Abstract:
A metal/synthetic resin laminate comprising a metal substrate layer, an epoxy resin-based adhesive layer (a "1st adhesive layer"), an adhesive layer (a "2nd adhesive layer") comprising an epoxidized styrenic thermoplastic elastomer D prepared through epoxidation of a double bond derived from a conjugated diene compound of a block copolymer C comprising a polymer block A composed mainly of a styrenic compound and a polymer block B composed mainly of a conjugated diene compound or a partial hydrogenation product thereof, and a synthetic resin layer; and a synthetic resin-clad metallic pipe wherein the above metal substrate layer is tubular.
Abstract:
A metal/synthetic resin laminate comprising a metal substrate layer, an epoxy resin-based adhesive layer (a "1st adhesive layer"), an adhesive layer (a "2nd adhesive layer") comprising an epoxidized styrenic thermoplastic elastomer D prepared through epoxidation of a double bond derived from a conjugated diene compound of a block copolymer C comprising a polymer block A composed mainly of a styrenic compound and a polymer block B composed mainly of a conjugated diene compound or a partial hydrogenation product thereof, and a synthetic resin layer; and a synthetic resin-clad metallic pipe wherein the above metal substrate layer is tubular.
Abstract:
According to a first aspect of the present invention, a regenerated thermoplastic resin composition is offered by melt blending 0.1 to 30 parts by weight of an epoxidized (partially hydrogenated) diene-based polymer (B) to 100 parts by weight of resin pieces (A) obtained by crushing the molded products comprising a thermoplastic resin (A1) or a thermoplastic resin composition (A2). According to a second aspect of the present invention, a regenerated thermoplastic resin composition is offered comprising 20 to 67 weight % of a non-rigid polyethylene resin (a), 30 to 77 weight % of a waste material (b) of a structural product made by laminating at least two kinds of thermoplastic resins, and 3 to 20 weight % of epoxidized (partially hydrogenated) diene-based polymer.
Abstract:
A metal/synthetic resin laminate comprising a metal substrate layer, an epoxy resin-based adhesive layer (a "1st adhesive layer"), an adhesive layer (a "2nd adhesive layer") comprising an epoxidized styrenic thermoplastic elastomer D prepared through epoxidation of a double bond derived from a conjugated diene compound of a block copolymer C comprising a polymer block A composed mainly of a styrenic compound and a polymer block B composed mainly of a conjugated diene compound or a partial hydrogenation product thereof, and a synthetic resin layer; and a synthetic resin-clad metallic pipe wherein the above metal substrate layer is tubular.
Abstract:
PURPOSE: To obtain an adhesive polymer useful as a structural adhesive ranging from flexible to rigid and also as a composite material excellent in heat resistance and having high performance. CONSTITUTION: This adhesive is an epoxy-modified hydrogenated block copolymer produced by partially hydrogenating a block copolymer comprising a block polymer A mainly comprising a vinyl aromatic compound and a block polymer B mainly comprising a conjugated diene compound in one molecule and epoxidizing double bonds of unsaturated carbons in the conjugated diene compound in the partially hydrogenated block copolymer.
Abstract:
PURPOSE:To obtain the subject copolymer compsn. which is excellent in processing stability, hardly allowing the occurrence of a gel during extrusion. CONSTITUTION:This copolymer compsn. is prepd. by adding a block copolymer of an A-B-A type or an (A-B)n type (wherein A is an arom. vinyl polymer block; and B is a partially epoxidized hydrogenated conjugated-diene polymer block) as the processing stabilizer to a compsn. comprising 60-95wt.% ethylene-vinyl alcohol copolymer and 40-5wt.% polyamide resin.
Abstract:
PURPOSE:To provide a polymer compsn. having improved impact strength and oil resistance. CONSTITUTION:A thermoplastic polymer compsn. comprising (i) a vinyl. alcohol polymer and (ii) an epoxy-modified block copolymer comprising, in the same molecule, a polymer block of a vinyl arom. compd. and a polymer block of a conjugated diene compd. contg. a partially added epoxy and/or a polymer block of a hydrogenated conjugated diene compd. contg. a partially added epoxy.
Abstract:
PROBLEM TO BE SOLVED: To obtain an adhesive of epoxidized styrene-based thermoplastic elastomer for metal-vinyl chloride-based resin, and a metal-vinyl chloride-based laminate where the metallic base layer is bonded to the vinyl chloride-based resin layer via a layer of the adhesive. SOLUTION: This adhesive consists of a block copolymer C which is composed of polymer block A consisting mainly of a styrene-based compound and polymer block B consisting mainly of a conjugated diene compound which may be partially hydrogenated, where the double bond of the conjugated diene compound is epoxidized to form an epoxidized styrene-based thermoplastic elastomer D. Degree of epoxidation of the epoxidized styrene-based thermoplastic elastomer D is preferably in the range of 10 to 40%.
Abstract:
PURPOSE:To provide a liquid crystal polyester resin composition having flexibil ity imparted without practically reducing the properties essential to the liquid crystal polyester. CONSTITUTION:This liquid crystal polyester resin composition contains (a) 70 to 99 pts.wt. liquid crystal polyester composed of the repeating units represented by the general formulae (I), (II) and (III) shown below; (I) COR O: 20 to 80mol% (II): COR CO: 40 to 10mol% (III): OR O: 40 to 10mol% [the molar ratio of (II) to (III) is 1 in the formulae, R is a 6 to 15C divalent aromatic derivative residue and R is a 6 to 15C divalent aromatic derivative residue, a 4 to 20C divalent alicyclic derivative residue or a 1 to 20C divalent aliphatic derivative residue. R is a 6 to 15C divalent aromatic derivative residue, a 4 to 20C divalent alicyclic derivative residue or a 1 to 20C divalent aliphatic derivative residue] and (b) 1 to 30 pts.wt. epoxy-modified block polymer synthesized by epoxydizing an unsaturated carbon-carbon double bond of a conjugated diene compound in a partly hydrogenated block polymer.
Abstract:
PURPOSE:To produce economically a cellulose ether of a uniform distribution of substituents, by treating cellulose with an alkali to form an alkali cellulose in a process for producing a cellulose ether, and further carrying out a specified treatment on this alkali cellulose with an epoxy compound. CONSTITUTION:Cellulose (e.g., wood pulp) is dispersed in 5-30pts.wt., per pt.wt. cellulose, lower aliphatic alcohol (e.g., t-butanol)/water solvent containing 1.0-3.0mol. of an alkali (e.g., NaOH) per mol of glucose residues of cellulose in a nitrogen stream to give an alkali cellulose, which is reacted with 2.5-5mol., per glucose residue, of an epoxy compound (e.g., ethylene oxide) in the presence of an alkali and further reacted with 0.1-0.9mol., per mol of the alkali metal hydroxide used, of a compound (e.g., 2-chloroethanol) which can react with an alkali to form an epoxy compound.