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公开(公告)号:CZ9400496A3
公开(公告)日:1994-09-14
申请号:CZ49694
申请日:1994-03-04
Applicant: HOECHST AG
Inventor: BRINDOEPKE GERHARD , ZOELLER JOACHIM
IPC: C08F2/24 , B01F17/52 , C08F290/00 , C08F299/06 , C08G18/28 , C08G18/36 , C08G18/48 , C08G18/66 , C08G18/67 , C08J3/03 , C08L75/16 , C09D175/14
CPC classification number: C08J3/03 , C08G18/2825 , C08G18/283 , C08G18/284 , C08G18/4833 , C08G18/672 , C08G18/0823
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公开(公告)号:AU5754594A
公开(公告)日:1994-09-08
申请号:AU5754594
申请日:1994-03-03
Applicant: HOECHST AG
Inventor: BRINDOEPKE GERHARD , ZOELLER JOACHIM
IPC: C08F2/24 , C08F290/00 , C08F299/06 , C08G18/08 , C08G18/28 , C08G18/36 , C08G18/48 , C08G18/66 , C08G18/67 , C08J3/03 , C08L75/16 , C09D175/14 , C09K23/52 , C08G18/32 , B01F17/52
Abstract: Unsaturated polyurethanes containing from 20 to 80 % by weight of polyethylene glycol units, obtainable by reacting a) at least one organic polyisocyanate, b) an unsaturated fatty alcohol, a polyalkylene glycol ether thereof or a hydroxyl-containing ester of unsaturated acids, c) one or more diols additionally containing at least one further hydroxyl group or carboxyl group, and d) a polyethylene glycol having a molecular weight in the range from 750 to 10,000, with observance of an NCO/OH equivalent ratio, based on all starting components a) to d), of from 0.7 : 1 to 1.2 : 1. These unsaturated polyurethanes are used as reactive emulsifiers for the preparation of dispersions of hydrophobic synthetic resins which can be cured by means of free radicals and/or oxidatively.
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公开(公告)号:ZA929811B
公开(公告)日:1993-06-23
申请号:ZA929811
申请日:1992-12-18
Applicant: HOECHST AG
Inventor: EXNER REINER , SCHWAB MICHAEL , KIHN UTE , ZOELLER JOACHIM
IPC: B05D20060101 , C09D20060101 , C09D , B05D
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公开(公告)号:CZ283991B6
公开(公告)日:1998-07-15
申请号:CS371992
申请日:1992-12-17
Applicant: HOECHST AG
Inventor: EXNER REINER , SCHWAB MICHAEL , KUHN UTE , ZOELLER JOACHIM
IPC: C08L67/00 , C08G63/68 , C08G63/688 , C08G63/692 , C09D167/00
Abstract: An aqueous filler composition containing a polyester resin which is built up from the starting materials (a), (b), (c), (d) and (e) or ester-forming derivatives thereof, where the sum of the reactants corresponds to 100 mol% and the ratio between the sum of the hydroxyl equivalents (eq of OH) and the sum of the carboxyl equivalents in the reactants is between 0.5 and 2.0, where (a) is at least one dicarboxylic acid which is not a sulpho or phosphorus monomer, (b) from 0 to 15 mol% of at least one difunctional sulpho or phosphono monomer whose functional groups are carboxyl or hydroxyl groups, containing at least one sulphonate or phosphonate group, (c) at least one difunctional compound which is derived from a glycol containing two -C(R)2-OH groups, (d) up to 40 mol% of a higher-functional compound (functionality > 2) whose functional groups comprise hydroxyl and/or carboxyl groups, and (e) from 0 to 20 mol% of a monofunctional carboxylic acid, where the radicals R in (c) may be, independently of one another, hydrogen, C1-C4-alkyl or C6-C10-aryl, the amounts of free hydroxyl groups are between 30 and 350 milliequivalents of OH/100 g, preferably between 100 and 250 meq of OH/100 g, and the content of free neutralised and/or neutralisable acid groups, in particular sulphonic, phosphonic or carboxyl groups, is between 5 and 350 meq of acid groups/100 g, preferably between 9 and 120 meq of acid groups/100 g.
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15.
公开(公告)号:ZA963461B
公开(公告)日:1997-11-03
申请号:ZA963461
申请日:1996-05-02
Applicant: HOECHST AG
Inventor: ZOELLER JOACHIM , BITTNER ANNEGRET , URBANO EDMUND
IPC: B05D7/24 , C08G18/08 , C08G18/40 , C08G18/42 , C08G18/65 , C08G18/66 , C08G18/70 , C08G18/79 , C08L75/00 , C08L75/04 , C09D5/00 , C09D5/02 , C09D5/08 , C09D167/00 , C09D167/08 , C09D175/04 , C09D175/06 , C09D
Abstract: Water-dilutable 2-component coating materials (I), contg. (a) an isocyanate component with a viscosity of 50-10,000 mPa.s at 23 degrees C, consisting of polyfunctional isocyanate(s), and (b) an alkyd resin emulsion, contg. (b1) 60-98 wt% alkyd resin(s) (based on solids), (b2) 2-40 wt% OH-functional emulsifier(s) (based on solids), (b3) opt. up to 15 wt% organic solvent (based on emulsion), and (b4) water. Also claimed is: (i) a process for the prodn. of (I) by transferring an alkyd resin into the aq. phase with the aid of OH-functional emulsifiers and then emulsifying polyisocyanate in this emulsion; (ii) a process for the prodn. of coatings using (I); (iii) a process for the prodn. of multilayer coatings, in which at least one of the coating materials used contains (I).
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公开(公告)号:ZA963460B
公开(公告)日:1997-11-03
申请号:ZA963460
申请日:1996-05-02
Applicant: HOECHST AG
Inventor: ZOELLER JOACHIM , MERTEN GERHARD , URBANO EDMUND , GOBEC MICHAEL
Abstract: Aq. alkyd resin emulsions (I), contg. (a) an alkyd resin made from (a1) a fatty acid or an oil and (a2) higher-functional cpd(s). with OH and/or COOH as functional gps., and (b) an emulsifier, in which all the raw materials required for components (a) and (b) can be obtd. exclusively from replaceable sources. Also claimed are coating materials contg. (I).
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公开(公告)号:CZ128396A3
公开(公告)日:1996-11-13
申请号:CZ128396
申请日:1996-05-02
Applicant: HOECHST AG
Inventor: ZOELLER JOACHIM , MERTEN GERHARD ING , URBANO EDMUND , GOBEC MICHAEL ING
IPC: C08G18/08 , C08G18/12 , C08G18/32 , C08G18/36 , C08G18/42 , C08G18/46 , C08G18/48 , C08G18/62 , C08G18/65 , C08G18/66 , C08G18/68 , C08J3/03 , C08L67/00 , C08L67/06 , C08L75/00 , C08L75/06 , C09K23/52 , B01F17/52
Abstract: Water-dispersible polyurethane-polyureas (I), obtd. by reacting (a) organic polyisocyanate(s) with (b) isocyanate-reactive polyester-polyol(s) obtd. from (i) dicarboxylic acid(s), (ii) diol(s) and opt. (iii) polyfunctional component(s) with OH and/or COOH gps., (c) opt. an isocyanate-reactive fatty acid deriv., (d) opt. a higher-functional OH and/or COOH gp.-contg. cpd. with a functionality of more than 2, (e) a polyalkylene glycol with a mol. wt. of 750-10,000 and (f) an active H-contg. cpd. in which the active H reacts with the NCO gps. faster than water, with a ratio of (NCO gps.):(NCO-reactive H atoms) = (0.6:1)- (1:1), to give a prod. contg. 10-60 wt% of polyester units and 25-75 wt% of glycol units.
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公开(公告)号:ZA953669B
公开(公告)日:1996-11-08
申请号:ZA953669
申请日:1995-05-08
Applicant: HOECHST AG
Inventor: MERTEN GERHARD , ZOELLER JOACHIM , URBANO EDMUND
IPC: C08G18/00 , C08G18/08 , C08G18/12 , C08G18/28 , C08G18/34 , C08G18/36 , C08G18/48 , C08G18/65 , C08G18/66 , C08J3/03 , C09K23/52 , C08G , B01F , C08J
Abstract: Hydrophilic polyurethane-polyureas (I) are obtd. by reacting (A) polyisocyanate(s) with (B) fatty acid deriv(s). which is/are reactive towards (a), (C) opt. a cpd. with more than 2 OH and/or COOH gps., (D) a polyalkylene glycol with a mol. wt. of 500-10,000 and (E) a cpd. with active H atom(s) which react more rapidly than water with NOC gps., with a mole ratio of (NCO gps.):(all NCO-reactive H atoms in A-E) = (0.5:1)-(2:1). Pref. mole ratio of (NCO gps.):(H atoms in OH and amino gps. in all components A-E) = (0.7:1)-(1.5:1); amts. of co-reactants are 0.1-1 mole (B), 0-0.8 mole (C), 0.1-0.8 mole (D) and 0.01-0.3 mole (E) to 1 mole (A). (B) comprise opt. unsatd. cpds., pref. fatty alcohols, fatty amines, or ethoxylated fatty alcohols or amines contg. 1-30 ethylene oxide (EO) units, esp. ethoxylated fatty alcohols with 1-20 EO units, or reaction prods. of fatty acids with polyols which may also contain amino gps., or reaction prods. of fatty acids and mono-epoxides. (C) is a bis-hydroxy-alkanecarboxylic acid, pref. dimethylolpropionic acid (DMPA).
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19.
公开(公告)号:CZ9501185A3
公开(公告)日:1995-11-15
申请号:CZ118595
申请日:1995-05-09
Applicant: HOECHST AG
Inventor: MERTEN GERHARD ING , ZOELLER JOACHIM , URBANO EDMUND
IPC: B01F17/52 , C08G18/00 , C08G18/08 , C08G18/12 , C08G18/28 , C08G18/34 , C08G18/36 , C08G18/48 , C08G18/65 , C08G18/66 , C08J3/03
CPC classification number: C08J3/03 , C08G18/0823 , C08G18/12 , C08G18/2825 , C08G18/2865 , C08G18/6692 , C08G18/6696 , C08G18/3271 , C08G18/3225 , C08G18/3821 , C08G18/3834
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公开(公告)号:AU663398B2
公开(公告)日:1995-10-05
申请号:AU4467993
申请日:1993-08-18
Applicant: HOECHST AG
Inventor: SCHWAB MICHAEL , ZOELLER JOACHIM
IPC: C08G18/42 , C08G18/08 , C08G18/46 , C08G63/06 , C08G63/16 , C08G63/60 , C08G63/688 , C08G63/692 , C09D5/02 , C09D175/04 , C09D175/06 , C09D175/00 , C09D167/03 , C09D167/04
Abstract: Water-dilutable (water-thinnable), two-component coating composition containing 1) a polyisocyanate component and 2) a polyester resin built up from the starting materials (a), (b), (c), (d) and (e) or ester-forming derivatives thereof, where the ratio between the total of the hydroxyl equivalents and the total of the carboxyl equivalents in the reactants is between 1:0.5 and 1:2.0, where (a) is at least one dicarboxylic acid which is not a sulphomonomer, (b) is from 0 to 15 mol% of at least one difunctional sulpho or phosphonomonomer whose functional groups are carboxyl and/or hydroxyl groups, containing at least one sulphonate or phosphonate group, (c) is at least one glycol, (d) is from 0 to 40 mol% of a higher-functional compound (functionality > 2) whose functional groups comprise hydroxyl and/or carboxyl groups, and (e) is from 0 to 20 mol% of a monofunctional carboxylic acid, where the amounts of free hydroxyl groups are between 30 and 350 milliequivalents of OH/100 g, and the content of free neutralised and/or neutralisable acid groups is between 5 and 350 meq/100 g. These coating compounds are particularly suitable for the production of primers, fillers, topcoats and single-coat finishes.
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