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公开(公告)号:CA2891073C
公开(公告)日:2020-04-28
申请号:CA2891073
申请日:2012-11-12
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: GHOSH-DASTIDAR ABHIJIT , KAUJALGIKAR SAURABH , CHAUDHARY BHARAT I
IPC: C07D303/42 , C08K5/00 , C08K5/1515 , C08L27/06
Abstract: Epoxidized fatty acid alkyl esters and methods for making epoxidized fatty acid alkyl esters. Such epoxidized fatty acid alkyl esters can be prepared by epoxidizing fatty acid alkyl esters with an acid and a peroxide. Epoxidation can be performed under controlled reaction conditions to provide epoxidized fatty acid alkyl esters having an iodine value in the range of from 4 to 15 g I2 / 100 g of epoxidized fatty acid alkyl esters. Epoxidized fatty acid alkyl esters can be employed in plasticizer compositions, either alone or in combination with other plasticizers, such as epoxidized natural oils. Such plasticizers in turn may be used in the formation of polymeric compositions.
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12.
公开(公告)号:BR112015010689A2
公开(公告)日:2019-12-17
申请号:BR112015010689
申请日:2012-11-12
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: CHAUDHARY I BHARAT , GHOSH-DASTIDAR ABHIJIT , KAUJALGIKAR SAURABH , RAO NEETA
IPC: C07D301/12 , C07D303/42 , C08K5/1515
Abstract: resumo processo para produzir alquil ésteres de ácido graxo epoxidado, plastificante e composição polimérica métodos para preparar alquil ésteres de ácido graxo epoxidado. tais alquil ésteres de ácido graxo epoxidado podem ser preparados epoxidando-se um óleo natural com um ácido e um peróxido. o ácido residual no óleo natural epoxidado não é neutralizado, tal como com uma base, antes da esterificação para produzir os alquil ésteres de ácido graxo epoxidado. os alquil ésteres de ácido graxo epoxidado podem ser empregados em plastificantes, seja isoladamente ou em combinação com outros plastificantes, tais como óleos naturais epoxidados. tais plastificantes, por sua vez, podem ser usados na formação de composições poliméricas. 1/1
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公开(公告)号:MX365389B
公开(公告)日:2019-05-31
申请号:MX2015005985
申请日:2012-11-12
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: KAUJALGIKAR SAURABH , RAO NEETA , I CHAUDHARY BHARAT , GHOSH-DASTIDAR ABHIJIT
IPC: C08K5/1515 , C07D301/12 , C07D303/42
Abstract: Métodos para fabricar ésteres de alquilo de ácidos grasos epoxidados. Tales ésteres de alquilo de ácidos grasos epoxidados pueden prepararse por epoxidación de un aceite natural con un ácido y un peróxido. El ácido residual en el aceite natural epoxidado no se neutraliza, tal como con una base, antes de la esterificación para producir los ésteres de alquilo de ácidos grasos epoxidados. Los ésteres de alquilo de ácidos grasos epoxidados se pueden emplear en plastificantes, ya sea solo o en combinación con otros plastificantes, tales como aceites naturales epoxidados. Tales plastificantes a su vez pueden ser utilizados en la formación de composiciones poliméricas.
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公开(公告)号:CA3069289A1
公开(公告)日:2019-01-03
申请号:CA3069289
申请日:2018-06-06
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: CHAUDHARY BHARAT I , TALREJA MANISH , ZHANG YICHI , BAWISKAR SANTOSH S , DREUX PETER C , MUNDRA MANISH K , GHOSH-DASTIDAR ABHIJIT , PATEL RAJEN M , SEHANOBISH KALYAN , HEAH CHIEH YING , ONG KENNETH HIN-LEONG
Abstract: Articles made from a moisture-crosslinkable, polymeric composition comprising in weight percent based on the weight of the composition: (A) 10 to 99.99 wt% of a nonpolar ethylenic polymer grafted with silane functionality (Si-g-npPE), the npPE having the following properties before grafting: (1) a vinyl content of 0.2 to 0.7 per 1,000 carbon atoms, (2) a melt index of 1.5 to 7.0 dg/min, (3) a density of 0.913 to 0.965 g/cc, and (4) a molecular weight distribution (Mw/Mn) of equal to or less than 8; (B) 0.01 to 20 wt% of a silanol condensation catalyst; and (C) 0 to 70 wt% of a flame retardant additive; exhibit one or more of desirable (a) silane grafting efficiency; (b) hot creep performance as a cable jacket/insulation after moisture crosslinking; (c) retained dielectric strength after glancing impact as a moisture crosslinked cable construction; and (d) crush resistance as a moisture crosslinked cable construction.
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15.
公开(公告)号:MX2014003843A
公开(公告)日:2014-04-30
申请号:MX2014003843
申请日:2012-09-13
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: COGEN JEFFREY M , EATON ROBERT F , LAUFER CAROLINE H , FU LIN , GHOSH-DASTIDAR ABHIJIT , MUNDRA MANISH , CHAUDHARY BHARAT I
IPC: C08K5/00 , C07D303/42
Abstract: La presente descripción se dirige a un plastificante, composiciones poliméricas que contienen plastificante y conductores recubiertos con la composición polimérica. El plastificante incluye (i) un éster metílico de ácido graso epoxidado, (ii) un aceite natural epoxidado, y (iii) un éster de ftalato epoxidado. Las composiciones poliméricas que contienen la resma polimérica y el plastificante exhiben una pérdida de peso menor a 50 mg/cm2 después de exposición a una temperatura de 100°C durante siete días. Los conductores recubiertos con la composición polimérica (que contiene el plastificante) pasan la prueba de desenrollado a baja temperatura de UL719, y exhiben una pérdida de peso menor a 50 mg/cm2 después de exposición a una temperatura de 100°C durante siete días.
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公开(公告)号:CA2850326A1
公开(公告)日:2013-04-04
申请号:CA2850326
申请日:2012-09-14
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: MUNDRA MANISH K , DUNCHUS NEIL W , NEUBAUER ANTHONY C , LAUFER CAROLINE H , BISCOGLIO MICHAEL B , EATON ROBERT F , GHOSH-DASTIDAR ABHIJIT
IPC: C08L27/06 , B29C48/395 , C08J3/20 , C08K5/103
Abstract: Processes for making a polyvinyl chloride (PVC) dry blend composition with a phthalate-free, bio-based plasticizer and filler, having a bulk density of greater than 0.67 g/cc and an extrusion rate of greater than 65 gm/minute for a single screw extruder of 0.75 in barrel diameter with a 25: 1 L:D general purpose polyethylene screw at 75 rotations per minute screw speed, and compositions made by the processes are provided.
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公开(公告)号:CA2747898A1
公开(公告)日:2010-07-01
申请号:CA2747898
申请日:2009-12-04
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: SENGUPTA SAURAV S , GHOSH-DASTIDAR ABHIJIT , CHAUDHARY BHARAT I
Abstract: Ethylene-vinylsilane copolymers are moisture-cured under ambient conditions using a synergistic combination of at least one Lewis acid and at least one Brønsted acid or at least one Lewis base and at least one Brønsted base. Preferably the catalyst system comprises a Lewis acid, e.g., dibutyltin dilaurate, in combination with a Brønsted acid, e.g., sulfonic acid. The Lewis acid or base and the Brønsted acid or base is present in the catalyst system at a molar ratio of Lewis acid/base to Brønsted acid/base of 1:10 to 10:1.
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公开(公告)号:BR112017007918B1
公开(公告)日:2022-04-05
申请号:BR112017007918
申请日:2015-10-14
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: GHOSH-DASTIDAR ABHIJIT , MUNDRA MANISH
IPC: C07D301/12 , C07D303/42 , C08G59/02 , C08K5/00 , C08K5/1515 , C08L27/06 , C11C3/00
Abstract: a presente divulgação é dirigida a uma composição plastificante, composições poliméricas contendo a composição plastificante e condutores revestidos que compreendem a composição polimérica. a composição plastificante compreende um éster alquílico de ácido graxo epoxidado que tem um valor de cor apha menor que 100, um teor de triepóxido de pelo menos 6,5 por cento em peso e um teor em oxigênio de oxirano de pelo menos 5 gramas de oxirano por 100 gramas de éster alquílico de ácido graxo epoxidado.
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公开(公告)号:CA2850429C
公开(公告)日:2020-06-02
申请号:CA2850429
申请日:2012-09-13
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: LAUFER CAROLINE H , EATON ROBERT F , GHOSH-DASTIDAR ABHIJIT , MUNDRA MANISH , CHAUDHARY BHARAT I , COGEN JEFFREY M , FU LIN
IPC: C08K5/00 , C07D303/42
Abstract: The present disclosure is directed to a plasticizer, polymeric compositions containing the plasticizer, and conductors coated with the polymeric composition. The plasticizer includes (i) an epoxidized fatty acid methyl ester, (ii) an epoxidized natural oil, and (iii) an epoxidized tallate ester. Polymeric compositions containing a polymeric resin and the plasticizer exhibit a weight loss less than 50 mg/cm2 after exposure to 100°C for seven days. Conductors coated with the polymeric composition (containing the plasticizer) pass the low temperature unwind test of UL719 and exhibit a weight loss less than 50 mg/cm2 after exposure to 100°C for seven days.
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公开(公告)号:CA2861332C
公开(公告)日:2020-05-05
申请号:CA2861332
申请日:2013-01-28
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: MUNDRA MANISH , GHOSH-DASTIDAR ABHIJIT , EATON ROBERT F , FU LIN , CAMPBELL ROBERT M , BELL BRUCE M
IPC: C08K5/00 , C07D303/42
Abstract: The present disclosure is directed to a plasticizer composition, polymeric compositions containing the plasticizer composition, and conductors coated with the polymeric composition. The plasticizer composition includes a first plasticizer comprising epoxidized fatty acid alkyl esters and a second plasticizer comprising an epoxidized natural oil. The plasticizer composition, first plasticizer, and/or second plasticizer can undergo one or more color-reducing treatment processes, such as distillation, filtration, and/or peroxide treatment.
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