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11.
公开(公告)号:ZA921642B
公开(公告)日:1992-10-28
申请号:ZA921642
申请日:1992-03-05
Applicant: HOECHST AG
Inventor: STARK HERBERT , HERBERT STARK , BAUER KLAUS , KLAUS BAUER , BIERINGER HERMANN , HERMANN BIERINGER
IPC: A01N35/06 , A01N37/34 , A01N41/04 , A01N41/06 , A01N41/10 , C07C45/54 , C07C45/72 , C07C49/84 , C07C205/45 , C07C205/48 , C07C255/17 , C07C255/56 , C07C317/24 , C07C317/46 , C07C323/22 , C07C323/62 , C07C , A01N
Abstract: Compounds of the formula I (* CHEMICAL STRUCTURE *) (I) in which n is 0-6, R1 is alkyl, haloalkyl, cycloalkyl, halocycloalkyl, phenyl or halogenated phenyl, R2 is Hal, CN, alkyl, haloalkyl, alkoxy, haloalkoxy, thioalkyl, RaSO2-, RaSO2O-, RaSO2NR6, Ra and Rb being alkyl or haloalkyl, and R3 is H, Hal, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio, and R4 is haloalkyl, are suitable as selective herbicides and as growth regulators. To prepare them, a cyclohexanedione can be reacted a) with a 4-oxy-substituted benzoyl chloride and the resulting enol ether can be rearranged, or b) with a benzoyl cyanide. The benzoyl chloride or benzoyl cyanide required can be obtained from correspondingly substituted toluenes via the carboxylic acid.
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12.
公开(公告)号:CA2062440A1
公开(公告)日:1992-09-07
申请号:CA2062440
申请日:1992-03-05
Applicant: HOECHST AG
Inventor: STARK HERBERT , BAUER KLAUS , BIERINGER HERMANN
IPC: A01N35/06 , A01N37/34 , A01N41/04 , A01N41/06 , A01N41/10 , C07C45/54 , C07C45/72 , C07C49/84 , C07C205/45 , C07C205/48 , C07C255/17 , C07C255/56 , C07C317/24 , C07C317/46 , C07C323/22 , C07C323/62 , C07C311/02 , A01N35/04 , C07C317/32 , A01N37/42 , C07C205/59 , C07C309/65
Abstract: - 1 - HOE 91/F 066 of the disclosure Haloalkoxy-substituted benzoylcyclohexanediones as herbicides and plant growth regulators Compounds of the formula I (I) in which n is 0-6, R1 is alkyl, haloalkyl, cycloalkyl, halocycloalkyl, phenyl or halogenated phenyl, R2 is Hal, CN, alkyl, haloalkyl, alkoxy, haloalkoxy, thioalkyl, RaSO2-, RaSO2O-, RaSO2NR6, Ra and Rb being alkyl or haloalkyl, and R3 is H) Hal, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio, and R4 i haloalkyl, are suitable as selective herbicides and as growth regulators. To prepare them, a cyclohexanedione can be reacted a) with a 4-oxy-substituted benzoyl chloride and the resulting enol ether can be rearranged, or b) with a benzoyl cyanide. The benzoyl chloride or benzoyl cyanide required can be obtained from correspondingly substituted toluenes via the carboxylic acid.
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公开(公告)号:HU9200770D0
公开(公告)日:1992-05-28
申请号:HU9200770
申请日:1992-03-06
Applicant: HOECHST AG
Inventor: STARK HERBERT , BAUER KLAUS , BIERINGER HERMANN
IPC: A01N35/06 , A01N37/34 , A01N41/04 , A01N41/06 , A01N41/10 , C07C45/54 , C07C45/72 , C07C49/84 , C07C205/45 , C07C205/48 , C07C255/17 , C07C255/56 , C07C317/24 , C07C317/46 , C07C323/22 , C07C323/62
Abstract: Compounds of the formula I (* CHEMICAL STRUCTURE *) (I) in which n is 0-6, R1 is alkyl, haloalkyl, cycloalkyl, halocycloalkyl, phenyl or halogenated phenyl, R2 is Hal, CN, alkyl, haloalkyl, alkoxy, haloalkoxy, thioalkyl, RaSO2-, RaSO2O-, RaSO2NR6, Ra and Rb being alkyl or haloalkyl, and R3 is H, Hal, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio, and R4 is haloalkyl, are suitable as selective herbicides and as growth regulators. To prepare them, a cyclohexanedione can be reacted a) with a 4-oxy-substituted benzoyl chloride and the resulting enol ether can be rearranged, or b) with a benzoyl cyanide. The benzoyl chloride or benzoyl cyanide required can be obtained from correspondingly substituted toluenes via the carboxylic acid.
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公开(公告)号:NZ231829A
公开(公告)日:1992-05-26
申请号:NZ23182989
申请日:1989-12-18
Applicant: HOECHST AG
Inventor: STARK HERBERT , SALBECK GERHARD , BONIN WERNER
IPC: A61K31/415 , A61P33/00 , C07D233/20 , C07D233/22 , C07D233/24 , A23K1/00 , A23K1/17 , A01N43/50
Abstract: The present invention relates to agents for systemic combating of ectoperasites in host animals, containing a compound of the formul I (I) in which R1 denotes hydrogen, (C1-C5)-alkyl, (C1-C3)-halogenoalkyl or halogen; R2 and R3 independently of one another denote (c1-C5)-alkyl, (C2-C5)-alkenyl, (C2-C5)-alkynyl, (C3-C7)-cycloalkyl, (C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl, halogen, cyano, nitro, (C1-C5)-alkoxy, (C1 -C3)-alkoxy-C1-C3)-alkyl, (C1-C3)-halogenoalkoxy or (C1-C3)-alkylthio, or R2 and R3 together form a polymethylene chain having 2 to 5 carbon atoms: R4 denotes hydrogen, (c1-C10)-alkyl, (C2-C5)-alkenyl or (C3-C7)-cycloalkyl; R5 denotes hydrogen, (C1-C10)-alkyl, (C3-C5)-alkenyl, C3-C5)-alkynyl, (C3-C7)- cycloalkyl, (C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl or (C1-C3)-alkoxy-(C hd 1-C3)-alkyl; X denotes oxygen, sulfur or an -NR6-group; and R6 denotes hydrogen, (C1-C5)-alkyl, (C3-C5)-alkenyl, C3-C5)-alkynyl, (C3-C7)-cycloalkyl, C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl or (C1-C3)-alkoxy-(C1 -C3)-alkyl, or biologically tolerated acid addition salts thereof. The compounds of the formulas I are novel in some cases and are likewise included in the invention.
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公开(公告)号:CA2086491C
公开(公告)日:2003-09-16
申请号:CA2086491
申请日:1992-12-30
Applicant: HOECHST AG
Inventor: ORT OSWALD , WILLMS LOTHAR , ZEIS HANS-JOACHIM , MULLER STEPHAN , STARK HERBERT , SCHUTZE RAINER , BAUER KLAUS , BIERINGER HERMANN
Abstract: Combinations of herbicides and crop-protecting substances Herbicide/safener combinations of A) herbicides selected from the group of the 2-acylated 1,3-dicarbonyl compounds or salts thereof, and B) safeners B1 and/or B2 as they are defined in claim 1, are suitable for controlling harmful plants in crops such as cereals, maize and rice.
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公开(公告)号:AU662581B2
公开(公告)日:1995-09-07
申请号:AU3047792
申请日:1992-12-30
Applicant: HOECHST AG
Inventor: ORT OSWALD , WILLMS LOTHAR , ZEIS HANS-JOACHIM , MULLER STEPHEN , STARK HERBERT , SCHUTZE RAINER , BAUER KLAUS , BIERINGER HERMANN
IPC: A01N25/32 , A01N35/06 , A01N43/42 , A01N43/56 , A01N43/653 , A01N43/80 , A01N33/20 , A01N33/22 , A01N41/10 , A01N37/42 , A01N41/04 , A01N41/06 , A01N43/16 , A01N43/18 , A01N43/40 , A01N43/54 , A01N47/02
Abstract: A herbicide-safener combination comprises a cyclic 2-acyl-1,3-dicarbonyl compound herbicide (I) and an 8-quinolinyloxyalkanoic acid derivative safener (II). A herbicidal composition contains at least one 2-acyl-1,3-dicarbonyl compound herbicide of formula (I) (or its salt) and at least one quinoline derivative safener of formula (II). R1, R3 = H, halo, alkyl, haloalkyl, haloalkoxy, CN, NO2, S(O)mR11, NR12R13, NR14COR15, COR16 or OCH2CH2OR21; R2 = halo, CN, NO2, alkyl, alkoxy, haloalkyl, haloalkoxy, S(O)pR10, OSO2R10 or N(R20)SO2R19; W = N or CH; R10 = alkyl, haloalkyl or alkoxy; R11 = alkyl, haloalkyl or NR17R16; or phenyl or benzyl (both optionally ring-substituted); R12-R15, R17, R18, R21 = H or alkyl; R16 = H, alkyl, haloalkyl or alkoxy; R19, R20 = alkyl or haloalkyl; m, p = 0-2; U = group completing an optionally further substituted 5- or 6-membered carbocyclic or heterocyclic ring; Y = halo, A', NO2 or OA; A = 1-4C alkyl; A' = 1-4C alkyl or 1-4C haloalkyl; n = 1-5; Q = 1-2C alkylene (optionally substituted by 1 or 2 A); Z' = ORa, SRa or NRRa; R = H, 1-6C alkyl, 1-6C alkoxy or optionally substituted phenyl; Ra = H; or 1-18C alkyl, 3-12C cycloalkyl, 2-8C alkenyl or 2-8C alkynyl (all optionally substituted by one or more of halo, OH, OB, SB, 3-7C cycloalkyl, 3-7C cycloalkoxy, CN, NHA, N(A)2, BOCO, 1-8C alkylthiocarbonyl, BCO, 1-(=NOH, =NA or =NOA)-1-6C alkyl, BCONH, CONH2, mono- or di-(1-6C alkyl)-aminocarbonyl, (2-6C alkenyl, 2-6C alkynyl or 1-8C alkoxy)-aminocarbonyl, 1-8C alkylaminocarbonylamino, 1-6C alkylcarbonyloxy (optionally substituted by halo, NO2, OA or optionally substituted phenyl), (2-6C alkenyl or 2-6C alkynyl)carbonyloxy, 1-8C alkylsulfonyl, Ar, Ar-(1-6C) alkoxy, Ar-(1-6C) alkoxycarbonyl, OAr, ArCOO, ArCONH, Ar-(1-6C) alkylcarbonylamino, Si(R')3, OSi(R')3, (R')3-(1-6C) alkoxy, COON(R')2, ON=C(R')2, N=C(R')2, ON(R')2, CH(OR')2, O(CH2)qCH(OR')2 or R''OCR'''(OR'')-(1-6C) alkoxy); or NRRa = optionally unsaturated 3-7 membered heterocycle containing 1-3 heteroatoms (optionally substituted by A, OA or optionally substituted phenyl); B = 1-8C alkyl, 2-8C alkenyl or 2-8C alkynyl; Ar = phenyl (optionally substituted by one or more of halo, A', OA' and NO2); R' = H, A or phenyl (optionally substituted by one or more of halo, A', OA; and NO2); or (R')2 = 2-6C alkylene; q = 0-6; R'' = A; or (R'')2 = 1-6C alkylene; R''' = H or A. Independent claims are included for: (1) a method for protecting crop plants against the phytotoxic side-effects of (I), involving applying (II) to the plants (or their seeds or growth area) before, after or simultaneously with application of (I); and (2) the use of (II) for protecting crop plants against the phytotoxic side-effects of herbicides (I).
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17.
公开(公告)号:ZA9201642B
公开(公告)日:1992-10-28
申请号:ZA9201642
申请日:1992-03-05
Applicant: HOECHST AG
Inventor: STARK HERBERT , HERBERT STARK , BAUER KLAUS , KLAUS BAUER , BIERINGER HERMANN , HERMANN BIERINGER
IPC: A01N35/06 , A01N37/34 , A01N41/04 , A01N41/06 , A01N41/10 , C07C45/54 , C07C45/72 , C07C49/84 , C07C205/45 , C07C205/48 , C07C255/17 , C07C255/56 , C07C317/24 , C07C317/46 , C07C323/22 , C07C323/62 , C07C , A01N
CPC classification number: C07C205/45 , A01N35/06 , C07C45/54 , C07C45/72 , C07C49/84 , C07C255/56 , C07C317/24 , C07C317/46 , C07C323/22 , C07C323/62 , C07C2601/08 , C07C2601/14
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公开(公告)号:AU623461B2
公开(公告)日:1992-05-14
申请号:AU4685689
申请日:1989-12-19
Applicant: HOECHST AG
Inventor: STARK HERBERT , SALBECK GERHARD , BONIN WERNER
IPC: A61K31/415 , A61P33/00 , C07D233/20 , C07D233/22 , C07D233/24
Abstract: The present invention relates to agents for systemic combating of ectoperasites in host animals, containing a compound of the formul I (I) in which R1 denotes hydrogen, (C1-C5)-alkyl, (C1-C3)-halogenoalkyl or halogen; R2 and R3 independently of one another denote (c1-C5)-alkyl, (C2-C5)-alkenyl, (C2-C5)-alkynyl, (C3-C7)-cycloalkyl, (C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl, halogen, cyano, nitro, (C1-C5)-alkoxy, (C1 -C3)-alkoxy-C1-C3)-alkyl, (C1-C3)-halogenoalkoxy or (C1-C3)-alkylthio, or R2 and R3 together form a polymethylene chain having 2 to 5 carbon atoms: R4 denotes hydrogen, (c1-C10)-alkyl, (C2-C5)-alkenyl or (C3-C7)-cycloalkyl; R5 denotes hydrogen, (C1-C10)-alkyl, (C3-C5)-alkenyl, C3-C5)-alkynyl, (C3-C7)- cycloalkyl, (C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl or (C1-C3)-alkoxy-(C hd 1-C3)-alkyl; X denotes oxygen, sulfur or an -NR6-group; and R6 denotes hydrogen, (C1-C5)-alkyl, (C3-C5)-alkenyl, C3-C5)-alkynyl, (C3-C7)-cycloalkyl, C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl or (C1-C3)-alkoxy-(C1 -C3)-alkyl, or biologically tolerated acid addition salts thereof. The compounds of the formulas I are novel in some cases and are likewise included in the invention.
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公开(公告)号:ZA899722B
公开(公告)日:1990-09-26
申请号:ZA899722
申请日:1989-12-19
Applicant: HOECHST AG
Inventor: STARK HERBERT , HERBERT STARK , SALBECK GERHARD , GERHARD SALBECK , BONIN WERNER , WERNER BONIN
IPC: A61K31/415 , A61P33/00 , C07D233/20 , C07D233/22 , C07D233/24 , C07D , A01N
Abstract: The present invention relates to agents for systemic combating of ectoperasites in host animals, containing a compound of the formul I (I) in which R1 denotes hydrogen, (C1-C5)-alkyl, (C1-C3)-halogenoalkyl or halogen; R2 and R3 independently of one another denote (c1-C5)-alkyl, (C2-C5)-alkenyl, (C2-C5)-alkynyl, (C3-C7)-cycloalkyl, (C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl, halogen, cyano, nitro, (C1-C5)-alkoxy, (C1 -C3)-alkoxy-C1-C3)-alkyl, (C1-C3)-halogenoalkoxy or (C1-C3)-alkylthio, or R2 and R3 together form a polymethylene chain having 2 to 5 carbon atoms: R4 denotes hydrogen, (c1-C10)-alkyl, (C2-C5)-alkenyl or (C3-C7)-cycloalkyl; R5 denotes hydrogen, (C1-C10)-alkyl, (C3-C5)-alkenyl, C3-C5)-alkynyl, (C3-C7)- cycloalkyl, (C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl or (C1-C3)-alkoxy-(C hd 1-C3)-alkyl; X denotes oxygen, sulfur or an -NR6-group; and R6 denotes hydrogen, (C1-C5)-alkyl, (C3-C5)-alkenyl, C3-C5)-alkynyl, (C3-C7)-cycloalkyl, C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl or (C1-C3)-alkoxy-(C1 -C3)-alkyl, or biologically tolerated acid addition salts thereof. The compounds of the formulas I are novel in some cases and are likewise included in the invention.
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公开(公告)号:DK648489A
公开(公告)日:1990-06-21
申请号:DK648489
申请日:1989-12-19
Applicant: HOECHST AG
Inventor: STARK HERBERT , SALBECK GERHARD , BONIN WERNER
IPC: A61K31/415 , A61P33/00 , C07D233/20 , C07D233/22 , C07D233/24 , A01N43/50
Abstract: The present invention relates to agents for systemic combating of ectoperasites in host animals, containing a compound of the formul I (I) in which R1 denotes hydrogen, (C1-C5)-alkyl, (C1-C3)-halogenoalkyl or halogen; R2 and R3 independently of one another denote (c1-C5)-alkyl, (C2-C5)-alkenyl, (C2-C5)-alkynyl, (C3-C7)-cycloalkyl, (C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl, halogen, cyano, nitro, (C1-C5)-alkoxy, (C1 -C3)-alkoxy-C1-C3)-alkyl, (C1-C3)-halogenoalkoxy or (C1-C3)-alkylthio, or R2 and R3 together form a polymethylene chain having 2 to 5 carbon atoms: R4 denotes hydrogen, (c1-C10)-alkyl, (C2-C5)-alkenyl or (C3-C7)-cycloalkyl; R5 denotes hydrogen, (C1-C10)-alkyl, (C3-C5)-alkenyl, C3-C5)-alkynyl, (C3-C7)- cycloalkyl, (C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl or (C1-C3)-alkoxy-(C hd 1-C3)-alkyl; X denotes oxygen, sulfur or an -NR6-group; and R6 denotes hydrogen, (C1-C5)-alkyl, (C3-C5)-alkenyl, C3-C5)-alkynyl, (C3-C7)-cycloalkyl, C3-C7)-cycloalkenyl, (C1-C3)-halogenoalkyl or (C1-C3)-alkoxy-(C1 -C3)-alkyl, or biologically tolerated acid addition salts thereof. The compounds of the formulas I are novel in some cases and are likewise included in the invention.
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