OXYGEN-SCAVENGING POLYESTER COMPOSITIONS USEFUL FOR PACKAGING
    3.
    发明申请
    OXYGEN-SCAVENGING POLYESTER COMPOSITIONS USEFUL FOR PACKAGING 审中-公开
    用于包装的OXYGEN-SCAVENGING POLYESTER组合物

    公开(公告)号:WO2008088533A1

    公开(公告)日:2008-07-24

    申请号:PCT/US2007/025323

    申请日:2007-12-11

    CPC classification number: C08G63/547 C08G63/553 C08K5/0091 C08K5/098 C08L67/02

    Abstract: Oxygen-scavenging polyester compositions are disclosed that include residues of one or more unsaturated diols having from 4 to 8 carbon atoms, in an amount from about 0.01 mole percent to about 10 mole percent, and residues of terephthalic acid in an amount of at least 50 mole percent, in each case based on the total amount of residues of dicarboxylic acids in the polyester composition comprising 100 mole percent. The polyester compositions typically have an intrinsic viscosity that is at least 0.65 dL/g.

    Abstract translation: 公开了清除氧的聚酯组合物,其包含一种或多种具有4至8个碳原子的不饱和二醇的残基,其量为约0.01摩尔%至约10摩尔%,对苯二甲酸残基的量为至少50 在每种情况下,基于包含100摩尔%的聚酯组合物中的二羧酸残基的总量。 聚酯组合物通常具有至少0.65dL / g的特性粘度。

    OXYGEN-SCAVENGING POLYMER BLENDS SUITABLE FOR USE IN PACKAGING
    5.
    发明申请
    OXYGEN-SCAVENGING POLYMER BLENDS SUITABLE FOR USE IN PACKAGING 审中-公开
    OXYGEN-SCAVENGING聚合物混合物适用于包装

    公开(公告)号:WO2008127542A1

    公开(公告)日:2008-10-23

    申请号:PCT/US2008/003998

    申请日:2008-03-27

    CPC classification number: C08L67/02 C08G63/84 C08K5/098 C08L77/06 C08L2666/20

    Abstract: Polymer blends suitable for packaging are disclosed that include a transition metal; one or more polyamide homopolymers or copolymers; and one or more polyethylene terephthalate homopolymers or copolymers obtained by a melt phase polymerization using a catalyst system comprising aluminum atoms in an amount, for example, from about 3 ppm to about 60 ppm and one or more alkaline earth metal atoms, alkali metal atoms, or alkali compound residues in an amount, for example, from about 1 ppm to about 25 ppm, in each case based on the weight of the one or more polyethylene terephthalate homopolymers or copolymers. The polymer blends disclosed exhibit improved oxygen-scavenging activity compared with blends made using polymers prepared with conventional catalyst systems.

    Abstract translation: 公开了适用于包装的聚合物共混物,其包括过渡金属; 一种或多种聚酰胺均聚物或共聚物; 和一种或多种通过熔融相聚合获得的聚对苯二甲酸乙二醇酯均聚物或共聚物,其使用包含例如约3ppm至约60ppm的铝原子和一种或多种碱土金属原子的碱金属原子的催化剂体系, 或碱金属化合物残基,其量例如为约1ppm至约25ppm,基于一种或多种聚对苯二甲酸乙二醇酯均聚物或共聚物的重量。 与使用用常规催化剂体系制备的聚合物制备的共混物相比,所公开的聚合物共混物显示出改进的除氧活性。

    POLYESTER MELT-PHASE COMPOSITIONS HAVING IMPROVED THERMO-OXIDATIVE STABILITY, AND METHODS OF MAKING AND USING THEM
    7.
    发明申请
    POLYESTER MELT-PHASE COMPOSITIONS HAVING IMPROVED THERMO-OXIDATIVE STABILITY, AND METHODS OF MAKING AND USING THEM 审中-公开
    具有改善的热氧化稳定性的聚酯熔融相组合物及其制备和使用方法

    公开(公告)号:WO2010033162A1

    公开(公告)日:2010-03-25

    申请号:PCT/US2009/005045

    申请日:2009-09-08

    CPC classification number: C08G63/187 C08G63/85

    Abstract: Polyester compositions are disclosed that include a melt-phase polyethylene terephthalate polyester having incorporated therein residues of a monomer having two or more fused aromatic rings, and that also include titanium. Also disclosed are articles that include the disclosed polyester compositions, and processes for producing such polyester compositions, that include the steps of forming a mixture comprising ethylene glycol, at least one acid chosen from terephthalic acid and derivatives of terephthalic acid, and a monomer having two or more fused aromatic rings; and reacting the mixture in the presence of titanium to obtain the melt-phase polyethylene terephthalate polyester.

    Abstract translation: 公开了聚酯组合物,其包括熔融相聚对苯二甲酸乙二醇酯聚酯,其中掺入具有两个或更多个稠合芳环的单体的残基,并且还包括钛。 还公开了包括所公开的聚酯组合物的制品,以及制备这种聚酯组合物的方法,其包括形成包含乙二醇,至少一种选自对苯二甲酸和对苯二甲酸衍生物的酸的混合物和具有两个 或更多稠合芳环; 并在钛的存在下使该混合物反应,得到熔融相聚对苯二甲酸乙二醇酯聚酯。

    POLYESTER MELT-PHASE COMPOSITIONS HAVING IMPROVED THERMO-OXIDATIVE STABILITY, AND METHODS OF MAKING AND USING THEM
    8.
    发明申请
    POLYESTER MELT-PHASE COMPOSITIONS HAVING IMPROVED THERMO-OXIDATIVE STABILITY, AND METHODS OF MAKING AND USING THEM 审中-公开
    具有改善的热氧化稳定性的聚酯熔融相组合物及其制备和使用方法

    公开(公告)号:WO2010033161A2

    公开(公告)日:2010-03-25

    申请号:PCT/US2009/005044

    申请日:2009-09-08

    CPC classification number: C08G63/187 C08G63/189 C08G63/83 C08G63/84

    Abstract: Polyester compositions are disclosed that include a melt-phase polyethylene terephthalate polyester having incorporated therein residues of a monomer having two or more fused aromatic rings, and that also include aluminum, and optionally an alkali metal or an alkaline earth metal. Also disclosed are articles that include the disclosed polyester compositions, and processes for producing such polyester compositions, that include the steps of forming a mixture comprising ethylene glycol, at least one acid chosen from terephthalic acid and derivatives of terephthalic acid, and a monomer having two or more fused aromatic rings; and reacting the mixture in the presence of aluminum, and optionally an alkali metal or an alkaline earth metal, to obtain the melt-phase polyethylene terephthalate polyester.

    Abstract translation: 公开了包含熔融相聚对苯二甲酸乙二醇酯聚酯的聚酯组合物,所述聚对苯二甲酸乙二醇酯聚酯具有并入其中的具有两个或更多个稠合芳环的单体的残基,并且还包括铝和任选的碱金属或碱金属 土金属。 还公开了包括所公开的聚酯组合物的制品以及制备这种聚酯组合物的方法,所述方法包括以下步骤:形成包含乙二醇,选自对苯二甲酸和对苯二甲酸衍生物的至少一种酸和具有两个 或更多稠合芳环; 并在铝和任选的碱金属或碱土金属的存在下使混合物反应以获得熔融相聚对苯二甲酸乙二醇酯聚酯。

    POLYESTER MELT PHASE PRODUCTS AND PROCESS FOR MAKING THE SAME
    9.
    发明申请
    POLYESTER MELT PHASE PRODUCTS AND PROCESS FOR MAKING THE SAME 审中-公开
    聚酯熔融相制品及其制备方法

    公开(公告)号:WO2009094102A1

    公开(公告)日:2009-07-30

    申请号:PCT/US2009/000103

    申请日:2009-01-08

    CPC classification number: C08G63/84 C08K5/13 Y10T428/1352 C08L67/02

    Abstract: Articles comprising at least one polyester polymer melt phase product comprising at least one polyethylene terephthalate polyester; at least one metal compound chosen from alkali metal-aluminum compounds; and from 5 ppm to 1000 ppm of at least one phenolic stabilizer. Also provided is a melt phase process for making a polyester polymer melt phase product comprising: forming a slurry comprising at least one glycol chosen from ethylene glycol and derivatives of ethylene glycol and at least one acid chosen from terephthalic acid and derivatives of terephthalic acid; adding 5 ppm to 1000 ppm of at least one phenolic stabilizer; and reacting said at least one glycol and said at least one acid in the presence of at least one catalyst chosen from alkali metal- aluminum catalysts.

    Abstract translation: 包含至少一种包含至少一种聚对苯二甲酸乙二醇酯聚酯的聚酯聚合物熔融相产品的制品; 至少一种选自碱金属 - 铝化合物的金属化合物; 和5ppm至1000ppm的至少一种酚类稳定剂。 还提供了一种用于制备聚酯聚合物熔体相产物的熔融相方法,包括:形成包含至少一种选自乙二醇和乙二醇衍生物的至少一种二醇和至少一种选自对苯二甲酸和对苯二甲酸衍生物的酸的浆料; 加入5ppm至1000ppm的至少一种酚类稳定剂; 并在至少一种选自碱金属 - 铝催化剂的催化剂的存在下使所述至少一种二醇和所述至少一种酸反应。

    NON-PRECIPITATING ALKALI/ALKALINE EARTH METAL AND ALUMINUM SOLUTIONS MADE WITH DIOLS HAVING AT LEAST TWO PRIMARY HYDROXYL GROUPS
    10.
    发明申请
    NON-PRECIPITATING ALKALI/ALKALINE EARTH METAL AND ALUMINUM SOLUTIONS MADE WITH DIOLS HAVING AT LEAST TWO PRIMARY HYDROXYL GROUPS 审中-公开
    不含碱性碱金属/碱性金属和铝溶液与具有至少两个主要羟基基团的二醇

    公开(公告)号:WO2008073209A2

    公开(公告)日:2008-06-19

    申请号:PCT/US2007/024080

    申请日:2007-11-16

    Abstract: A stable catalyst solution suitable for catalyzing the polycondensation of reactants to make polyester polymers comprising: (i) M, wherein M is represented by an alkaline earth metal or alkali metal and (ii) aluminum metal and (iii) a polyhydroxyl solvent having at least 3 carbon atoms and at least two primary hydroxyl groups, the longest carbon chain being a hydrocarbon; such as 1,3-propane diol, 1,4-butane diol, 1,5-pentane diol, or combinations thereof., wherein the molar ratio of M:AI ranges from 0.75:1 to less than 1.5:1. The catalyst solution is desirably a solution which does not precipitate upon standing over a period of at least one week at room temperature (25°C-40°C), even at molar ratios of M:AI approaching 1 :1. There is also provided a method for the manufacture of the solution, its feed to and use in the manufacture of a polyester polymer, and polyester polymers obtained by combining certain ingredients or containing the residues of these ingredients in the composition.

    Abstract translation: 一种稳定的催化剂溶液,其适用于催化反应物的缩聚以制备聚酯聚合物,所述聚酯聚合物包含:(i)M,其中M由碱土金属或碱金属代表,和(ii)铝金属和(iii)多羟基溶剂至少具有 3个碳原子和至少两个伯羟基,最长的碳链是烃; 例如1,3-丙二醇,1,4-丁二醇,1,5-戊二醇或其组合,其中M:Al的摩尔比范围为0.75:1至小于1.5:1。 催化剂溶液理想地是在室温(25℃-40℃)下至少一周的时间内不沉淀的溶液,即使接近1:1的M:AA的摩尔比也是如此。 还提供了一种用于制造溶液,其用于制造聚酯聚合物的进料和通过组合某些成分或将组合物中的这些成分的残余物组合而获得的聚酯聚合物的方法。

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