公开(公告)号：DE59806910D1

公开(公告)日：2003-02-20

申请号：DE59806910

申请日：1998-07-01

Applicant: DEGUSSA

Inventor： GOEBEL DR ,  DESCHLER DR ,  MUENZENBERG DR ,  ZEZULKA GERD

IPC: C07F7/18 ,  C08L101/00

Abstract: Mixtures of bis(organosilyl)sulphanes (IA) and organosilyl thiocyanates (IB) of formula: (R R R SiR )xX (I) (Where: X = Sn; n = 2-20, especially 2-8 if x = 2; and X = SCN if x = 1 (thiocyanato-silane); (a) R , R , R = 1-8 carbon (C) alkyl and/or alkoxy or (b) at least one of R , R , R = alkoxy, the rest = H or monovalent aryl, especially phenyl, tolyl or benzyl; R = divalent 1-8, especially 2-4 C alkylidene or -(CH2)y-Phe-(CH2)y-; Phe = phenylene; y = 1-4.) Also claimed is a method of producing the mixtures.

公开(公告)号：ES2191226T3

公开(公告)日：2003-09-01

申请号：ES98112124

申请日：1998-07-01

Applicant: DEGUSSA

Inventor： GOBEL THOMAS DR ,  DESCHLER ULRICH DR ,  MUNZENBERG JORG DR ,  ZEZULKA GERD

IPC: C07F7/18 ,  C08L101/00

Abstract: Mixtures of bis(organosilyl)sulphanes (IA) and organosilyl thiocyanates (IB) of formula: (R R R SiR )xX (I) (Where: X = Sn; n = 2-20, especially 2-8 if x = 2; and X = SCN if x = 1 (thiocyanato-silane); (a) R , R , R = 1-8 carbon (C) alkyl and/or alkoxy or (b) at least one of R , R , R = alkoxy, the rest = H or monovalent aryl, especially phenyl, tolyl or benzyl; R = divalent 1-8, especially 2-4 C alkylidene or -(CH2)y-Phe-(CH2)y-; Phe = phenylene; y = 1-4.) Also claimed is a method of producing the mixtures.

公开(公告)号：AT231152T

公开(公告)日：2003-02-15

申请号：AT98112124

申请日：1998-07-01

Applicant: DEGUSSA

Inventor： GOEBEL THOMAS DR ,  DESCHLER ULRICH DR ,  MUENZENBERG JOERG DR ,  ZEZULKA GERD

IPC: C07F7/18 ,  C08L101/00

Abstract: Mixtures of bis(organosilyl)sulphanes (IA) and organosilyl thiocyanates (IB) of formula: (R R R SiR )xX (I) (Where: X = Sn; n = 2-20, especially 2-8 if x = 2; and X = SCN if x = 1 (thiocyanato-silane); (a) R , R , R = 1-8 carbon (C) alkyl and/or alkoxy or (b) at least one of R , R , R = alkoxy, the rest = H or monovalent aryl, especially phenyl, tolyl or benzyl; R = divalent 1-8, especially 2-4 C alkylidene or -(CH2)y-Phe-(CH2)y-; Phe = phenylene; y = 1-4.) Also claimed is a method of producing the mixtures.

公开(公告)号：AT228138T

公开(公告)日：2002-12-15

申请号：AT98112029

申请日：1998-06-30

Applicant: DEGUSSA

Inventor： MUENZENBERG JOERG DR ,  WILL WERNER ,  ZEZULKA GERD

IPC: C07F7/08 ,  C07F7/18

Abstract: Two-stage preparation of highly pure organosilicon disulfans of formula Z-Alk-S2-Alk-Z (I) comprises (1) dissolving or suspending sulfur (S) and an anhydrous sulfide of formula Me2S (II) in 1:(0.2-0.9) molar ratio and treating the solution or suspension with an organosilicon compound of formula Z-Alk-Hal (III), with a molar ratio of (III) to sulfur of (1.2-2):1; and (2) adding more (II) after reaction, in an amount approximately equimolar to the total amounts of (II) and S used for reaction, and isolating (I); in which Z = -Si(R )2R , -Si(R )(R )2 or -Si(R )3; R = 1-5C alkyl, 5-8C cycloalkyl, benzyl or a phenyl group optionally substituted by methyl (Me), ethyl (Et) or chlorine (Cl); R = 1-5C alkoxy, 5-8C cycloalkoxy, phenoxy or benzyloxy; Alk = a 1-10C divalent, saturated linear or branched hydrocarbon group or -CH2-Phe-CH2-; Phe = phenylene; Me = ammonium, an alkali metal or one equivalent of an alkaline earth metal or zinc; Hal = Cl or bromine (Br).

公开(公告)号：BR9802875A

公开(公告)日：2000-05-02

申请号：BR9802875

申请日：1998-08-07

Applicant: DEGUSSA

Inventor： MUENZENBERG JOERG DR ,  WILL WERNER ,  ZEZULKA GERD

IPC: C07F7/08 ,  C07F7/18

Abstract: Two-stage preparation of highly pure organosilicon disulfans of formula Z-Alk-S2-Alk-Z (I) comprises (1) dissolving or suspending sulfur (S) and an anhydrous sulfide of formula Me2S (II) in 1:(0.2-0.9) molar ratio and treating the solution or suspension with an organosilicon compound of formula Z-Alk-Hal (III), with a molar ratio of (III) to sulfur of (1.2-2):1; and (2) adding more (II) after reaction, in an amount approximately equimolar to the total amounts of (II) and S used for reaction, and isolating (I); in which Z = -Si(R )2R , -Si(R )(R )2 or -Si(R )3; R = 1-5C alkyl, 5-8C cycloalkyl, benzyl or a phenyl group optionally substituted by methyl (Me), ethyl (Et) or chlorine (Cl); R = 1-5C alkoxy, 5-8C cycloalkoxy, phenoxy or benzyloxy; Alk = a 1-10C divalent, saturated linear or branched hydrocarbon group or -CH2-Phe-CH2-; Phe = phenylene; Me = ammonium, an alkali metal or one equivalent of an alkaline earth metal or zinc; Hal = Cl or bromine (Br).

公开(公告)号：CS202090B2

公开(公告)日：1980-12-31

申请号：CS870977

申请日：1977-12-22

Applicant: DEGUSSA

Inventor： PLETKA HANS-DIETER ,  ZEZULKA GERD

IPC: C08K5/00 ,  C07F9/02 ,  C07F9/141 ,  C07F9/16 ,  C07F9/165 ,  C08K5/548 ,  C08L7/00 ,  C08L21/00

Abstract: There are prepared compounds of the formula [Rn1(R2O)3-n-Si-Alk-S-]xZ(I) where Z is 3BOND PO, 3BOND PS, 3BOND P, =PR, -P(R)2, -P(OR)2, =P(OR), -PO(OR)2, -PS(OR)2, =PO(OR) or =PS(OR) where R is an alkyl group of 1 to 5 carbon atoms, phenyl or o-, m- or p-nitrophenyl; Alk is an alkylene group with 2 to 4 carbon atoms; R1 is an alkyl group having 1 to 5 carbon atoms, benzyl or phenyl; R2 is an alkyl group having 1 to 5 carbon atoms, a cycloalkyl group having 5 to 8 carbon atoms, phenyl, benzyl or 2-methoxyethyl, each R1 and R2 can have the same or different meanings; n is 0, 1 or 2; and, x is 1, 2 or 3, being the residual valence of Z. The compounds are useful as reinforcing agents in vulcanizable rubber mixtures which contain a silicate filler and optionally carbon black.

公开(公告)号：DE2658368A1

公开(公告)日：1978-07-06

申请号：DE2658368

申请日：1976-12-23

Applicant: DEGUSSA

Inventor： PLETKA HANS-D DR ,  ZEZULKA GERD

IPC: C08K5/00 ,  C07F9/02 ,  C07F9/141 ,  C07F9/16 ,  C07F9/165 ,  C08K5/548 ,  C08L7/00 ,  C08L21/00 ,  C08K5/54

Abstract: There are prepared compounds of the formula [Rn1(R2O)3-n-Si-Alk-S-]xZ(I) where Z is 3BOND PO, 3BOND PS, 3BOND P, =PR, -P(R)2, -P(OR)2, =P(OR), -PO(OR)2, -PS(OR)2, =PO(OR) or =PS(OR) where R is an alkyl group of 1 to 5 carbon atoms, phenyl or o-, m- or p-nitrophenyl; Alk is an alkylene group with 2 to 4 carbon atoms; R1 is an alkyl group having 1 to 5 carbon atoms, benzyl or phenyl; R2 is an alkyl group having 1 to 5 carbon atoms, a cycloalkyl group having 5 to 8 carbon atoms, phenyl, benzyl or 2-methoxyethyl, each R1 and R2 can have the same or different meanings; n is 0, 1 or 2; and, x is 1, 2 or 3, being the residual valence of Z. The compounds are useful as reinforcing agents in vulcanizable rubber mixtures which contain a silicate filler and optionally carbon black.