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    PRODUCTION OF CARBOXYLATE, SULFONIC ACID GROUP-CONTAINING POLYSILOXANE AND ITS PRODUCTION
    11.
    发明专利
    PRODUCTION OF CARBOXYLATE, SULFONIC ACID GROUP-CONTAINING POLYSILOXANE AND ITS PRODUCTION 失效

    公开(公告)号：JPH1095747A

    公开(公告)日：1998-04-14

    申请号：JP23585697

    申请日：1997-09-01

    Applicant: DEGUSSA

    Inventor： WIELAND STEFAN DR ,  PANSTER PETER DR

    IPC: B01J31/06 ,  C07B61/00 ,  C07C67/08 ,  C07C69/14 ,  C07C69/80

    Abstract: PROBLEM TO BE SOLVED: To obtain a carboxylate by reacting an alcohol with a carboxylic acid in the presence of a sulfonic acid group a polysiloxane having under a vigorous agitation. SOLUTION: This method for producing a carboxylate ester comprises mixing an alcohol with a carboxylic acid and/or a carboxylic anhydride and/or a carboxylate ester and/or a partially esterified carboxylic acid, vigorously stirring the mixture in the presence of a sulfonic acid group-containing solid polysiloxane insoluble in the reaction solvent at 100-220 deg.C, simultaneously continuously separating off the by-produced reaction water, and subsequently isolating the ester. The polysilixane is modified with a soluble titanium, zirconium and/or aluminum compounds. The polysiloxane comprises 0.01-3mm spherical granules, and has a specific surface area of 0.1-1200m /g, a specific pore volume of 0.01-6.0ml/g and a bulk density of 50-1000g/liter.

    12.
    发明专利
    未知

    公开(公告)号：DE19635769A1

    公开(公告)日：1998-03-05

    申请号：DE19635769

    申请日：1996-09-04

    Applicant: DEGUSSA

    Inventor： WIELAND STEFAN DR ,  PANSTER PETER DR

    IPC: B01J31/06 ,  C07B61/00 ,  C07C67/08 ,  C07C69/14 ,  C07C69/80 ,  C07C67/03 ,  C07C69/30 ,  C07C69/58 ,  C08L83/04

    Abstract: The preparation of carboxylic acid esters comprises: (a) preparation of a reaction mixture containing an alcohol and at least one compound chosen from a carboxylic acid, carboxylic acid anhydride, carboxylic acid ester or partially esterified carboxylic acid; (b) heating the reaction mixture in the presence of a solid polysiloxane with sulphonic acid groups which is insoluble in the reaction medium, whilst stirring intensively and removing water formed in the reaction; and (c) isolating the chosen ester product. Also claimed are: (i) polysiloxanes with sulphonic acid groups, whose surface is modified with 0.1-1 % aluminium oxide compounds or 0.1-5 % titanium or zirconium oxide compounds, with respect to the solids content and (ii) the preparation of surface-modified polysiloxanes with sulphonic acid groups.

    13.
    发明专利
    未知

    公开(公告)号：DK0672640T3

    公开(公告)日：1998-02-02

    申请号：DK95103449

    申请日：1995-03-10

    Applicant: REMMERS BAUCHEMIE GMBH ,  DEGUSSA

    Inventor： PANSTER PETER DR ,  WIELAND STEFAN DR ,  GOEBEL THOMAS DR ,  BRANDES CHRISTIAN ,  WERNER UTE ,  ZINSMEISTER KLAUS DR ,  LANGEN MARION

    IPC: C04B41/49 ,  C04B41/64 ,  C09D183/04

    Abstract: Method for the undercoating or impregnation of natural or synthetic mineral building materials with aq. suspensions or solns. that contain 0.1-70 (10-30) wt.% at least one silicon-contg. ion exchange material of formula (I) or an oligomer thereof, w.r.t. soln. or suspension. The treatment method is a single- or multi-stage process and is opt. combined with a treatment process with organic or aq. solns. or emulsions contg. hydrolysable sil(ox)anes. Ä(YO)3Si(CH2)xÜnEX (I) x = 1-12; n = 1-3, depending on E; Y = H, Na, K, Mg, Ca or Ba; E = cation or anion exchanging gp.; and X = H or alkali(ne earth) metal ion, or OH or an anion.

    14.
    发明专利
    未知

    公开(公告)号：DE19536366A1

    公开(公告)日：1997-04-03

    申请号：DE19536366

    申请日：1995-09-29

    Applicant: DEGUSSA

    Inventor： AUER EMMANUEL DR ,  WIELAND STEFAN DR ,  LANSINK-ROTGERINK HANS DR ,  JACOBSEN HAUKE DR ,  RIEDEMANN HEIKE

    IPC: C07C37/11 ,  C07C37/20 ,  C07C39/16 ,  C07C37/16

    Abstract: The prodn. of 2,2'-bis-(4-hydroxyphenyl)-propanes (BHPP) comprises reacting the corresp. phenols and carbonyl cpds. at 40-150 degrees C in presence of a formed acid catalyst consisting of a sulphonate gp.- and mercapto gp.-contg. organopolysiloxane (OFP) contg. units of formula (O3/2SiR'SO3)M(x+) (I) and O3/2SiR SH (III). In (I) and (III), R = 1-12C alkylene, 5-8C cycloalkylene or a gp. of formula -(CH2)n-Cyc-(CH2)m- or -(CH2)n-Phe-(CH2)m- (II) (with n, m = 0-6, i.e. the no. of Si- or S-linked CH2 gps.; Cyc = cyclohexylene; Phe = phenylene); M = H, opt. NH4, or a metal with a valency of x = 1-4; R = R . The free valencies of the O atoms attached to Si are taken up by the Si atoms of other gps. (I) and/or (II) and/or by the metal atom-oxygen gps. of crosslinking bridging gps. of formula SiO4/2 (IV) and opt. R''SiO3/2, R'SiO3/2, R'2SiO2/2, AlO3/2, R'AlO2/2, TiO4/2, R'TiO3/2 and R'2TiO2/2 (V). In (V) and (IV), R' = Me or Et; R" = Ph or 2-12C alkyl. The ratio of gps. (I):(III) = (10:1)-(1:10), the ratio of (I):(IV) = (1:3)-(1:20), and the ratio of (IV):(V) = (1:0)-(1:0.5). The required prod. is then isolated.

    16.
    发明专利
    未知

    公开(公告)号：ES2038962T3

    公开(公告)日：1994-11-16

    申请号：ES90114313

    申请日：1990-07-26

    Applicant: DEGUSSA

    Inventor： PANSTER PETER DR ,  WIELAND STEFAN DR

    IPC: B01D15/00 ,  B01J20/22 ,  B01J20/26 ,  C02F1/62 ,  C08G77/22 ,  C08G77/26 ,  C08G77/28 ,  C08G77/48 ,  C08G77/54 ,  C08G77/58 ,  C08J3/12

    Abstract: The invention relates to an organosiloxane copolycondensate comprising where R - R = in which R is C1-C10-alkylene, C5-C8-cycloalkylene or which is bonded directly to N or X, where X = NH-, N-CH3, N-C2H5, -S-, -S2-, -S3-, -S4-, P-C6H5, where R" is H or C1-C5-alkyl, which has optionally been crosslinked by means of Si-, Ti-, Zr- and/or Al-containing crosslinking agents, in the form of spherical particles having a diameter of from 0.01 to 3.0 mm, a specific surface area of from 0 to 1000 m /g, a specific pore volume of from 0 to 6.0 ml/g and a bulk density of from 50 to 1000 g/l. The invention furthermore relates to various preparation processes for the shaped copolycondensates, and to the use of certain compositions in each case for removing metals from solutions or for adsorption of gaseous organic compounds and/or steam.

    17.
    发明专利
    未知

    公开(公告)号：DE69002810D1

    公开(公告)日：1993-09-23

    申请号：DE69002810

    申请日：1990-07-27

    Applicant: DEGUSSA

    Inventor： PANSTER PETER DR ,  WIELAND STEFAN DR

    IPC: C08G77/28 ,  B01J20/22 ,  B01J20/26 ,  C02F1/62 ,  C02F5/00 ,  C02F5/08 ,  C02F5/10 ,  C08G77/22 ,  C08G77/26 ,  C08G77/48 ,  C08G77/54 ,  C08G77/58 ,  C08J3/12

    Abstract: Die Erfindung betrifft gegebenenfalls mittels Si-, Ti-, Zr- und/oder Al-haltigen Vernetzern vernetztes Organosiloxanamin-Copolykondensat aus Einheiten R = direkt an N bzw. an X gebundenes Alkylen mit C1-C10, Cycloalkylen mit C5-C8 oder X = -NH2, -NH-(CH2)2-NH2, -N(CH3)2, -N(C2H5)2 -NH-(CH2)2-NH-(CH2)2-NH2, -Cl, -Br, -J, -SH, -P(C6H5)2, wobei R sec = H oder Alkyl mit C1-C3, in Form kugelförmiger Teilchen mit einem Durchmesser von 0,01 bis 3,0 mm, einer spezifischen Oberfläche von 0 bis 1000 m /g, einem spezifischen Porenvolumen von 0 bis 6,0 ml/g sowie einer Schüttdichte von 50 bis 1000 g/l. Sie betrifft weiterhin diverse Herstellungsverfahren für die geformten Copolykondensate sowie eine Verwendung jeweils bestimmter Zusammensetzungen zur Entfernung von Metallen aus Lösungen bzw. zur Adsorption von gasförmigen organischen Verbindungen und/oder von Wasserdampf.

    18.
    发明专利
    未知

    公开(公告)号：AT93251T

    公开(公告)日：1993-09-15

    申请号：AT90114426

    申请日：1990-07-27

    Applicant: DEGUSSA

    Inventor： PANSTER PETER DR ,  WIELAND STEFAN DR

    IPC: C08G77/28 ,  B01J20/22 ,  B01J20/26 ,  C02F1/62 ,  C02F5/00 ,  C02F5/08 ,  C02F5/10 ,  C08G77/22 ,  C08G77/26 ,  C08G77/48 ,  C08G77/54 ,  C08G77/58 ,  C08J3/12

    Abstract: Die Erfindung betrifft gegebenenfalls mittels Si-, Ti-, Zr- und/oder Al-haltigen Vernetzern vernetztes Organosiloxanamin-Copolykondensat aus Einheiten R = direkt an N bzw. an X gebundenes Alkylen mit C1-C10, Cycloalkylen mit C5-C8 oder X = -NH2, -NH-(CH2)2-NH2, -N(CH3)2, -N(C2H5)2 -NH-(CH2)2-NH-(CH2)2-NH2, -Cl, -Br, -J, -SH, -P(C6H5)2, wobei R sec = H oder Alkyl mit C1-C3, in Form kugelförmiger Teilchen mit einem Durchmesser von 0,01 bis 3,0 mm, einer spezifischen Oberfläche von 0 bis 1000 m /g, einem spezifischen Porenvolumen von 0 bis 6,0 ml/g sowie einer Schüttdichte von 50 bis 1000 g/l. Sie betrifft weiterhin diverse Herstellungsverfahren für die geformten Copolykondensate sowie eine Verwendung jeweils bestimmter Zusammensetzungen zur Entfernung von Metallen aus Lösungen bzw. zur Adsorption von gasförmigen organischen Verbindungen und/oder von Wasserdampf.

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