公开(公告)号：WO2008153688A2

公开(公告)日：2008-12-18

申请号：PCT/US2008/006446

申请日：2008-05-20

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： COLHOUN, Frederick, Leslie ,  STEWART, Mark, Edward ,  WEINHOLD, Stephen ,  PETERS, Richard, Dalton ,  MARTIN, Roger, Lee

CPC classification number: C08L67/02 ,  B29C51/002 ,  B29C51/10 ,  B29K2067/00 ,  B29K2995/0041 ,  C08J5/18 ,  C08J2367/02 ,  C08K3/04 ,  C08K3/36 ,  C08L23/06 ,  C08L23/08 ,  C08L77/00 ,  Y10T428/1397 ,  C08L2666/02 ,  C08L2666/04

Abstract: Polymer blends suitable for packaging are disclosed that include one or more impact modifiers; and one or more polyethylene terephthalate homopolymers or copolymers obtained by a melt phase polymerization using a catalyst system comprising aluminum atoms in an amount, for example, from about 3 ppm to about 60 ppm and one or more alkaline earth metal atoms, alkali metal atoms, or alkali compound residues in an amount, for example, from about 1 ppm to about 25 ppm, in each case based on the weight of the one or more polyethylene terephthalate homopolymers or copolymers The polymer blends disclosed exhibit improved low temperature toughness compared with blends made using polymers prepared with conventional catalyst systems.

Abstract translation: 公开了适用于包装的聚合物共混物，其包括一种或多种抗冲改性剂; 和一种或多种通过熔融相聚合获得的聚对苯二甲酸乙二醇酯均聚物或共聚物，其使用包含例如约3ppm至约60ppm的铝原子和一种或多种碱土金属原子的碱金属原子， 或碱化合物残基的量，例如约1ppm至约25ppm，基于一种或多种聚对苯二甲酸乙二醇酯均聚物或共聚物的重量。所公开的聚合物共混物与制备的共混物相比显示出改善的低温韧性 使用用常规催化剂体系制备的聚合物。

公开(公告)号：WO2008088533A1

公开(公告)日：2008-07-24

申请号：PCT/US2007/025323

申请日：2007-12-11

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： JENKINS, Jason, Christopher ,  MORROW, Rebekah, Fauver ,  STEWART, Mark, Edward

IPC: C08G63/54 ,  C08L67/00

CPC classification number: C08G63/547 ,  C08G63/553 ,  C08K5/0091 ,  C08K5/098 ,  C08L67/02

Abstract: Oxygen-scavenging polyester compositions are disclosed that include residues of one or more unsaturated diols having from 4 to 8 carbon atoms, in an amount from about 0.01 mole percent to about 10 mole percent, and residues of terephthalic acid in an amount of at least 50 mole percent, in each case based on the total amount of residues of dicarboxylic acids in the polyester composition comprising 100 mole percent. The polyester compositions typically have an intrinsic viscosity that is at least 0.65 dL/g.

Abstract translation: 公开了清除氧的聚酯组合物，其包含一种或多种具有4至8个碳原子的不饱和二醇的残基，其量为约0.01摩尔％至约10摩尔％，对苯二甲酸残基的量为至少50 在每种情况下，基于包含100摩尔％的聚酯组合物中的二羧酸残基的总量。 聚酯组合物通常具有至少0.65dL / g的特性粘度。

公开(公告)号：WO2006094165A1

公开(公告)日：2006-09-08

申请号：PCT/US2006/007531

申请日：2006-03-02

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： HALE, Wesley, Raymond ,  PECORINI, Thomas, Joseph ,  STEWART, Mark, Edward ,  ROGERS, Martin, Emerson ,  GILLIAM, Spencer, Allen ,  CLIFFTON, Michael, Duane

IPC: C08L67/02

CPC classification number: C08L69/00 ,  B32B27/08 ,  B32B27/18 ,  B32B27/34 ,  B32B27/36 ,  B32B27/365 ,  B32B2250/24 ,  B32B2264/105 ,  B32B2270/00 ,  B32B2307/412 ,  B32B2307/738 ,  B32B2307/74 ,  B32B2439/60 ,  C08K3/08 ,  C08L67/00 ,  C08L67/02 ,  C08L77/00 ,  C08L2205/02 ,  C08L2205/03 ,  Y10T428/13 ,  Y10T428/1334 ,  Y10T428/1352 ,  Y10T428/1355 ,  Y10T428/1359 ,  Y10T428/1379 ,  Y10T428/1383 ,  Y10T428/31725 ,  Y10T428/31736 ,  Y10T428/31739 ,  C08L2666/20 ,  C08L2666/14 ,  C08L2666/18

Abstract: Disclosed are oxygen-scavenging polymer compositions having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, a copolyamide or a transamidized, homogeneous blend of a least two polyamides, and a metal catalyst. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about -0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. The blends of the present invention are useful in producing shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties.

Abstract translation: 公开了具有高透明度和低雾度的除氧聚合物组合物，其包含选自聚酯，聚碳酸酯和聚芳酯的一种或多种热塑性聚合物的不混溶的共混物，至少两种聚酰胺的共聚酰胺或酰胺化的均匀共混物和金属催化剂。 不混溶共混物的组分具有约0.006至约-0.0006的折射率。 折射率的小差异使得能够将再研磨物掺入聚合物组合物中以产生透明成型制品。 本发明的共混物可用于生产成形制品，例如片材，薄膜，管，瓶，预型件和型材。 这些制品可以具有一层或多层，并且可以表现出改进的优异的阻隔性能和良好的熔融加工性，同时保持优异的机械性能。

公开(公告)号：WO2006063032A2

公开(公告)日：2006-06-15

申请号：PCT/US2005/044230

申请日：2005-12-05

Applicant: CONSTAR INTERNATIONAL INC. ,  EASTMAN CHEMICAL COMPANY ,  STEWART, Mark, Edward ,  ESTEP, Robert, Noah ,  GAMBLE, Benjamin ,  CLIFFTON, Michael, Duane ,  QUILLEN, Donna, Rice ,  BUEHRIG, Lavonna, Suzanne ,  GOVINDARAJAN, Venkat ,  DAUZVARDIS, Matthew, J.

Inventor： STEWART, Mark, Edward ,  ESTEP, Robert, Noah ,  GAMBLE, Benjamin ,  CLIFFTON, Michael, Duane ,  QUILLEN, Donna, Rice ,  BUEHRIG, Lavonna, Suzanne ,  GOVINDARAJAN, Venkat ,  DAUZVARDIS, Matthew, J.

IPC: C08K3/08

CPC classification number: C08K3/08 ,  B29B2911/1402 ,  B29B2911/14026 ,  B29B2911/14033 ,  B29B2911/1404 ,  B29B2911/14106 ,  B29B2911/14113 ,  B29B2911/1412 ,  B29B2911/14126 ,  B29B2911/14133 ,  B29B2911/1414 ,  B29B2911/14146 ,  B29B2911/14153 ,  B29B2911/1416 ,  B29B2911/14166 ,  B29B2911/14173 ,  B29B2911/1418 ,  C08K2003/0843 ,  C08K2003/0893 ,  C08L67/00

Abstract: The present invention concerns a method for forming an article by combining a polyester polymer and an oxygen scavenging composition comprising a polyamide in the presence of zinc and a cobalt in a melt processing zone to form a melt; and forming an article such as a sheet or preform from the melt. Also provided are molten formulated polyester polymer compositions containing a blend of a polyethylene terephthalate polymer and a polyamide polymer along with zinc and cobalt. Articles made from the composition are resistant to the transmission of oxygen, possess short induction periods, and have high capacity for sustaining lengthy periods of low oxygen transmission through the wall of the article.

Abstract translation: 本发明涉及通过在熔融加工区中将含有聚酰胺的聚酯聚合物和含氧清除组合物在锌和钴的存在下组合以形成熔体而形成制品的方法; 以及从所述熔体形成诸如片材或预成型件的制品。 还提供了含有聚对苯二甲酸乙二醇酯聚合物和聚酰胺聚合物以及锌和钴的共混物的熔融配制的聚酯聚合物组合物。 由该组合物制成的制品对氧气的传播具有抗性，具有短的诱导期，并且具有高的容量以维持通过制品壁的低氧传递的长时间段。

公开(公告)号：WO2007001574A1

公开(公告)日：2007-01-04

申请号：PCT/US2006/012074

申请日：2006-03-30

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： HALE, Wesley, Raymond ,  PECORINI, Thomas, Joseph ,  STEWART, Mark, Edward ,  ROGERS, Martin, Emerson ,  GILLIAM, Spencer, Allen ,  CLIFFTON, Michael, Duane ,  CRAWFORD, Emmett, Dudley ,  PORTER, David, Scott ,  CONNELL, Gary, Wayne

IPC: C08L67/02 ,  C08L77/06

CPC classification number: B32B27/34 ,  B29B17/0042 ,  B29B2911/14906 ,  B29K2067/00 ,  B32B27/08 ,  B32B27/18 ,  B32B27/36 ,  B32B2250/24 ,  B32B2264/105 ,  B32B2307/412 ,  B32B2307/716 ,  B32B2307/7244 ,  B32B2307/7246 ,  B32B2553/00 ,  C08G63/199 ,  C08L67/02 ,  C08L77/00 ,  C08L2205/02 ,  Y02W30/62 ,  C08L2666/20

Abstract: Disclosed is a process for the preparation of shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles, having high transparency and low haze, and comprising immiscible blends of at least one polyester comprising 2,2,4,4-tetramethyl-l ,3-cyclobutanediol, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend have refractive indices which differ by about 0.006 to about -0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce shaped articles having oxygen-scavenging properties.

Abstract translation: 公开了一种制备成形制品的方法，例如片状，薄膜，管，瓶，预成型件和型材，具有高透明度和低雾度，并且包括至少一种聚酯的不混溶共混物，包括2,2,4 ，4-四甲基-1,3-环丁二醇，以及共聚酰胺或至少两种聚酰胺的酰胺化均匀共混物。 不混溶共混物的组分具有约0.006至约-0.0006的折射率。 折射率的小差异使得能够将再研磨物掺入聚合物组合物中以产生透明成型制品。 这些制品可以具有一层或多层，并且可以表现出改进的优异的阻隔性能和良好的熔融加工性，同时保持优异的机械性能。 可以将金属催化剂引入到组合物中以产生具有除氧性能的成形制品。

公开(公告)号：WO2007001561A1

公开(公告)日：2007-01-04

申请号：PCT/US2006/011928

申请日：2006-03-30

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： HALE, Wesley, Raymond ,  PECORINI, Thomas, Joseph ,  STEWART, Mark, Edward ,  ROGERS, Martin, Emerson ,  GILLIAM, Spencer, Allen ,  CLIFFTON, Michael, Duane ,  CRAWFORD, Emmett, Dudley ,  PORTER, David, Scott ,  CONNELL, Gary, Wayne

IPC: B23B27/00 ,  C08L67/02 ,  C08L77/06

CPC classification number: B32B27/34 ,  B29B17/0042 ,  B29B2911/14906 ,  B29K2067/00 ,  B32B27/08 ,  B32B27/18 ,  B32B27/36 ,  B32B2250/24 ,  B32B2264/105 ,  B32B2307/412 ,  B32B2307/716 ,  B32B2307/7244 ,  B32B2307/7246 ,  B32B2553/00 ,  C08G63/199 ,  C08L67/02 ,  C08L77/00 ,  C08L2205/02 ,  Y02W30/62 ,  C08L2666/20

Abstract: Disclosed is a process for the preparation of multi layered, shaped articles having high transparency and low haze and in which at least one layer contains at least one polyester comprising 2,2,4,4-tetramethyl-1 ,3-cyclobutanediol and a separate layer which contains a transamidized, homogeneous blend of a least two polyamides. The polyester component and the polyamide component have refractive indices which differ by about 0.006 to about -0.0006. The small difference in the refractive indices enable the incorporation of regrind into one or more of the layers of the article while maintaining high clarity. These articles can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into one or more layers to impart oxygen-scavenging properties.

Abstract translation: 公开了一种制备具有高透明度和低雾度的多层成型制品的方法，其中至少一层含有至少一种包含2,2,4,4-四甲基-1,3-环丁二醇的聚酯和单独的 其包含至少两种聚酰胺的酰胺化均匀共混物。 聚酯组分和聚酰胺组分的折射率相差约0.006至约-0.0006。 折射率的小差异使得可以将再研磨物掺入制品的一层或多层中同时保持高透明度。 这些制品在保持优异的机械性能的同时可显示出优异的阻隔性能和良好的熔融加工性。 可以将金属催化剂并入一个或多个层中以赋予氧气清除性能。

公开(公告)号：WO2006062749A2

公开(公告)日：2006-06-15

申请号：PCT/US2005/042677

申请日：2005-11-28

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： STAFFORD, Steven, Lee ,  STEWART, Mark, Edward ,  GAMBLE, Benjamin, Bradford

IPC: C08K3/08

CPC classification number: B65D81/266 ,  B29B2911/1402 ,  B29B2911/14026 ,  B29B2911/14033 ,  B29B2911/1404 ,  B29B2911/14106 ,  B29B2911/14133 ,  B29C49/0005 ,  B29C49/04 ,  B29C49/06 ,  B29C51/002 ,  B29K2067/00 ,  B29K2077/00 ,  B29K2995/0067 ,  B60C1/0008 ,  C08K5/098 ,  C08K2201/008 ,  C08L67/02 ,  C08L77/06 ,  Y10T428/1352 ,  C08L77/00 ,  C08L2666/20

Abstract: This invention relates to a polyester/polyamide blend having an excellent gas barrier property. More particularly, the present invention relates to combinations of a polyethylene terephthalate polymer and a polyamide polymer having an excellent gas barrier property and short oxygen scavenging induction periods, where the polyamide polymer has a C:A terminal group concentration ratio of 2:1 or more and a C + A terminal group concentration of at least 0.17 meq/g of polyamide polymer, wherein C represents a cumulative total of a terminal carboxyl group concentration and a terminal hydrocarbyl group concentration expressed in meq/g of polyamide, and A represents a terminal amine group concentration expressed in meq/g of polyamide.

Abstract translation: 本发明涉及具有优异气体阻隔性的聚酯/聚酰胺共混物。 更具体地说，本发明涉及具有优异的阻气性和短的除氧诱导期的聚对苯二甲酸乙二醇酯聚合物和聚酰胺聚合物的组合，其中聚酰胺聚合物具有2:1或更大的C：A端基浓度比 且C + A端基浓度为至少0.17meq / g聚酰胺聚合物，其中C表示以meq / g聚酰胺表示的末端羧基浓度和末端烃基浓度的累计总和，并且A表示末端羧基浓度 胺基浓度以meq / g聚酰胺表示。

公开(公告)号：EP1824920B9

公开(公告)日：2010-08-04

申请号：EP05852745.8

申请日：2005-12-02

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： STEWART, Mark, Edward ,  SHARPE, Emerson, Eston, Jr. ,  GAMBLE, Benjamin, Bradford ,  STAFFORD, Steven, Lee ,  ESTEP, Robert, Noah ,  WILLIAMS, James, Carl ,  CLARK, Thomas, Roger

IPC: C08K5/09 ,  C08G63/60 ,  C08F283/04 ,  C08G69/48 ,  C08L67/02

CPC classification number: C08K5/098 ,  C08L67/02 ,  C08L77/00 ,  Y10T428/1352 ,  Y10T428/1383 ,  C08L2666/14

Abstract: A solid concentrate is provided having a combination of a transition metal present in an amount ranging from 1000 to 40,000 ppm (weight by metal) and a polyester polymer present in an amount of at least 40 wt.% based on the weight of the concentrate. Concentrates made with highly modified polyester polymers are easy to compound with transition metals forming less brittle polymer upon melt extrusion. Bottle preforms and oxygen scavenging bottles can be made from these concentrates by combining solid polyester particles, solid polyamide particles, and solid these concentrate particles c into an melt processing zone, forming a melt, and forming an article directly from the melt. The b* color and the L* color and the haze levels of the preforms are improved over the preforms made with liquid carriers instead of solid concentrates. The particles are also advantageously simultaneously dried in a drying zone under conditions effective to at least partially remove moisture from the blend to thereby further improve the b* color and L* color.

公开(公告)号：EP2125929A1

公开(公告)日：2009-12-02

申请号：EP07867709.3

申请日：2007-12-11

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： JENKINS, Jason, Christopher ,  MORROW, Rebekah, Fauver ,  STEWART, Mark, Edward

IPC: C08G63/00

CPC classification number: C08G63/54 ,  C08G63/676 ,  C08G63/826

Abstract: Oxygen-scavenging polyester compositions are disclosed that comprise one or more polyesters having incorporated therein residues of 3-hexenedioic acid and terephthalic acid. The compositions may further comprise residues of one or more aliphatic dicarboxylic acids such as adipic acid. One or more of the polyesters of the compositions may comprise significant amounts of repeating units of polyethylene terephthalate as homopolymers or copolymers, making them suitable for us in packaging compositions having oxygen-scavenging properties.

公开(公告)号：EP1901871B1

公开(公告)日：2008-11-12

申请号：EP06749031.8

申请日：2006-03-30

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： HALE, Wesley, Raymond ,  PECORINI, Thomas, Joseph ,  STEWART, Mark, Edward ,  ROGERS, Martin, Emerson ,  GILLIAM, Spencer, Allen ,  CLIFFTON, Michael, Duane ,  CRAWFORD, Emmett, Dudley ,  PORTER, David, Scott ,  CONNELL, Gary, Wayne

IPC: B23B27/00 ,  C08L67/02 ,  C08L77/06

CPC classification number: B32B27/34 ,  B29B17/0042 ,  B29B2911/14906 ,  B29K2067/00 ,  B32B27/08 ,  B32B27/18 ,  B32B27/36 ,  B32B2250/24 ,  B32B2264/105 ,  B32B2307/412 ,  B32B2307/716 ,  B32B2307/7244 ,  B32B2307/7246 ,  B32B2553/00 ,  C08G63/199 ,  C08L67/02 ,  C08L77/00 ,  C08L2205/02 ,  Y02W30/62 ,  C08L2666/20

Abstract: Disclosed is a process for the preparation of multi layered, shaped articles having high transparency and low haze and in which at least one layer contains at least one polyester comprising 2,2,4,4-tetramethyl-1 ,3-cyclobutanediol and a separate layer which contains a transamidized, homogeneous blend of a least two polyamides. The polyester component and the polyamide component have refractive indices which differ by about 0.006 to about -0.0006. The small difference in the refractive indices enable the incorporation of regrind into one or more of the layers of the article while maintaining high clarity. These articles can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into one or more layers to impart oxygen-scavenging properties.