公开(公告)号：CA1134541A

公开(公告)日：1982-10-26

申请号：CA346698

申请日：1980-02-29

Applicant: HOECHST AG

Inventor： RITZ JUERGEN ,  HOTZE HERMANN ,  MUMMENTHEY HANS-DIETER

IPC: C08F20/00 ,  C08F20/52 ,  C08F212/02 ,  C08F222/20 ,  C08G18/62 ,  C09D133/04 ,  C09D135/00 ,  C09J133/04 ,  C08G65/32 ,  C08G18/42

Abstract: A process for the preparation of copolymers in which in a first step an olefinically unsaturated dicarboxylic acid is reacted with a polyhydric alcohol to yield a hemi-ester having free hydroxyl groups, which in a second step is reacted with a monoepoxy compound to yield an olefinically unsaturated diester containg hydroxyl groups, wherein the diester is copolymerized in at least one further step with at least one unsaturated monomer having no free carboxyl groups, and the hardenable reaction product thus obtained is either isolated or hardened with a hardening agent, and coating and adhesive compositions containing a copolymer thus obtained.

公开(公告)号：CA978693A

公开(公告)日：1975-11-25

申请号：CA138626

申请日：1972-03-30

Applicant: HOECHST AG

Inventor： WIRTH THADDAEUS ,  SPRENGER WALTER ,  PETER JOACHIM ,  RITZ JUERGEN

IPC: C08G59/14

Abstract: An article of manufacture comprising a substrate which is coated with a primer and a second coating adhering to the primer. The primer comprising as an essential ingredient an epoxy resin modified by acetoacetic ester groups which may also contain chemically bound metal atoms as a chelate. The cover layer contains a homo- or a copolymer of a fluorine-containing vinyl monomer having up to two fluorine atoms or a combination of such polymers.

公开(公告)号：IT1157316B

公开(公告)日：1987-02-11

申请号：IT2310182

申请日：1982-09-02

Applicant: HOECHST AG

Inventor： HESSE WOLFGANG ,  RITZ JUERGEN ,  ZIMMERMANN ROLF

IPC: C08G8/28 ,  C08G8/00 ,  C08G8/36 ,  C08G59/14 ,  C08G59/50 ,  C08G59/56 ,  C08G59/62 ,  C08L63/00 ,  C09D5/44 ,  C09D161/04 ,  C09D163/00 ,  C08G

Abstract: Binders based on co-condensates of epoxy resins and resols with amines, the epoxy resin being partially defunctionalized and still containing on average 0.5-1.3 epoxide groups per molecular unit, the resol component being composed of methylol compounds of oligomethylene compounds, which are additionally substituted by hydrocarbon or hydroxyalkyl or hydroxyaralkyl radicals, and the amine containing at least one primary or secondary amino group and at most 2 hydroxyl groups. The invention further relates to a process for the preparation of a binder and for the electrophoretic deposition of a cationic resin from an aqueous dispersion onto an article connected as the cathode and to an aqueous electrophoresis bath for carrying out this process.

公开(公告)号：AT20473T

公开(公告)日：1986-07-15

申请号：AT83900029

申请日：1982-12-13

Applicant: HOECHST AG

Inventor： JUST CHRISTOPH ,  RITZ JUERGEN ,  ZIMMERMANN ROLF

IPC: C08G18/00 ,  C08G18/69 ,  C08G18/80 ,  C09D5/44 ,  C09D115/00 ,  C09D175/00 ,  C09D3/36 ,  C09D3/49

公开(公告)号：CA1174790A

公开(公告)日：1984-09-18

申请号：CA384398

申请日：1981-08-21

Applicant: HOECHST AG

Inventor： RITZ JUERGEN ,  FISCHER HANNES ,  PLUM HELMUT

IPC: C08F20/00 ,  C08F20/26 ,  C08F222/10 ,  C08L75/00 ,  C09D133/14 ,  C09D167/07 ,  C09J133/04 ,  C08G63/42 ,  C08G18/42

Abstract: : Process for the manufacture of hardenable copolymers by the polymerisation of unsaturated esters with unsaturated polymerisable monomers containing no free COOH groups, wherein an olefinically unsaturated diester containing OH groups is used as the unsaturated ester, said diester being obtained by reacting olefinically unsaturated dicarboxylic acids or the anhydrides thereof with a polyhydric alcohol and a monoepoxide compound in one or more steps, characterised in that the copolymerisation of the diesters with monomers which contain no free COOH groups is carried out in the presence of copolymerisable monomers containing free COOH groups, and the use of the copolymers as hardenable binders for lacquers and/or coating compositions.

公开(公告)号：CA1221790A

公开(公告)日：1987-05-12

申请号：CA417790

申请日：1982-12-15

Applicant: HOECHST AG

Inventor： JUST CHRISTOPH ,  RITZ JUERGEN ,  ZIMMERMANN ROLF

IPC: C08G18/00 ,  C08G18/69 ,  C08G18/80 ,  C09D5/44 ,  C09D115/00 ,  C09D175/00 ,  C08L7/00 ,  C08L15/00

Abstract: of the disclosure: A water-dilutable binder for coatings based on reaction products of diene polymers and poly-unsaturated polyfunctional amidoamines, which comprises a) a cyclorubber, b) a polyfunctional amidoamine which has been added to component a) and is derived from reaction with a monomeric unsaturated fatty acid free from conjugated double bonds but having 12 to 18 carbon atoms or from its oligomers, and c) a polyisocyanate which is bonded to component b) and whose isocyanate groups which are not bonded to component b) are blocked , a process for its preparation and its use for paints and coatings.

公开(公告)号：CA1218488A

公开(公告)日：1987-02-24

申请号：CA389414

申请日：1981-11-04

Applicant: HOECHST AG

Inventor： HESSE WOLFGANG ,  HOFMANN KLAUS ,  MANZ ALBRECHT ,  RITZ JUERGEN

IPC: C08L61/00 ,  C08G8/00 ,  C08G8/12 ,  C08G59/00 ,  C08G59/14 ,  C08G59/56 ,  C08G59/62 ,  C08L61/04 ,  C08L61/06 ,  C08L63/00 ,  C08L63/02 ,  C09D5/44 ,  C09D161/04 ,  C09D161/06 ,  C09D163/00 ,  C09D163/02 ,  C09D3/56

Abstract: Dispersion based on self-hardening mixtures of A) epoxy resins obtained from diphenylolalkane and epihalohydrin and B) phenolic resins in the form of methylol compounds of substituted polyphenol compounds based on a mixture of substituted and unsubstituted phenols on the one hand and formaldehyde on the other hand, in a weight ratio of A) : B) of from 10 : 90 to 90 : 10, characterised in that the dispersion, which can be deposited by means of bases or electric current, contains a reaction product which has been prepared from an epoxy resin A) with an average molecular weight of from 300 to 30,000 with C) a secondary amine which is thus present in the reaction product as a tertiary amine and is converted into a salt therein with an inorganic or monocarboxylic acid D), the amine C) having been reacted in an amount of from 10 to 100 equivalent-% per epoxy group, whilst the equivalent ratio between the tertiary amine group and the acid is (25 to 200) : 100, process for preparing the dispersion and the use thereof in the production of coatings.

公开(公告)号：AT16195T

公开(公告)日：1985-11-15

申请号：AT82902722

申请日：1982-09-01

Applicant: HOECHST AG

Inventor： HESSE WOLFGANG ,  RITZ JUERGEN ,  ZIMMERMANN ROLF

IPC: C08G59/56 ,  C08G59/62 ,  C08L63/00 ,  C09D5/44

公开(公告)号：ZA829210B

公开(公告)日：1983-10-26

申请号：ZA829210

申请日：1982-12-15

Applicant: HOECHST AG

Inventor： JUST CHRISTOPH ,  RITZ JUERGEN ,  ZIMMERMANN ROLF

IPC: C08G18/00 ,  C08G18/69 ,  C08G18/80 ,  C09D5/44 ,  C09D115/00 ,  C09D175/00 ,  C08G

Abstract: A water-dilutable binder for coatings based on reaction products of diene polymers and poly-unsaturated polyfunctional amidoamines, which comprises (a) a cyclorubber, (b) a polyfunctional amidoamine which has been added to component (a) and is derived from reaction with a monomeric unsaturated fatty acid free from conjugated double bonds but having 12 to 18 carbon atoms or from its oligomers, and (c) a polyisocyanate which is bonded to component (b) and whose isocyanate groups which are not bonded to component (b) are blocked, a process for its preparation and its use for paints and coatings.

公开(公告)号：ZA826454B

公开(公告)日：1983-08-31

申请号：ZA826454

申请日：1982-09-03

Applicant: HOECHST AG

Inventor： HESSE WOLFGANG ,  RITZ JUERGEN ,  ZIMMERMANN ROLF

IPC: C08G8/28 ,  C08G8/00 ,  C08G8/36 ,  C08G59/14 ,  C08G59/50 ,  C08G59/56 ,  C08G59/62 ,  C08L63/00 ,  C09D5/44 ,  C09D161/04 ,  C09D163/00 ,  C08G

Abstract: Binders based on co-condensates of epoxy resins and resols with amines, the epoxy resin being partially defunctionalized and still containing on average 0.5-1.3 epoxide groups per molecular unit, the resol component being composed of methylol compounds of oligomethylene compounds, which are additionally substituted by hydrocarbon or hydroxyalkyl or hydroxyaralkyl radicals, and the amine containing at least one primary or secondary amino group and at most 2 hydroxyl groups. The invention further relates to a process for the preparation of a binder and for the electrophoretic deposition of a cationic resin from an aqueous dispersion onto an article connected as the cathode and to an aqueous electrophoresis bath for carrying out this process.