IMIDAZOLINE DERIVATIVES: ECTOPARASITICIDAL COMPOSITIONS AND PREPARATORY PROCESSES

    公开(公告)号:NZ231829A

    公开(公告)日:1992-05-26

    申请号:NZ23182989

    申请日:1989-12-18

    Applicant: HOECHST AG

    Abstract: The present invention relates to agents for systemic combating of ectoperasites in host animals, containing a compound of the formul I (I) in which R1 denotes hydrogen, (C1-C5)-alkyl, (C1-C3)-halogenoalkyl or halogen; R2 and R3 independently of one another denote (c1-C5)-alkyl, (C2-C5)-alkenyl, (C2-C5)-alkynyl, (C3-C7)-cycloalkyl, (C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl, halogen, cyano, nitro, (C1-C5)-alkoxy, (C1 -C3)-alkoxy-C1-C3)-alkyl, (C1-C3)-halogenoalkoxy or (C1-C3)-alkylthio, or R2 and R3 together form a polymethylene chain having 2 to 5 carbon atoms: R4 denotes hydrogen, (c1-C10)-alkyl, (C2-C5)-alkenyl or (C3-C7)-cycloalkyl; R5 denotes hydrogen, (C1-C10)-alkyl, (C3-C5)-alkenyl, C3-C5)-alkynyl, (C3-C7)- cycloalkyl, (C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl or (C1-C3)-alkoxy-(C hd 1-C3)-alkyl; X denotes oxygen, sulfur or an -NR6-group; and R6 denotes hydrogen, (C1-C5)-alkyl, (C3-C5)-alkenyl, C3-C5)-alkynyl, (C3-C7)-cycloalkyl, C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl or (C1-C3)-alkoxy-(C1 -C3)-alkyl, or biologically tolerated acid addition salts thereof. The compounds of the formulas I are novel in some cases and are likewise included in the invention.

    Combinations of herbicides and crop-protecting substances

    公开(公告)号:AU662581B2

    公开(公告)日:1995-09-07

    申请号:AU3047792

    申请日:1992-12-30

    Applicant: HOECHST AG

    Abstract: A herbicide-safener combination comprises a cyclic 2-acyl-1,3-dicarbonyl compound herbicide (I) and an 8-quinolinyloxyalkanoic acid derivative safener (II). A herbicidal composition contains at least one 2-acyl-1,3-dicarbonyl compound herbicide of formula (I) (or its salt) and at least one quinoline derivative safener of formula (II). R1, R3 = H, halo, alkyl, haloalkyl, haloalkoxy, CN, NO2, S(O)mR11, NR12R13, NR14COR15, COR16 or OCH2CH2OR21; R2 = halo, CN, NO2, alkyl, alkoxy, haloalkyl, haloalkoxy, S(O)pR10, OSO2R10 or N(R20)SO2R19; W = N or CH; R10 = alkyl, haloalkyl or alkoxy; R11 = alkyl, haloalkyl or NR17R16; or phenyl or benzyl (both optionally ring-substituted); R12-R15, R17, R18, R21 = H or alkyl; R16 = H, alkyl, haloalkyl or alkoxy; R19, R20 = alkyl or haloalkyl; m, p = 0-2; U = group completing an optionally further substituted 5- or 6-membered carbocyclic or heterocyclic ring; Y = halo, A', NO2 or OA; A = 1-4C alkyl; A' = 1-4C alkyl or 1-4C haloalkyl; n = 1-5; Q = 1-2C alkylene (optionally substituted by 1 or 2 A); Z' = ORa, SRa or NRRa; R = H, 1-6C alkyl, 1-6C alkoxy or optionally substituted phenyl; Ra = H; or 1-18C alkyl, 3-12C cycloalkyl, 2-8C alkenyl or 2-8C alkynyl (all optionally substituted by one or more of halo, OH, OB, SB, 3-7C cycloalkyl, 3-7C cycloalkoxy, CN, NHA, N(A)2, BOCO, 1-8C alkylthiocarbonyl, BCO, 1-(=NOH, =NA or =NOA)-1-6C alkyl, BCONH, CONH2, mono- or di-(1-6C alkyl)-aminocarbonyl, (2-6C alkenyl, 2-6C alkynyl or 1-8C alkoxy)-aminocarbonyl, 1-8C alkylaminocarbonylamino, 1-6C alkylcarbonyloxy (optionally substituted by halo, NO2, OA or optionally substituted phenyl), (2-6C alkenyl or 2-6C alkynyl)carbonyloxy, 1-8C alkylsulfonyl, Ar, Ar-(1-6C) alkoxy, Ar-(1-6C) alkoxycarbonyl, OAr, ArCOO, ArCONH, Ar-(1-6C) alkylcarbonylamino, Si(R')3, OSi(R')3, (R')3-(1-6C) alkoxy, COON(R')2, ON=C(R')2, N=C(R')2, ON(R')2, CH(OR')2, O(CH2)qCH(OR')2 or R''OCR'''(OR'')-(1-6C) alkoxy); or NRRa = optionally unsaturated 3-7 membered heterocycle containing 1-3 heteroatoms (optionally substituted by A, OA or optionally substituted phenyl); B = 1-8C alkyl, 2-8C alkenyl or 2-8C alkynyl; Ar = phenyl (optionally substituted by one or more of halo, A', OA' and NO2); R' = H, A or phenyl (optionally substituted by one or more of halo, A', OA; and NO2); or (R')2 = 2-6C alkylene; q = 0-6; R'' = A; or (R'')2 = 1-6C alkylene; R''' = H or A. Independent claims are included for: (1) a method for protecting crop plants against the phytotoxic side-effects of (I), involving applying (II) to the plants (or their seeds or growth area) before, after or simultaneously with application of (I); and (2) the use of (II) for protecting crop plants against the phytotoxic side-effects of herbicides (I).

    AGENTS CONTAINING IMIDAZOLINE DERIVATIVES FOR SYSTEMIC COMBATING OF EXTOPARASITES IN HOST ANIMALS AND NOVEL IMIDAZOLINE DERIVATIVES

    公开(公告)号:AU623461B2

    公开(公告)日:1992-05-14

    申请号:AU4685689

    申请日:1989-12-19

    Applicant: HOECHST AG

    Abstract: The present invention relates to agents for systemic combating of ectoperasites in host animals, containing a compound of the formul I (I) in which R1 denotes hydrogen, (C1-C5)-alkyl, (C1-C3)-halogenoalkyl or halogen; R2 and R3 independently of one another denote (c1-C5)-alkyl, (C2-C5)-alkenyl, (C2-C5)-alkynyl, (C3-C7)-cycloalkyl, (C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl, halogen, cyano, nitro, (C1-C5)-alkoxy, (C1 -C3)-alkoxy-C1-C3)-alkyl, (C1-C3)-halogenoalkoxy or (C1-C3)-alkylthio, or R2 and R3 together form a polymethylene chain having 2 to 5 carbon atoms: R4 denotes hydrogen, (c1-C10)-alkyl, (C2-C5)-alkenyl or (C3-C7)-cycloalkyl; R5 denotes hydrogen, (C1-C10)-alkyl, (C3-C5)-alkenyl, C3-C5)-alkynyl, (C3-C7)- cycloalkyl, (C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl or (C1-C3)-alkoxy-(C hd 1-C3)-alkyl; X denotes oxygen, sulfur or an -NR6-group; and R6 denotes hydrogen, (C1-C5)-alkyl, (C3-C5)-alkenyl, C3-C5)-alkynyl, (C3-C7)-cycloalkyl, C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl or (C1-C3)-alkoxy-(C1 -C3)-alkyl, or biologically tolerated acid addition salts thereof. The compounds of the formulas I are novel in some cases and are likewise included in the invention.

    AGENTS CONTAINING IMIDAZOLINE DERIVATIVES FOR SYSTEMIC COMBATING OF ECTOPARASITES IN HOST ANIMALS AND NOVEL IMIDAZOLINE DERIVATIVES

    公开(公告)号:ZA899722B

    公开(公告)日:1990-09-26

    申请号:ZA899722

    申请日:1989-12-19

    Applicant: HOECHST AG

    Abstract: The present invention relates to agents for systemic combating of ectoperasites in host animals, containing a compound of the formul I (I) in which R1 denotes hydrogen, (C1-C5)-alkyl, (C1-C3)-halogenoalkyl or halogen; R2 and R3 independently of one another denote (c1-C5)-alkyl, (C2-C5)-alkenyl, (C2-C5)-alkynyl, (C3-C7)-cycloalkyl, (C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl, halogen, cyano, nitro, (C1-C5)-alkoxy, (C1 -C3)-alkoxy-C1-C3)-alkyl, (C1-C3)-halogenoalkoxy or (C1-C3)-alkylthio, or R2 and R3 together form a polymethylene chain having 2 to 5 carbon atoms: R4 denotes hydrogen, (c1-C10)-alkyl, (C2-C5)-alkenyl or (C3-C7)-cycloalkyl; R5 denotes hydrogen, (C1-C10)-alkyl, (C3-C5)-alkenyl, C3-C5)-alkynyl, (C3-C7)- cycloalkyl, (C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl or (C1-C3)-alkoxy-(C hd 1-C3)-alkyl; X denotes oxygen, sulfur or an -NR6-group; and R6 denotes hydrogen, (C1-C5)-alkyl, (C3-C5)-alkenyl, C3-C5)-alkynyl, (C3-C7)-cycloalkyl, C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl or (C1-C3)-alkoxy-(C1 -C3)-alkyl, or biologically tolerated acid addition salts thereof. The compounds of the formulas I are novel in some cases and are likewise included in the invention.

    20.
    发明专利
    未知

    公开(公告)号:DK648489A

    公开(公告)日:1990-06-21

    申请号:DK648489

    申请日:1989-12-19

    Applicant: HOECHST AG

    Abstract: The present invention relates to agents for systemic combating of ectoperasites in host animals, containing a compound of the formul I (I) in which R1 denotes hydrogen, (C1-C5)-alkyl, (C1-C3)-halogenoalkyl or halogen; R2 and R3 independently of one another denote (c1-C5)-alkyl, (C2-C5)-alkenyl, (C2-C5)-alkynyl, (C3-C7)-cycloalkyl, (C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl, halogen, cyano, nitro, (C1-C5)-alkoxy, (C1 -C3)-alkoxy-C1-C3)-alkyl, (C1-C3)-halogenoalkoxy or (C1-C3)-alkylthio, or R2 and R3 together form a polymethylene chain having 2 to 5 carbon atoms: R4 denotes hydrogen, (c1-C10)-alkyl, (C2-C5)-alkenyl or (C3-C7)-cycloalkyl; R5 denotes hydrogen, (C1-C10)-alkyl, (C3-C5)-alkenyl, C3-C5)-alkynyl, (C3-C7)- cycloalkyl, (C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl or (C1-C3)-alkoxy-(C hd 1-C3)-alkyl; X denotes oxygen, sulfur or an -NR6-group; and R6 denotes hydrogen, (C1-C5)-alkyl, (C3-C5)-alkenyl, C3-C5)-alkynyl, (C3-C7)-cycloalkyl, C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl or (C1-C3)-alkoxy-(C1 -C3)-alkyl, or biologically tolerated acid addition salts thereof. The compounds of the formulas I are novel in some cases and are likewise included in the invention.

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