Abstract:
Manufacture of heat-drying, water-dilutable paints on the basis of (a) epoxy resins with no amino groups, (b) of an aqueous dispersion or solution of saturated polyester resins or of their modification products in oil, (c) organic wetting agents and, where appropriate (d) pigments and/or the usual additives in specific quantity ratios, whereby these components are processed together in one or more stages reducing the size of the original particles to produce a homogeneous paint whose particle size is lower that 100 microns, and the use of the paints obtained in this way as a covering medium for coating, in particular of metallic substrates, by means of non-electric coating procedures or of electrostatic spraying.
Abstract:
Coating compsn. contains (A) a film-forming resin, (B) a cellulose ester, (C) solvent, (D) metal pigment and opt. (E) crosslinkers and (F) further lacquer additives and of the type esp. to give a multi-layer coating with a base layer and opt. a clear topcoat. (i) the cellulose ester (B) has an acetyl content of 2-30 (pref. 2-5) wt.%, a butyryl content of 17-53 (pref. 47-53) wt.% and an average mol.wt. of at least 25000, pref. 30000-60000; and (ii) this cellulose ester is introduced into the coating compsn. in the form of a pasty, thixotropic pre-mix (e.g. with the crosslinkers). The solids content of the compsn. is pref. 15-30 wt.%. The cellulose ester pre-mix pref. contains a diluent which swells the cellulose ester, esp. an aromatic or aliphatic hydrocarbon or a higher alcohol. alcohol.
Abstract:
Preparation of heat-curable, water-dilutable coating compositions based on (A) epoxy resins free from amino groups, (B) an aqueous dispersion or solution of saturated polyester resins or the modification products thereof with oils, (C) organic cross-linking agents and optionally (D) pigments and/or conventional adjuvants, in specific proportions, these components being processed together in one or more stages, while being comminuted from their original particle size, to form a homogeneous coating composition which has a particle size of less than 100 mu m, and the use of the coating compositions thus obtained as coating agents, particularly for coating metal substrates, by the use of current-free methods of application or electrostatic spraying.
Abstract:
A water-dilutable binder composition for the preparation of a metallic base paint comprising A) a water-soluble condensation product derived from a) a saturated or unsaturated oil-free polyester containing OH-groups having been prepared from at least one polycarboxylic acid and at least one polyhydric alcohol, b) a polycarboxylic acid mixture containing trimellitic acid, c) at least one epoxidized oil, and d) a basic compound; B) an additive selected from the group consisting of one or more metal powders, one or more metal powders in combination with at least one other pigment, and one or more metal powders in combination with at least one other dyestuff; and C) at least one water-miscible solvent a process for the preparation of a two-layer metallic paint coating with said composition.
Abstract:
Polymerizable carbamoyloxyalkyldicarboxylic acid esters, carrying hydroxyl groups, of the general formula (I) (I) in which R1 represents hydrogen or allyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical, R2 represents alkyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical or the radical subject to the proviso that R1 is hydrogen and x is an integer from 2 to 20, R3 represents linear or branched alkylene having 2 to 5 carbon atoms, R4 represents hydrogen or methyl and R5 represents hydroxyalkyl or hydroxyaminoalkyl having in each case 2 to 20 carbon atoms in the alkyl radical or an alkyl radical of this type which also contains ester and/or ether groups, and a process for their preparation. The esters according to the invention can be used for the preparation of copolymers.
Abstract:
Coating compsn. contains (A) a film-forming resin, (B) a cellulose ester, (C) solvent, (D) metal pigment and opt. (E) crosslinkers and (F) further lacquer additives and of the type esp. to give a multi-layer coating with a base layer and opt. a clear topcoat. (i) the cellulose ester (B) has an acetyl content of 2-30 (pref. 2-5) wt.%, a butyryl content of 17-53 (pref. 47-53) wt.% and an average mol.wt. of at least 25000, pref. 30000-60000; and (ii) this cellulose ester is introduced into the coating compsn. in the form of a pasty, thixotropic pre-mix (e.g. with the crosslinkers). The solids content of the compsn. is pref. 15-30 wt.%. The cellulose ester pre-mix pref. contains a diluent which swells the cellulose ester, esp. an aromatic or aliphatic hydrocarbon or a higher alcohol. alcohol.
Abstract:
Copolymers based on A) 5-95% by weight of at least one polymerizable carbamoyloxyalkyldicarboxylic acid ester, carrying hydroxyl groups, of the general formula I in which R1 represents hydrogen or alkyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical, R2 represents alkyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical, or the radical subject to the proviso that R1 is hydrogen and x is an integer from 2 to 10, R3 represents linear or branched alkylene having 2 to 5 carbon atoms, R4 represents hydrogen or methyl and R5 represents hydroxyalkyl or hydroxyaminoalkyl having in each case 2 to 20 carbon atoms in the alkyl radical, or an alkyl radical of this type which also contains ester groups and/or ether groups, and 8) 5-95% by weight of at least one copolymerizable monomer belonging to the group comprising a) .alpha.,.beta.-olefinically unsaturated monocarboxylic acid and alkyl and hydroxyalkyl esters thereof having in each case 1 to 18 carbon atoms in the alkyl radical, and amides and nitriles thereof, and also monoalkyl and dialkyl esters of .alpha.,.beta.-olefinically unsaturated dicarboxylic acids having 1 to 18 carbon atoms in the alkyl radical, b) vinyl-aromatic monomers, c) vinyl esters of organic monocarboxylic acids having 1 to 18 carbon atoms in the carboxylic acid radical, and d) glycidyl esters of unsaturated monocarboxylic and/or dicarboxylic acids, the sum of the components A) and B) being in all cases 100% by weight, and a process for their preparation. The copolymers are used for the preparation of shaped articles and/or coatings which have excellent properties.
Abstract:
Coating compsn. contains (A) a film-forming resin, (B) a cellulose ester, (C) solvent, (D) metal pigment and opt. (E) crosslinkers and (F) further lacquer additives and of the type esp. to give a multi-layer coating with a base layer and opt. a clear topcoat. (i) the cellulose ester (B) has an acetyl content of 2-30 (pref. 2-5) wt.%, a butyryl content of 17-53 (pref. 47-53) wt.% and an average mol.wt. of at least 25000, pref. 30000-60000; and (ii) this cellulose ester is introduced into the coating compsn. in the form of a pasty, thixotropic pre-mix (e.g. with the crosslinkers). The solids content of the compsn. is pref. 15-30 wt.%. The cellulose ester pre-mix pref. contains a diluent which swells the cellulose ester, esp. an aromatic or aliphatic hydrocarbon or a higher alcohol. alcohol.
Abstract:
of the disclosure: Preparation of heat-curable, water-dilutable coating compositions based on A) epoxy resins free from amino groups, B) an aqueous dispersion or solution of saturated polyester resins or the modification products thereof with oils, C) organic cross-linking agents and optionally D) pigments and/or conventional adjuvants, in specific proportions, these components being processed together in one or more stages, whilst being comminuted from their original particle size, to form a homogeneous coating composition which has a particle size of less than 100 pm, and the use of the coating compositions thus obtained as coating agents, particularly for coating metal substrates, by the use of current-free mcthods of application or electrostatic spraying.