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公开(公告)号:CA1286317C
公开(公告)日:1991-07-16
申请号:CA506740
申请日:1986-04-15
Applicant: HOECHST AG
Inventor: SEMLER GUENTHER , SCHAEFFER GEORG
IPC: C07C271/04 , C07C67/00 , C07C239/00 , C07C271/02
Abstract: Carbamoyl chlorides derived from secondary aliphatic amines having alkyl groups which are branched in the 1position are prepared by passing phosgene at an elevated temperature into the corresponding, initially taken - if appropriate dissolved in an inert solvent - secondary aliphatic amines having alkyl groups which are branched in the 1-position. The reaction products are intermediates in various specialized fields, particularly in the plant protection sector.
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公开(公告)号:AU538329B2
公开(公告)日:1984-08-09
申请号:AU6627581
申请日:1981-01-16
Applicant: HOECHST AG
Inventor: SPIELMAN WERNER , SCHAEFFER GEORG
IPC: C07C59/52 , C07C51/00 , C07C51/377 , C07C67/00 , C07C59/48
Abstract: p-Hydroxyphenylacetic acid is prepared by reduction of p-hydroxymandelic acid with HI in the presence of red phosphorus. According to a preferred embodiment, the reaction is carried out in one vessel in which the mandelic acid is prepared in situ from phenol and glyoxylic acid.
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公开(公告)号:AU530755B2
公开(公告)日:1983-07-28
申请号:AU5320579
申请日:1979-11-27
Applicant: HOECHST AG
Inventor: SPIELMANN WERNER , SCHAEFFER GEORG
IPC: C07C45/45 , C07C45/75 , C07C49/00 , C07C69/76 , C07D307/46 , C07D333/16 , C07D333/22 , C07C45/15
Abstract: Ketones are prepared by reacting carboxylic acid halides, in particular carboxylic acid chlorides, with aluminum-alkyl compounds, optionally in the presence of an aluminum trihalide, in methylene chloride as the solvent, at a temperature between about 20 DEG and about 100 DEG C., preferably between about 30 DEG and about 60 DEG C., more preferably of about 40 DEG C. which is the reflux temperature of the methylene chloride. When operating at a temperature above approximately 40 DEG C., pressure higher than atmospheric is applied. The reaction mixture is worked up in usual manner, suitably by decomposition with water followed by distillation.
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公开(公告)号:DE2962101D1
公开(公告)日:1982-03-18
申请号:DE2962101
申请日:1979-11-13
Applicant: HOECHST AG
Inventor: LANDAUER FRANZ , SCHAEFFER GEORG
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公开(公告)号:DE2849692A1
公开(公告)日:1980-05-22
申请号:DE2849692
申请日:1978-11-16
Applicant: HOECHST AG
Inventor: LANDAUER FRANZ , SCHAEFFER GEORG
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公开(公告)号:CA1019763A
公开(公告)日:1977-10-25
申请号:CA197964
申请日:1974-04-22
Applicant: HOECHST AG
Inventor: SEMLER GUENTHER , SCHAEFFER GEORG , WALDMANN KARL
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公开(公告)号:CA891526A
公开(公告)日:1972-01-25
申请号:CA891526D
Applicant: HOECHST AG
Inventor: SCHAEFFER GEORG , KAPPENBERGER HELMUT , SCHUTTE HEINZ
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公开(公告)号:DE2964310D1
公开(公告)日:1983-01-20
申请号:DE2964310
申请日:1979-11-13
Applicant: HOECHST AG
Inventor: LANDAUER FRANZ , SCHAEFFER GEORG
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公开(公告)号:CA1135276A
公开(公告)日:1982-11-09
申请号:CA363700
申请日:1980-10-31
Applicant: HOECHST AG
Inventor: SPIELMANN WERNER , SCHAEFFER GEORG
IPC: C07C69/614 , B01J23/00 , C07B61/00 , C07C51/00 , C07C51/377 , C07C57/32 , C07C57/58 , C07C59/52 , C07C59/64 , C07C67/00 , C07C69/73 , C07C69/76 , C07C227/00 , C07C227/16 , C07C229/42 , C07C231/00 , C07C231/12 , C07C235/42 , C07C59/11
Abstract: of the disclosure: Phenylacetic acid and the simple derivatives thereof are prepared by catalytic hydrogenation of mandelic acid and its appropriate derivatives in the presence of a noble metal catalyst in aqueous solution which is free from mineral acid, especially free from hydrochloric acid.
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公开(公告)号:CA1133939A
公开(公告)日:1982-10-19
申请号:CA339937
申请日:1979-11-15
Applicant: HOECHST AG
Inventor: LANDAUER FRANZ , SCHAEFFER GEORG
IPC: C07C22/04 , C07C25/02 , C07C25/13 , C07C45/43 , C07C45/80 , C07C45/85 , C07C47/542 , C07C47/55 , C07C63/06
Abstract: p-tert.Butylbenzaldehyde and the derivatives thereof halogen-substituted at the nucleus are prepared by bromination of p-tert.butyltoluene and the derivatives thereof halogen-substituted at the nucleus under side chain halogenation conditions until the benzal bromine is obtained which is then saponified. Practically no indesired bromination at the nuclear or the tert.butyl group takes place. The products obtained are valued intermediates for the manufacture of pharmaceutical agents. plant protecting agents and dyestuffs.
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