POLYMERIZABLE CARBAMOYLOXYALKYLDICARBOXYLIC ACID ESTERS CARRYING HYDROXYL GROUPS

    公开(公告)号:AU582712B2

    公开(公告)日:1989-04-06

    申请号:AU5331786

    申请日:1986-02-07

    Applicant: HOECHST AG

    Abstract: Polymerizable carbamoyloxyalkyldicarboxylic acid esters, carrying hydroxyl groups, of the general formula (I) (I) in which R1 represents hydrogen or allyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical, R2 represents alkyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical or the radical subject to the proviso that R1 is hydrogen and x is an integer from 2 to 20, R3 represents linear or branched alkylene having 2 to 5 carbon atoms, R4 represents hydrogen or methyl and R5 represents hydroxyalkyl or hydroxyaminoalkyl having in each case 2 to 20 carbon atoms in the alkyl radical or an alkyl radical of this type which also contains ester and/or ether groups, and a process for their preparation. The esters according to the invention can be used for the preparation of copolymers.

    POLYMERIZABLE CARBAMOYLOXYALKYLDICARBOXYLIC ACID ESTERS CARRYING HYDROXYL GROUPS

    公开(公告)号:AU5331786A

    公开(公告)日:1986-08-14

    申请号:AU5331786

    申请日:1986-02-07

    Applicant: HOECHST AG

    Abstract: Polymerizable carbamoyloxyalkyldicarboxylic acid esters, carrying hydroxyl groups, of the general formula (I) (I) in which R1 represents hydrogen or allyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical, R2 represents alkyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical or the radical subject to the proviso that R1 is hydrogen and x is an integer from 2 to 20, R3 represents linear or branched alkylene having 2 to 5 carbon atoms, R4 represents hydrogen or methyl and R5 represents hydroxyalkyl or hydroxyaminoalkyl having in each case 2 to 20 carbon atoms in the alkyl radical or an alkyl radical of this type which also contains ester and/or ether groups, and a process for their preparation. The esters according to the invention can be used for the preparation of copolymers.

    COATING COMPOSITIONS IN POWDER FORM

    公开(公告)号:CA2064292A1

    公开(公告)日:1992-10-19

    申请号:CA2064292

    申请日:1992-03-27

    Applicant: HOECHST AG

    Abstract: HOECHST AKTIENGESELLSCHAFT - Werk KALLE-ALBERT 91/F 114 16 April 1991 WL-Dr.Ot.-ui Coating compositions in powder form A coating composition in powder form which is composed of (A) a copolymer containing glycidyl groups, (B) an aliphatic or cycloaliphatic dibasic acid, its anhydride or a polyol-modified anhydride of a dibasic acid, (C) optionally, pigments and other additives. The copolymer (A) has a molecular weight tMn) of 1,000-10,000 and a glass transition temperature of 30-90.degree.C and is a mixed polymer composed of a) at least 20% by weight of glycidyl acrylate or glycidyl methacrylate, b) 35-50% by weight of styrene, c) 10-45% by weight of one or more alkyl esters of aliphatic unsaturated monocarboxylic or dicarboxylic acids and d) 0-50% by weight of one or more other olefinically unsaturated monomers.

    CARBAMOYLOXYALKYLDIACID ESTER COPOLYMERS

    公开(公告)号:AU578876B2

    公开(公告)日:1988-11-03

    申请号:AU5331886

    申请日:1986-02-07

    Applicant: HOECHST AG

    Abstract: Copolymers based on (A) 5-95% by weight of at least one polymerizable carbamoyloxyalkyldicarboxylic acid ester, carrying hydroxyl groups, of the general formula I in which R1 represents hydrogen or alkyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical, R2 represents alkyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical, or the radical subject to the proviso that R1 is hydrogen and x is an integer from 2 to 10, R3 represents linear or branched alkylene having 2 to 5 carbon atoms, R4 represents hydrogen or methyl and R5 represents hydroxyalkyl or hydroxyaminoalkyl having in each case 2 to 20 carbon atoms in the alkyl radical, or an alkyl radical of this type which also contains ester groups and/or ether groups, and (B) 5-95% by weight of at least one copolymerizable monomer belonging to the group comprising (a) alpha , beta -olefinically unsaturated monocarboxylic acid and alkyl and hydroxyalkyl esters thereof having in each case 1 to 18 carbon atoms in the alkyl radical, and amides and nitriles thereof, and also monoalkyl and dialkyl esters of alpha , beta -olefinically unsaturated dicarboxylic acids having 1 to 18 carbon atoms in the alkyl radical, (b) vinyl-aromatic monomers, (c) vinyl esters of organic monocarboxylic acids having 1 to 18 carbon atoms in the carboxylic acid radical, and (d) glycidyl esters of unsaturated monocarboxylic and/or dicarboxylic acids, the sum of the components (A) and (B) being in all cases 100% by weight, and a process for their preparation. The copolymers are used for the preparation of shaped articles and/or coatings which have excellent properties.

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