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公开(公告)号:BRPI1006962A2
公开(公告)日:2016-04-12
申请号:BRPI1006962
申请日:2010-02-02
Applicant: ESSILOR INT
Inventor: VALERI ROBERT
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公开(公告)号:AU2011353751B8
公开(公告)日:2015-10-15
申请号:AU2011353751
申请日:2011-01-04
Applicant: ESSILOR INT
Inventor: VALERI ROBERT
Abstract: The present invention is drawn to a method for manufacturing antistatic UV-cured hard-coatings on optical articles, comprising (a) coating an organic or mineral optical substrate with an essentially anhydrous solution containing from 20 % to 90 % by weight, relative to the total dry matter of the solution, of at least one non hydrolyzed epoxyalkyltrialkoxysilane and at least 3.2 % by weight, relative to the total dry matter of the solution, of at least one photoinitiator selected from the group consisting of triarylsulfonium salts, diaryliodonium salts, and mixtures thereof, (b) curing the resulting coating by irradiation with UV-radiation, said method not comprising any hydrolysis step before the UV curing step.
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公开(公告)号:FR2887488A1
公开(公告)日:2006-12-29
申请号:FR0506350
申请日:2005-06-22
Applicant: ESSILOR INT
Inventor: BIVER CLAUDINE , LESARTRE NOEMIE , PADIOU JEAN MARC , VALERI ROBERT
Abstract: Procédé d'obtention d'un article transparent exempt de raies de surfaçage visibles, comprenant :- l'obtention d'un substrat en un matériau transparent d'indice de réfraction ns, dont au moins une face principale a été ébauchée et polie à une valeur de Ra variant de 0,001 à 0,01 mum mais qui présente des défauts de surface visibles sous la forme de fines rayures individualisées ;- le dépôt directement sur la face principale ébauchée et polie du substrat d'une composition liquide, polymérisable, de revêtement de masquage présentant un angle de contact avec la face principale du substrat d'au plus 30 degree , et formant par polymérisation un revêtement de masquage ayant un indice de réfraction nc tel que 0,01
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公开(公告)号:AT328943T
公开(公告)日:2006-06-15
申请号:AT01945327
申请日:2001-06-28
Applicant: ESSILOR INT
Inventor: VALERI ROBERT , ANDERSON KIMBERLEY , WHITE SIDNEY JR
IPC: B05D5/00 , B05D7/02 , B05D7/24 , B32B17/10 , C08J3/24 , C08J7/04 , C09D4/00 , C09D5/00 , C09D163/00 , C09D201/10 , C08J7/18 , C09D183/06
Abstract: The process comprises, (a) adding to a polymerizable composition containing a component A comprising at least one silane compound containing at least one epoxy group and at least two alkoxy groups directly bonded to the Si atom of the molecule or hydrolysate thereof and a component B comprising fine particles of silica, an effective amount of at least one cationic photopolymerization initiator and an effective amount of at least one thermal polymerization catalyst, (b) coating at least one surface of the substrate with the composition resulting from step (a), (c) submitting the coated substrate to a photopolymerization step for pre-curing the coating layer; and thereafter, (d) submitting the substrate with the pre-cured coating layer thereon to a thermal curing at a predetermined temperature and for a predetermined time to complete curing of the coating layer.
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公开(公告)号:CA2727618C
公开(公告)日:2016-10-18
申请号:CA2727618
申请日:2009-06-09
Applicant: ESSILOR INT (COMPAGNIE GENERALE D'OPTIQUE)
Inventor: VALERI ROBERT
IPC: C09D4/06 , C08K5/06 , C09D133/08 , G02B1/04
Abstract: An abrasion resistant photocurable acrylic coating composition that can provide good adhesion to subsequent coatings deposited thereon, and a hard coated article, especially an optical article such as an ophthalmic lens, comprising a substrate coated with a coating obtained from an abrasion resistant acrylic coating composition providing good subsequent adhesion Said composition comprises adequate amounts of at least one compound having from 5 to 7 acrylate groups, at least one compound having from 3 to 4 acrylate groups, at least one compound having 2 acrylate groups, at least one diepoxy compound, at least one hydrolyzate of an expoxysilane, and at least one non polymerizable ether compound.
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16.
公开(公告)号:EA024448B1
公开(公告)日:2016-09-30
申请号:EA201300795
申请日:2011-01-04
Applicant: ESSILOR INT
Inventor: VALERI ROBERT
IPC: C09D5/24 , C09D4/00 , C09D183/06 , G02B1/10
Abstract: Настоящееизобретениеотноситсяк способуизготовленияантистатическихУФ-отверждённыхтвёрдыхпокрытийнаоптическихизделиях, включающемустадии, накоторых: (a) наорганическуюилинеорганическуюоптическуюподложкунаносят, посуществу, безводныйраствор, включающий 20-90 мас.% относительнообщеймассысухоговеществав растворепоменьшеймереодногонегидролизованногоэпоксиалкилтриалкоксисиланаи поменьшеймере 3,2 мас.% относительнообщеймассысухоговеществав растворепоменьшеймереодногофотоинициатора, выбранногоизгруппы, состоящейизсолейтриарилсульфония, солейдиарилйодонияи ихсмесей, (b) полученноепокрытиеотверждаютприоблученииУФ-излучением.
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公开(公告)号:AU2011353751A8
公开(公告)日:2015-10-15
申请号:AU2011353751
申请日:2011-01-04
Applicant: ESSILOR INT
Inventor: VALERI ROBERT
IPC: C09D5/24 , C09D4/00 , C09D183/06 , G02B1/10
Abstract: The present invention is drawn to a method for manufacturing antistatic UV-cured hard-coatings on optical articles, comprising (a) coating an organic or mineral optical substrate with an essentially anhydrous solution containing from 20 % to 90 % by weight, relative to the total dry matter of the solution, of at least one non hydrolyzed epoxyalkyltrialkoxysilane and at least 3.2 % by weight, relative to the total dry matter of the solution, of at least one photoinitiator selected from the group consisting of triarylsulfonium salts, diaryliodonium salts, and mixtures thereof, (b) curing the resulting coating by irradiation with UV-radiation, said method not comprising any hydrolysis step before the UV curing step.
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公开(公告)号:IN5098DEN2012A
公开(公告)日:2015-10-09
申请号:IN5098DEN2012
申请日:2012-06-08
Applicant: ESSILOR INT
Inventor: VALERI ROBERT
IPC: C08G59/38
Abstract: A heat-curable composition comprises - from 25 to 65 % by weight of a mixture of epoxyfunctional monomers, said mixture consisting of at least one polyfunctional epoxy monomer selected from monomers comprising from 4 to 8 glycidyl groups and/or cycloaliphatic epoxy groups, and at least one bi- or tri-functional epoxy monomer selected from monomers comprising two or three glycidyl groups and/or cycloaliphatic epoxy groups, - from 25 to 70 % by weight of at least one organic solvent selected from glycol monoethers, - fiom 2.5 to 5 % by weight, relative to the total weight of epoxyfunctional monomers (a) and (b), of at least one blocked strong acid catalyst, said heat-curable composition not containing any nonepoxyfunctional monomers, in particular not containing any acrylic, methacrylic or silane monomers.
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19.
公开(公告)号:CA2934674A1
公开(公告)日:2015-06-25
申请号:CA2934674
申请日:2013-12-20
Applicant: ESSILOR INT (COMPAGNIE GENERALE D'OPTIQUE)
Inventor: VALERI ROBERT , BITEAU JOHN
Abstract: The present invention proposes a polymer composition of manufacturing ophthalmic lens by polymerization of polymerizable composition wherein the shrinkage phenomenon is minimized. The polymerizable composition comprised two different categories of monomers which are able during crosslinking to control and limit said chemical shrinkage. The present invention comprises also ophthalmic lens obtained from said polymer composition using a manufacturing process of casting or additive manufacturing.
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公开(公告)号:AU2011353751B2
公开(公告)日:2015-06-11
申请号:AU2011353751
申请日:2011-01-04
Applicant: ESSILOR INT
Inventor: VALERI ROBERT
IPC: C09D5/24 , C09D4/00 , C09D183/06 , G02B1/10
Abstract: The present invention is drawn to a method for manufacturing antistatic UV-cured hard-coatings on optical articles, comprising (a) coating an organic or mineral optical substrate with an essentially anhydrous solution containing from 20 % to 90 % by weight, relative to the total dry matter of the solution, of at least one non hydrolyzed epoxyalkyltrialkoxysilane and at least 3.2 % by weight, relative to the total dry matter of the solution, of at least one photoinitiator selected from the group consisting of triarylsulfonium salts, diaryliodonium salts, and mixtures thereof, (b) curing the resulting coating by irradiation with UV-radiation, said method not comprising any hydrolysis step before the UV curing step.
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