KATAYAMA MASAHIRO ,  OTSUKA YOSHIHIRO

IPC: C08L51/04 ,  C08L25/06 ,  C08L53/02 ,  C08L67/02 ,  C08L69/00

Abstract: A thermoplastic resin composition is obtained by adding, to 100 parts by weight of a resin composition comprising polycarbonate (1)/styrenic resin (2) = 50/50 to 95/5 (% by weight), 0.1 to 20 parts by weight of a compatibilizing agent (3), if necessary together with a polyalkylene arylate resin (4) and/or a polyphenylene ether (5). Component (2) includes rubber-modified polystyrenic resins. The domains of component (2) dispersed in the matrix composed of component (1) are surrounded by component (3). Component (3) is a block copolymer (C) comprising a polystyrene block (A) and a terminally located polybutadiene block (B) with the double bond originating from butadiene being epoxidized. By adding an organophosphorus compound as flame retardant (6) and a fluororesin (7) as a flame retardant auxiliary (7), a halogen-free flame-retarded thermoplastic resin composition can be obtained. A polycarbonate-styrenic resin polymer blend improves flow characteristics and impact strength.

公开(公告)号：ID20276A

公开(公告)日：1998-11-19

申请号：ID980678

申请日：1998-05-07

Applicant: DAICEL CHEM

Inventor： KATAYAMA MASAHIRO ,  OTSUKA YOSHIHIRO

IPC: C08L51/04 ,  C08L25/06 ,  C08L53/02 ,  C08L67/02 ,  C08L69/00 ,  C08L25/10

Abstract: A thermoplastic resin composition is obtained by adding, to 100 parts by weight of a resin composition comprising polycarbonate (1)/styrenic resin (2) = 50/50 to 95/5 (% by weight), 0.1 to 20 parts by weight of a compatibilizing agent (3), if necessary together with a polyalkylene arylate resin (4) and/or a polyphenylene ether (5). Component (2) includes rubber-modified polystyrenic resins. The domains of component (2) dispersed in the matrix composed of component (1) are surrounded by component (3). Component (3) is a block copolymer (C) comprising a polystyrene block (A) and a terminally located polybutadiene block (B) with the double bond originating from butadiene being epoxidized. By adding an organophosphorus compound as flame retardant (6) and a fluororesin (7) as a flame retardant auxiliary (7), a halogen-free flame-retarded thermoplastic resin composition can be obtained. A polycarbonate-styrenic resin polymer blend improves flow characteristics and impact strength.

公开(公告)号：DE69816706T2

公开(公告)日：2004-03-11

申请号：DE69816706

申请日：1998-05-11

Applicant: DAICEL CHEM

Inventor： KATAYAMA MASAHIRO ,  OTSUKA YOSHIHIRO

IPC: C08L51/04 ,  C08L25/06 ,  C08L53/02 ,  C08L67/02 ,  C08L69/00

Abstract: A thermoplastic resin composition is obtained by adding, to 100 parts by weight of a resin composition comprising polycarbonate (1)/styrenic resin (2) = 50/50 to 95/5 (% by weight), 0.1 to 20 parts by weight of a compatibilizing agent (3), if necessary together with a polyalkylene arylate resin (4) and/or a polyphenylene ether (5). Component (2) includes rubber-modified polystyrenic resins. The domains of component (2) dispersed in the matrix composed of component (1) are surrounded by component (3). Component (3) is a block copolymer (C) comprising a polystyrene block (A) and a terminally located polybutadiene block (B) with the double bond originating from butadiene being epoxidized. By adding an organophosphorus compound as flame retardant (6) and a fluororesin (7) as a flame retardant auxiliary (7), a halogen-free flame-retarded thermoplastic resin composition can be obtained. A polycarbonate-styrenic resin polymer blend improves flow characteristics and impact strength.

公开(公告)号：ID20726A

公开(公告)日：1999-02-25

申请号：ID981026

申请日：1998-07-20

Applicant: DAICEL CHEM

Inventor： KATAYAMA MASAHIRO ,  ITO MASAAKI ,  OTSUKA YOSHIHIRO

IPC: C08L69/00 ,  C08L101/00 ,  C08L25/10 ,  C08L25/04

Abstract: A thermoplastic resin composition can be obtained by adding about 0.1 to 20 parts by weight of a diene-series block copolymer (2) to 100 parts by weight of a resin composition containing a polycarbonate-series resin (1) as a basic component of which the proportion of terminal hydroxy groups relative to the whole of the terminals is 1 mole% or above (about 5 to 40 mole%). The polycarbonate-series resin base may further comprise a thermoplastic resin composition (3) such as a rubber-modified styrenic resin. The block copolymer component (2) includes an epoxy-modified block copolymer, etc. When added an organophosphorus compound as a flame retardant (4), or a fluorine-containing resin as a flame-retartant auxiliary (5), a halogen-free flame-retardant thermoplastic resin composition can be obtained. A thermoplastic resin with an improved flowability and impact strength can be obtained by modifying a polymer blend of the polycarbonate-series resin and the styrenic-series resin in quality.

公开(公告)号：HK1016629A1

公开(公告)日：1999-11-05

申请号：HK99101463

申请日：1999-04-10

Applicant: DAICEL CHEM

Inventor： KATAYAMA MASAHIRO ,  OTSUKA YOSHIHIRO

IPC: C08L51/04 ,  C08L25/06 ,  C08L53/02 ,  C08L67/02 ,  C08L69/00 ,  C08L ,  C08K

Abstract: A thermoplastic resin composition is obtained by adding, to 100 parts by weight of a resin composition comprising polycarbonate (1)/styrenic resin (2) = 50/50 to 95/5 (% by weight), 0.1 to 20 parts by weight of a compatibilizing agent (3), if necessary together with a polyalkylene arylate resin (4) and/or a polyphenylene ether (5). Component (2) includes rubber-modified polystyrenic resins. The domains of component (2) dispersed in the matrix composed of component (1) are surrounded by component (3). Component (3) is a block copolymer (C) comprising a polystyrene block (A) and a terminally located polybutadiene block (B) with the double bond originating from butadiene being epoxidized. By adding an organophosphorus compound as flame retardant (6) and a fluororesin (7) as a flame retardant auxiliary (7), a halogen-free flame-retarded thermoplastic resin composition can be obtained. A polycarbonate-styrenic resin polymer blend improves flow characteristics and impact strength.

公开(公告)号：JP2007332389A

公开(公告)日：2007-12-27

申请号：JP2007243378

申请日：2007-09-20

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： YABUI AKIHIRO ,  OTSUKA YOSHIHIRO

IPC: C08F8/08

Abstract: PROBLEM TO BE SOLVED: To conquer the stickiness of epoxidized thermoplastic polymers and the troublesome handling by blocking nature or the like and to provide epoxidized thermoplastic polymers excellent in workability and processes for their production. SOLUTION: An epoxidized granular thermoplastic polymer comprises a shell-like surface layer insoluble in toluene at 25°C formed on the polymer. The process for the production of the epoxidized granular thermoplastic polymer comprises: the first step of epoxidizing a granular thermoplastic polymer in a water medium in the presence of an epoxidizing agent or the epoxidizing agent and a solvent for accelerating an epoxidation reaction and a phosphoric acid series compound; the second step of the washing with water, or the neutralization and washing with water of the epoxidized granular thermoplastic polymer; and the third step, if necessary, of removing the solvent for accelerating epoxidation reaction which may be used in the first step. COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 待解决的问题：解决环氧化热塑性聚合物的粘性和通过阻断性质等麻烦的处理，并提供可加工性优异的环氧化热塑性聚合物及其制备方法。 解决方案：环氧化颗粒状热塑性聚合物包含在聚合物上形成的25℃不溶于甲苯的壳状表面层。 生产环氧化颗粒状热塑性聚合物的方法包括：在环氧化剂或环氧化剂和用于加速环氧化反应和磷酸系的溶剂的存在下，在水介质中环氧化粒状热塑性聚合物的第一步骤 复合; 用水洗涤的第二步骤，或环氧化颗粒状热塑性聚合物用水中和和洗涤; 如果需要，可以在第一步骤中除去用于加速环氧化反应的溶剂的第三步骤。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2002194184A

公开(公告)日：2002-07-10

申请号：JP2000396021

申请日：2000-12-26

Applicant: DAICEL CHEM

Inventor： OTSUKA YOSHIHIRO

IPC: C08J5/00 ,  C08K3/00 ,  C08K5/00 ,  C08K5/098 ,  C08K5/1515 ,  C08L67/00 ,  C08L67/02 ,  C08L67/04

Abstract: PROBLEM TO BE SOLVED: To improve a stability of a melt molding process, a gas and odor generation and a bleeding of a stabilizer or an epoxy compound caused by a hot storage of a molded article. SOLUTION: A cycloaliphatic epoxy compound having a lactone chain is blended to a thermoplastic polyester resin.

公开(公告)号：JP2001172501A

公开(公告)日：2001-06-26

申请号：JP35631999

申请日：1999-12-15

Applicant: DAICEL CHEM

Inventor： OTSUKA YOSHIHIRO

IPC: C08L81/02 ,  C08F8/00 ,  C08F297/04 ,  C08G59/20 ,  C08G59/40

Abstract: PROBLEM TO BE SOLVED: To provide a thermoplastic resin composition which has improved mechanical characteristics such as toughness and impact strength, causes little amount of evolved gas when melt kneaded and molded, and possesses excellent thermal resistance. SOLUTION: The thermtoplastic resin composition with toughness has as the essential components (A) a polyarylene sulfide with a functional group having a reactivity with an epoxy group; (B) an epoxidated, aromatic vinyl/ conjugated diene-based copolymer; and (C) a hydrogenated, diene-based block copolymer.

公开(公告)号：JP2001123020A

公开(公告)日：2001-05-08

申请号：JP30532499

申请日：1999-10-27

Applicant: TOYO CLOTH CO ,  DAICEL CHEM

Inventor： MAEDA SHIZUO ,  ISHIIHARA KOICHI ,  OTSUKA YOSHIHIRO ,  MATSUDA TORU

IPC: C08J5/18 ,  C08L23/00 ,  C08L23/08 ,  C08L25/12 ,  C08L25/14 ,  C08L33/20 ,  C08L51/00 ,  C08L53/00 ,  C08L63/08

Abstract: PROBLEM TO BE SOLVED: To provide a thermoplastic resin composition which shows an excellent balance among the high-frequency welder suitability, the mold processibility, the appearance of a sheet molded product, the tearing strength, the tinting, etc., without causing any enviromnental pollution, and a sheet molded product. SOLUTION: A thermoplastic resin composition is prepared by compounding, against 100 pts.wt. (A+B) resin composition containing (A) from 99 to 1 wt.% thermoplastic olefin resin and (B) from 1 to 99 wt.% acrylonitrile/styrene/alkyl acrylate copolymer, (C) from 1 to 30 pts.wt. epoxidized diene block copolymer and (D) from 1 to 30 pts.wt. glycidyl group-containing copolymer comprising a glycidyl ester of an α-olefin and an α,β-unsaturated acid. A sheet molded product is obtained using this.

公开(公告)号：JPH10310694A

公开(公告)日：1998-11-24

申请号：JP12385797

申请日：1997-05-14

Applicant: DAICEL CHEM

Inventor： KATAYAMA MASAHIRO ,  OTSUKA YOSHIHIRO

IPC: C08L51/04 ,  C08L25/06 ,  C08L53/02 ,  C08L67/02 ,  C08L69/00

Abstract: PROBLEM TO BE SOLVED: To modify a polyblend of a polycarbonate resin and a styrene resin to obtain a thermoplastic resin compsn. improved in flowability and impact strength. SOLUTION: 100 pts.wt. polyblend comprising 50-95 wt.% polycarbonate resin (1) and 50-5 wt.% styrene resin (2) is compounded with 0.1-20 pts.wt. compatibilizer (3) and, if necessary, with a polyalkylene arylate resin (4) and a polyphenylene ether resin (5) to obtain the objective compsn. Ingredient (2) includes a rubbermodified polystyrene resin. The domain 2 of ingredient (2) dispersed in the matrix 1 of ingredient (1) is surrounded by ingredient (3). Ingredient (3) is a block copolymer (C) comprising a polystyrene block (A) and polybutadiene blocks (B) present at the molecular ends, and the double bonds of the polybutadiene blocks have been epoxidized. The addition of an organophosphorus compd. (6) as a flame retardant and a fluororesin (7) as an auxiliary flame retardant to the above-obtd. compsn. gives a nonhalogen flame-retardant thermoplastic resin compsn.