6-(bifenil-éster)-3h-nafto[2,1-b]piranos como corantes dicróicos fotocrômicos e artigo óptico contendo os mesmos

    公开(公告)号:BRPI0716514B1

    公开(公告)日:2022-06-14

    申请号:BRPI0716514

    申请日:2007-09-05

    Abstract: 6-(bifenil-ester)-3h-nafto[2,1-bjpiranos como corantes dicróicos fotocrômicos e artigo óptico contendo os mesmos. um composto de naftopirano representado pela fórmula (1): em que: n1, n2, p, m e q representam um número inteiro; r1, r2, e r4, representam um grupo selecionado de halogênio, -ra, -oh, -ora, -sh, -sra, -nh2, -nrara1, -nrbrc, -cora, -cora, -oc (o)-ry, -x-(re)-y, grupo perfluoroalquila (c,-c+e) linear ou ramificado, em que ra, ra1, rb, rc, x, y, re, e rg são conforme definidos na descrição; z representa um grupo selecionado de co, cs, so, so2, co2, c(o)s, cs2, c(o)nh, c(o)nra, c(s)nh, c(s)nra, e c=nra; r3; representa um grupo selecionado de halogênio, -ra, grupo perfluoroalquila (c;-18) linear ou ramificado -oh, -ora, -sh, -sra, -nh2, e -nrara1; r6 representa um grupo selecionado de -ra que pode ser opcionalmente substituído, perfluoroalquila (c1-18) linear ou ramificado, cicloalquila, heterocicloalquila, arila, e heteroarila, que podem ser opcionalmente substituídos; r5 representa um grupo selecionado de: halogênio, -ra, grupo perfluoroalquila (c1-18) linear ou ramificado, -oh, -ora, -sh, -sra, -nha, -nrara1, -co-ra, -o-c(o)-ra, e -co-c(0)ra;ou quando q é igual a 2, então dois rs juntos representam ainda um grupo -o(ch2)-o- em que q1 representa um número inteiro compreendido de 1 a 3 inclusivos.

    realização de um composto ótico transparente com estrutura celular

    公开(公告)号:BR112012029580A2

    公开(公告)日:2016-08-02

    申请号:BR112012029580

    申请日:2011-05-16

    Abstract: realização de um composto ótico transparente com estrutura celular. a presente invenção refere-se um componente ótico transparente com estrutura celular que compreende uma rede de paredes (106) que forma um conjunto de células (104) justapostas paralelamente a uma superfície do componente. para realizar esse componente, determina-se inicialmente um conjunto irregular de pontos (101, 105) na superfície do componente, cada ponto sendo destinado a formar um centro de uma das células. em seguida, determina-se uma posição e uma orientação de cada parede, de modo que o conjunto das células forme uma divisão de voronoï da superfície do componente. o componente apresenta então um nível de transparência que é compatível com uma utilização ótica ou oftálmica.

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    公开(公告)号:IN4981DEN2012A

    公开(公告)日:2015-10-02

    申请号:IN4981DEN2012

    申请日:2012-06-06

    Applicant: ESSILOR INT

    Abstract: The invention relates to a photochromic optical article with reduced thermal dependency, comprising: (a) a transparent substrate, (b) a saturated photochromic layer having, in the activated state and at a temperature of 20°C, a relative transmission factor of less than 1% in the visible range, and (c) an anti-UV coating of plastic material at least partially covering the saturated photochromic layer, the said anti-UV coating containing at least one agent which absorbs UV radiation (anti-UV agent) and is distributed in a pattern consisting of a multitude of points, each having a surface area of less than 0.15 mm 2, the average distance between two neighbouring points lying between 0.5 and 2 mm and the ratio of the overall surface area of all ethe points to the total surface area of the anti-UV coating being such that the relative transmission factor of the optical article in the visible range in the activated state and at 20°C is at least equal to 5%. The invention also relates to two methods for manufacturing such an optical article.

    Photochromic optical article comprising a saturated photochromic coating and a film absorbing UV radiation

    公开(公告)号:AU2010333253B2

    公开(公告)日:2015-02-19

    申请号:AU2010333253

    申请日:2010-10-07

    Applicant: ESSILOR INT

    Abstract: The invention relates to a photochromic optical article with reduced thermal dependency, comprising: (a) a transparent substrate, (b) a saturated photochromic layer having, in the activated state and at a temperature of 20°C, a relative transmission factor of less than 1% in the visible range, and (c) an anti-UV coating of plastic material at least partially covering the saturated photochromic layer, the said anti-UV coating containing at least one agent which absorbs UV radiation (anti-UV agent) and is distributed in a pattern consisting of a multitude of points, each having a surface area of less than 0.15 mm 2, the average distance between two neighbouring points lying between 0.5 and 2 mm and the ratio of the overall surface area of all the points to the total surface area of the anti-UV coating being such that the relative transmission factor of the optical article in the visible range in the activated state and at 20°C is at least equal to 5%. The invention also relates to two methods for manufacturing such an optical article.

    Transparent electrochromic system with a plurality of pairs of supply electrodes

    公开(公告)号:AU2010299703B2

    公开(公告)日:2015-01-22

    申请号:AU2010299703

    申请日:2010-09-24

    Applicant: ESSILOR INT

    Abstract: The invention relates to a transparent electrochromic system (100) which includes two pairs of transparent supply electrodes (1-4), which are intended for being electrically connected to variable power sources (20, 21). The electrodes of the two pairs are supported by separate outer walls (10, 11) of the system, on either side of a closed volume which contains electroactive substances. The electrochromic system has superior dynamics and switching rate. Various embodiments of the invention correspond to various modes for connecting the electrodes to the power sources, and to various partitions of the closed volume into separate cells (13).

    ПРОЗРАЧНАЯ ЭЛЕКТРОХРОМНАЯ СИСТЕМА

    公开(公告)号:EA020357B1

    公开(公告)日:2014-10-30

    申请号:EA201200194

    申请日:2010-07-19

    Applicant: ESSILOR INT

    Abstract: Изобретениеотноситсяк прозрачнойэлектрохромнойсистеме (100), содержащейячеистуюструктуру (13), дваэлектрода (1, 2) питания, выполненныхнаоднойстенке (10), ипоменьшеймереодиндополнительныйэлектрод (3). Указанныйдополнительныйэлектродможноиспользоватьв качествеконтрольногоэлектродаилиэлектродаполяризации. Онможеттакжеобразоватьконденсаторс четвертымэлектродом, которыйдобавляютв системудляконтролязаперемещениемнекоторыхэлектроактивныхвеществ, отвечающихзаокрашиваниеи обесцвечиваниесистемы. Засчетэтогоулучшаютработусистемы.

    Transparent electrochromic system
    17.
    发明专利

    公开(公告)号:NZ597805A

    公开(公告)日:2014-02-28

    申请号:NZ59780510

    申请日:2010-07-19

    Applicant: ESSILOR INT

    Abstract: A transparent electrochromic system (100) for allowing clear vision across the system is claimed. The system comprises two parallel outer walls (10, 11) and a network of internal walls (12) placed between the two outer walls. The system is transparent for a viewing direction across the outer walls between two opposite sides. The internal walls extend perpendicularly to the outer walls and define a set of cells (13) juxtaposed in parallel to the outer Walls. Portions of liquid and/or gel are contained respectively in the cells (13) and first and second electroactive substances are distributed in the· portions of liquid and/or gel, with respective electrical redox potentials that are different. At least some of the first and second electro active substances have a variable optical effect between an oxidized form and a reduced form of the substances. The system further comprises two transparent power supply electrodes (1, 2) carried together by a single one (10) of the two outer walls, and intended to be connected respectively to two power supply terminals of a variable electrical power supply unit(20, 21). Each of the power supply electrodes is in direct electrical contact with the portions of liquid and/or gel contained in at least some of the cells (13) for transferring electrons to or from at least some of the electroactive substances, in an inverse way between the first and second electroactive substances at a given time. The system further comprises at least one additional transparent electrode (3) without direct electrical contact with the power supply electrodes (1, 2) inside the electrochromic system. The additional electrode is parallel to the power supply electrodes inside at least some of the cells (13).

    6-(biphenyl-ester)-3H-naphtho[2, 1-b]pyrans as photochromic dichroic dyes and optical article containing them

    公开(公告)号:AU2007293901B2

    公开(公告)日:2013-06-13

    申请号:AU2007293901

    申请日:2007-09-05

    Applicant: ESSILOR INT

    Abstract: A naphthopyran compound represented by the formula (I) wherein: n1, n2, p, m and q represent an integer; R1, R2 and R4, represent a group selected from halogen, -Ra, -OH, -ORa, -SH, -SRa, -NH2, -NRaRa1, -NRbRc, -CO-Ra, -CO2Ra1, -OC(O)-Rd, -X-(Re)-Y, linear or branched (C1-C18) perfluoroalkyl group, wherein Ra, Ra1, Rb, Rc, X, Y, Re, and Rd are as defined in the description; Z represents a group selected from CO, CS, SO, SO2, CO2, C(O)S, CS2, C(O)NH, C(O)NRa, C(S)NH, C(S)NRa and C=NRa; R3 represents a group selected from halogen, -Ra, linear or branched (C1-18) perfluoroalkyl group -OH, -ORa, -SH, -SRa, -NH2, and -NRaRa1; R6 represents a group selected from -Ra which may be optionally substituted, linear or branched (C1-18) perfluoroalkyl, cycloalkyl, heterocycloalkyl, aryl, and heteroaryl, which may be optionally substituted; R5 represents a group selected from: halogen, -Ra, linear or branched (C1-18) perfluoroalkyl group, -OH, -ORa, -SH, -SRa, -NH2, -NRaRa1, -CO-Ra, -O-C(O)-Ra and -CO2Ra1; or when q is equal to 2, then two R5 together represents further a group -O-(CH2)q1-O- wherein q1 represents an integer comprised from 1 to 3 inclusive.

    Photochromic optical article comprising a saturated photochromic coating and a film absorbing UV radiation

    公开(公告)号:AU2010333253A1

    公开(公告)日:2012-06-21

    申请号:AU2010333253

    申请日:2010-10-07

    Applicant: ESSILOR INT

    Abstract: The invention relates to a photochromic optical article with reduced thermal dependency, comprising: (a) a transparent substrate, (b) a saturated photochromic layer having, in the activated state and at a temperature of 20°C, a relative transmission factor of less than 1% in the visible range, and (c) an anti-UV coating of plastic material at least partially covering the saturated photochromic layer, the said anti-UV coating containing at least one agent which absorbs UV radiation (anti-UV agent) and is distributed in a pattern consisting of a multitude of points, each having a surface area of less than 0.15 mm 2, the average distance between two neighbouring points lying between 0.5 and 2 mm and the ratio of the overall surface area of all the points to the total surface area of the anti-UV coating being such that the relative transmission factor of the optical article in the visible range in the activated state and at 20°C is at least equal to 5%. The invention also relates to two methods for manufacturing such an optical article.

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